A new high-speed solar spectrograph for meter and decameter wavelengths

A new high-speed digital solar radio spectrograph has been designed and is being operated at the Clark Lake Radio Observatory in California. The spectrograph design attempts to optimize sensitivity, dynamic range, and frequency-time resolution while utilizing modern high-speed computer data-handling techniques. The system is described and initial data observations are presented.     

MORICE--new technology for mechanical oil recovery in ice infested waters

Mechanical oil recovery in ice infested waters (MORICE) was initiated in 1995 to develop technology for the recovery of oil spills in ice. It has been a multinational effort involving Norwegian, Canadian, American and German organizations and researchers. Through a stepwise approach with the development organized in six separate phases, laboratory tests and field experiments have been conducted to study various ideas and concepts, and to refine the ideas that were considered to have the best potential for removing oil in ice. Put together in one unit, these concepts included ice processing equipment and two alternative oil recovery units installed on a work platform. In January 2002, the final oil and ice testing with MORICE concepts was conducted at the Ohmsett test facility in Leonardo, New Jersey. The unit has been referred to as a harbor version to indicate the size and operating conditions, but the concepts could be scaled up to increase the capacity of oil and ice processing. For heavier ice conditions it would also be necessary to increase the overall strength.     

Intra-oceanic production of continental crust in a Th-depleted ca. 3.0 Ga arc complex,western Superior Province,Canada

The English Lake magmatic complex in the western Superior Province of Canada represents a fragment of early (3.0 Ga) continental crust exposed in oblique cross section through tonalitic upper levels and subjacent quartz diorite, diorite and gabbro, which are cut by late gabbro, anorthosite and hornblendite dykes. Massive, foliated and gneissic units of tonalitic to gabbroic composition, crystallized over a 10 to 18 m.y. period, bear common geochemical attributes, including negative Th, U and Nb anomalies, and only slight LREE and LILE enrichment on NMORB-normalized trace-element profiles. Epsilon Nd values (+0.1 to +1.7) and ¹⁸O (+6.7 to +8.0 ) do not co-vary with silica or other crustal contamination indices. High Mg#'s and Ni contents suggest derivation from, or interaction with mantle, and large positive anomalies for Ba, Sr and Pb, as well as high U/Th, suggest metasomatism by hydrous fluids. Trace-element profiles resemble those of primitive intra-oceanic island arc magmas except for the negative Th-U anomaly, which precludes the involvement of either oceanic (sedimentary or basaltic) or continental crust in the petrogenesis of English Lake magmas. In order to account for the unusual geochemical character of the suite, we postulate that water-rich fluids derived from subducted, sea-floor-altered serpentinite provided the flux for melting a depleted mantle wedge. Contemporaneous, proximal high Th/Nb tonalites suggest that the zone of serpentinite subduction occurred within a restricted arc segment possibly due to subduction of either: (a) a seamount chain oriented broadly perpendicular to an arc, or (b) a similarly oriented serpentinite-enclosed oceanic fracture zone or fault.Electronic Supplementary Material Supplementary material is available in the online version of this article at .Editorial responsibility: T.L. Grove     

Eastern Mississippi delta: late Wisconsin unconformity, overlying transgressive facies, sea level and subsidence

Analysis of 92 engineering core logs located in the Balize sector of the eastern Mississippi delta focuses on the late Wisconsin unconformity and lithofacies of strata lying immediately below and above this stratigraphic horizon. This major sequence boundary is a key feature used to correlate strata across shelf and slope to the basin. Observations emphasize lithofacies distributions of the latest Pleistocene sediments underlying the unconformity, the late Pleistocene to early Holocene transgressive facies, and the immediately overlying deltaic deposits. Maps and a cross-section compiled with this information highlight the critical relation between lithofacies distributions and late Wisconsin sea-level oscillations. Core analysis reveals that the transgressive facies comprises distinct environments of deposition, offshore to onshore. Findings identify criteria to determine the approximate position of the shoreline at the late Wisconsin maximum sea-level lowstand and at the extent of early Holocene maximum marine inundation in the Balize complex. Mapping of lithologies along the late Wisconsin unconformity serves to improve correlation of sediment facies with changes in acoustic response along high-resolution seismic profiles. An estimate of long-term averaged land subsidence suggests lowering of at least 1 mm/year near the shelfedge during the past 18 000 years. This mapping also refines sea-level response models for the Mississippi delta, including criteria to locate key paleogeographic features such as shelfedges and maximum flooding surfaces in other Recent marine deltas and in older, stacked deltaic sequences.     

Geochemical response of acid groundwater to neutralization by alkaline recharge

Solute transport and chemical neutralization (pH 3 to 7) within a shallow heterogeneous aquifer producing acid mine drainage (AMD) are examined at an abandoned surface coal mine in West Virginia. The aquifer is undergoing partial neutralization by mixing with alkalinity from a leaking sludge disposal pond, extending in preferential zones controlled by aquifer heterogeneity. Hydraulic heads interpolated from wells indicate leakage from a central alkaline (pH 7.1, 0.72 meq/L alkalinity) sludge pond is a principal source of recharge. Chemically-conservative sodium, added to AMD during treatment and leaked into the aquifer with the sludge, develops a dispersion plume over a restricted portion of the aquifer that correlates with pH, hydraulic head, and dissolved metals distributions. Concentrations of aluminum, iron, sulfate and acidity display higher concentrations downgradient from the pond as sludge alkalinity is consumed along flow paths. Before reaching springs, most dissolved iron is oxidized and hydrolyzed, likely precipitating in the aquifer as a ferric hydroxide or hydroxysulfate phase. The spatial pattern of iron and aluminum concentrations suggests accelerated oxidation caused by gas transport along the outer slopes of the spoil. Dissolved aluminum concentrations increase with total acidity, suggesting that dissolution of silicate minerals results from acidity released by iron hydrolysis. Neutralization reactions and higher pH are favored in more highly permeable portions of the spoil, where ferrihydrite and aluminum hydroxysulfate minerals (such as basaluminite) are supersaturated. In acid-producing zones at pH < 4.5, jurbanite is near equilibrium and an aluminum-sulfate phase with similar properties may limit aluminum concentrations, but become undersaturated in zones of advancing neutralization. At this particular site, ferrous iron produced by pyrite oxidation is almost completely oxidized over short transport distances, allowing hydrolysis of iron and aluminum should sufficient alkalinity be added to these acid waters.     

Mercury and methylmercury in water and sediment of the Sacramento River Basin, California

Mercury (Hg) and methylmercury (CH₃Hg⁺) concentrations in streambed sediment and water were determined at 27 locations throughout the Sacramento River Basin, CA. Mercury in sediment was elevated at locations downstream of either Hg mining or Au mining activities where Hg was used in the recovery of Au. Methylmercury in sediment was highest (2.84 ng/g) at a location with the greatest wetland land cover, in spite of lower total Hg at that site relative to other river sites. Mercury in unfiltered water was measured at 4 locations on the Sacramento River and at tributaries draining the mining regions, as well as agricultural regions. The highest levels of Hg in unfiltered water (2248 ng/l) were measured at a site downstream of a historic Hg mining area, and the highest levels at all sites were measured in samples collected during high streamflow when the levels of suspended sediment were also elevated. Mercury in unfiltered water exceeded the current federal and state recommended criterion for protection of aquatic life (50 ng/l as total Hg in unfiltered water) only during high streamflow conditions. The highest loading of Hg to the San Francisco Bay system was attributed to sources within the Cache Creek watershed, which are downstream of historic Hg mines, and to an unknown source or sources to the mainstem of the Sacramento River upstream of historic Au mining regions. That unknown source is possibly associated with a volcanic deposit. Methylmercury concentrations also were dependent on season and hydrologic conditions. The highest levels (1.98 ng/l) in the Sacramento River, during the period of study, were measured during a major flood event. The reactivity of Hg in unfiltered water was assessed by measuring the amount available for reaction by a strong reducing agent. Although most Hg was found to be nonreactive, the highest reactivity (7.8% of the total Hg in water) was measured in the sample collected from the same site with high CH₃Hg⁺ in sediment, and during the time of year when that site was under continual flooded conditions. Although Hg concentrations in water downstream of the Hg mining operations were measured as high as 2248 ng/l during stormwater runoff events, the transported Hg was found to have a low potential for geochemical transformations, as indicated by the low reactivity to the reducing agent (0.0001% of the total), probably because most of the Hg in the unfiltered water sample was in the mercury sulfide form.     

Integrated scenarios of acidification and climate change in Asia and Europe

Two integrated assessment models, one for climate change on a global scale (IMAGE 2) and another for the regional analysis of the impacts of acidifying deposition (RAINS), have been linked to assess the impacts of reducing sulphur emission on ecosystems in Asia and Europe. While such reductions have the beneficial effect of reducing the deposition of acidifying compounds and thus the exceedance of critical loads of ecosystems, they also reduce the global level of sulphate aerosols and thus enhance the impact of increased emissions of greenhouse gases, and consequently increase the risk of potential vegetation changes. The calculations indicate that about 70% of the ecosystems in Asia would be affected by either acid deposition or climate change in the year 2100 (up from 20% in 1990) for both sulphur emission scenarios (controlled and uncontrolled), whereas in Europe the impacted area would remain at a level of about 50%, with a dip early next century. More generally, the effects of reducing sulphur emissions and thus enhancing climate change would about balance for the Asian region, whereas for Europe the desirable impact of sulphur emission reductions would greatly outweigh its undesirable effects.     

Sources and paleoclimatic significance of Holocene Bignell Loess, central Great Plains, USA

This paper reexamines the stratigraphy, sources, and paleoclimatic significance of Holocene Bignell Loess in the central Great Plains. A broadly similar sequence of loess depositional units and paleosols was observed in thick Bignell Loess sections up to 300 km apart, suggesting that these sections record major regional changes in the balance between dust deposition and pedogenesis. New optical ages, together with previously reported radiocarbon ages, indicate Bignell Loess deposition began 9000–11,000 yr ago and continued into the late Holocene; some Bignell Loess is <1000 yr old. There is little evidence that Holocene Loess was derived from flood plain sources, as previously proposed. Instead, thick Bignell Loess occurs mainly near the downwind margins of inactive dune fields, particularly atop escarpments facing the dunes. Thus, the immediate loess source was dust produced when the dunes were active. Previous work indicates that widespread episodes of dune activity are likely to have resulted from drier-than-present climatic conditions. The regionally coherent stratigraphy of Bignell Loess can be interpreted as a near-continuous record of climatically driven variation in dune field activity throughout the Holocene.