Biogeochemical characterization of particulate organic matter from a coastal hydrothermal vent zone in the Aegean Sea

Three particle interceptor traps were moored from June to September 1996 along the SE coast of Milos Island (Aegean Sea), in an area known for its extensive seabed geothermal activity. The settling particles collected differed between sites not only in quantity but also in their geochemical composition. In the area directly influenced by warm water vents, the vertical flux of particulate material was almost one order of magnitude higher than that observed at the reference sites 6.5 km away from the vents, with a higher contribution of biogenic material in the former. The neutral lipid fractions exhibited a significant zooplankton biomarker signature (e.g. cholesterol and wax esters), followed by those of microalgal and terrigenous remains. The biogeochemical cycle of sterols included the formation of steroidal ketones, thiols and stanols, the latter two particularly associated with the venting activity. Moreover, the aliphatic and aromatic hydrocarbons in the particles from the venting area reflected a locally enhanced maturity of the organic matter. Although part of the material collected in the traps may have been exported in the vent waters, the higher fluxes observed in the vicinity of the hydrothermal plumes are mainly the result of an assemblage of zooplankton which, in turn, may contribute significantly to the sedimentation, through fast sinking faecal pellets, of the petrogenic hydrocarbons possibly generated in the vents.     

Neural network modelling of wave overtopping at coastal structures

A method has been developed to estimate wave overtopping discharges for a wide range of coastal structures. The prediction method is based on Neural Network modelling. For this purpose use is made of a data set obtained from a large number of physical model tests (collected within the framework of the European project CLASH, see e.g. [Steendam, G.J., Van der Meer, J.W., Verhaeghe, H., Besley, P., Franco, L. and Van Gent, M.R.A. (2004). The international database on wave overtopping. World Scientific, Proc. 29th ICCE, vol. 4, pp. 4301–4313, Lisbon, Portugal.]). Moreover, a method was developed to obtain confidence intervals for the overtopping predictions of the neural network.     

Dioxin compounds in the deep-sea rose shrimp Aristeus antennatus (Risso, 1816) throughout the Mediterranean Sea

Polychlorodibenzo-p-dioxins (PCDDs) and polychlorodibenzofurans (PCDFs) are among the more toxic anthropogenic contaminants. They are fat-soluble and accumulate in animal tissues. Exposure to PCDD/Fs can cause several endocrine, reproductive and developmental problems in animals, including human beings. Several studies have demonstrated that fish and invertebrates living in association with sediments are exposed to and accumulate contaminants, but to date there have been no studies of PCDD/Fs contamination in deep-sea regions. Specimens of Aristeus antennatus (Risso, 1816) were collected from depths of 600–2500 m at different points in the Mediterranean Sea, from the western basin off the coast of Barcelona to the central basin off the Peloponnesian Peninsula, with otter trawl gear. Amounts of PCDD/Fs were measured in different animal tissues by high resolution gas chromatography coupled to high resolution mass spectrometry (HRGC–HRMS). This is the first study to report the presence of PCDD/Fs in deep-sea organisms dwelling at depths below 600 m. A. antennatus presented levels of PCDD/Fs of the same order of magnitude, or slightly higher, as those found in shallow-water species (Melicertus kerathurus) with respect to land-generated contamination. This highlights the widespread distribution of these pollutants and the potential threat posed to the biodiversity of fragile and vulnerable ecosystems such as the deep-sea. PCDD/F levels detected in the edible parts (muscle) of the commercial shrimp A. antennatus were clearly below the toxic limit value established by European legislation. Levels followed the trend muscle<ovary<hepatopancreas, according to the lipid content of the organs in question. The specific profile of toxic PCDD/F congeners in the studied Penaeid shrimp specimens was characterized mainly by octachlorodibenzo-p-dioxin (OCDD), 2,3,7,8-tetrachlorodibenzofuran (TCDF) and 2,3,4,7,8-pentachlorodibenzofuran (PeCDF) congeners. Moreover, non 2,3,7,8-substituted congeners bioaccumulated in this species, as observed in shallow-water crustaceans. PCDD/Fs were found in the shrimp A. antennatus throughout the Mediterranean Sea. Total PCDD/Fs burdens were higher in shrimps caught in the western Mediterranean than in those caught at eastern Mediterranean sites. There was a tendency for higher levels of PCDD/F contamination in samples obtained from deeper (2500 m) than from shallower sites (600 m).     

Triassic paleomagnetism from the Western Pyrenees revisited: implications for the Iberian–Eurasian Mesozoic plate boundary

Since the pioneering studies of Van der Voo [Tectonophysics 7 (1969) 5] and Van der Voo and Boessenkool [J. Geophys. Res. 78 (1973) 5118], paleomagnetism of Permo-Triassic redbeds and volcanics from the Western Pyrenees has furnished important contributions for delineating the Mesozoic boundary between the Iberian and Eurasian plates. In this paper, we present a new paleomagnetic study focussed on Triassic red beds (23 sites) of the Paleozoic Basque Massifs (PBM). The aim of this study is to complement previous studies done in those massifs to better constrain the complex kinematics of the Western Pyrenees. Two stable magnetic components have been isolated: (1) a dual polarity, pre-folding magnetisation carried by specular hematite; and (2) a secondary, normal polarity component also carried by hematite. Our data confirm both the origin and the rotation pattern of the primary remanence described in previous works. Nevertheless, field tests performed on the secondary component do not confirm the earlier interpretations by Schott and Peres [Tectonophysics 156 (1988) 75] as they indicate a synfolding nature of the remagnetisation instead of a post-folding origin. We consider that the secondary component is better explained if a Cretaceous age is considered. The presence of such remagnetisation in the western Pyrenees strengthens the widespread occurrence of similar remagnetisation events reported in northern Iberia in connection with the extensional tectonic events that occurred during Cretaceous times. A comparison of the rotations recorded by the Triassic component and by the remagnetisation indicate that the Paleozoic units underwent variable tectonic rotations before the remagnetisation was acquired, most likely in connection with the counterclockwise rotation of Iberia with respect to Eurasia. These results favour that the Mesozoic plate boundary between the Iberian and Eurasian plates was a wide domain of distributed deformation and therefore contradict previous interpretations claiming for a discrete plate boundary.     

Hydrogeological interactions between fault zones and alluvial aquifers in regional flow systems

The hydrological influence of fault zones in tectonic areas is usually difficult to depict from field data. Numerical simulation allows representation of such flow systems and an estimation of flow lines and rates. This paper reports on simulations of the groundwater flow in a range‐and‐basin area affected by a regional fault zone, which may drain or recharge an overlaying alluvial aquifer. Different hydraulic conductivity values for the range rocks, the fault‐zone, and the sedimentary infill of the basin are considered, as well as different fault‐zone widths and boundary conditions. Results show that upward and downward fluxes develop in the upper part of the fault zone, controlled by the action of the alluvial aquifer, influencing the recharge of the sedimentary basin. This paper shows the hydrological efficiency of fault zones as preferential flow; it also analyses the constraints that determine groundwater recharge to the surrounding basins. These results contribute to the understanding of hydrogeological dynamics in tectonic areas. Copyright © 2008 John Wiley & Sons, Ltd.     

Asteroid 2002NY40 as a source of meteorite-dropping bolides

The existence of asteroidal meteoroid streams capable of producing meteorite-dropping bolides has long being invoked, but evidence is scarce. Recent modelling of previously reported associations suggests that the time-scales to keep the orbital coherence of these streams producing meteorites are too short. We present an unequivocal association between near earth object (NEO) 2002NY40 and at least one bright fireball detected over Finland in 2006 August. Another two additional fireballs recorded from Spain and Finland seem to be related, together producing a fireball-producing stream (β Aquarids). On the basis of historical data, the 2006 finding suggests the existence of a meteoroid complex capable of producing meteorites. Taking into account present time-scales for orbital decoherence, if 2002NY40 has large meteoroids associated with it, such behaviour would be the consequence of a relatively recent asteroidal fragmentation. Supporting our claim, the heliocentric orbits of two recently discovered NEOs, 2004NL8 and 2002NY40, were found to exhibit a good similarity to each other and also to the orbits of the three bolides. The fireball spectra of the two Finish bolides showed that the chemical abundances of these objects are consistent with the main elements found in chondrites. This result is consistent with the probable Low iron, Low metal (LL) chondritic mineralogy of asteroid 2002NY40. Consequently, this asteroid may be delivering LL chondrites to the Earth. Additional fireball reports found in the literature suggest that the associated β Aquarid complex may have been delivering meteorites to the Earth during, at least, the last millennium.     

A radar survey of M- and X-class asteroids

We observed ten M- and X-class main-belt asteroids with the Arecibo Observatory's S-band (12.6 cm) radar. The X-class asteroids were targeted based on their albedos or other properties which suggested they might be M-class. This work brings the total number of main-belt M-class asteroids observed with radar to 14. We find that three of these asteroids have rotation rates significantly different from what was previously reported. Based on their high radar albedo, we find that only four of the fourteen—16 Psyche, 216 Kleopatra, 758 Mancunia, and 785 Zwetana—are almost certainly metallic. 129 Antigone has a moderately high radar albedo and we suggest it may be a CH/CB/Bencubbinite parent body. Three other asteroids, 97 Klotho, 224 Oceana, and 796 Sarita have radar albedos significantly higher than the average main belt asteroid and we cannot rule out a significant metal content for them. Five of our target asteroids, 16 Psyche, 129 Antigone, 135 Hertha, 758 Mancunia, and 785 Zwetana, show variations in their radar albedo with rotation. We can rule out shape and composition in most cases, leaving variations in thickness, porosity, or surface roughness of the regolith to be the most likely causes. With the exception of 129 Antigone, we find no hydrated M-class asteroids (W-class; Rivkin, A.S., Howell, E.S., Lebofsky, L.A., Clark, B.E., Britt, D.T., 2000. Icarus 145, 351-368) to have high radar albedos.