Groundwater contamination with arsenic and other trace elements in an area of the pampa,province of Córdoba,Argentina

A geochemical study of groundwater of the pampa in the province of Córdoba, Argentina, was performed; the area covered approximately 10,000 km².Physical-chemical parameters, dissolved solids, and seven trace elements were determined in 60 selected water samples. Systematic and accurate measurements of arsenic, flourine, and vanadium were performed for the first time. Three trace element contaminants not reported earlier were found: an important one, selenium, and two others of less known effects, uranium and molybdenum.Eighty-four percent of the water analyzed showed arsenic contents over 0.05 mg/L, maximum contaminant level established by the U.S. Environmental Protection Agency (1982). The frequency distribution of trace elements was analyzed, and its fit to the lognormal distribution was proved by means of the Pearson and Kolmogorov-Smirnov test; the geographic distribution of the seven trace elements was mapped and its correlation with the anion-cation composition of the water was studied.The maximum arsenic, fluorine, vanadium, and uranium contents were found in the western part of the area under study, in waters containing dominant alkali metals in the cation composition. Maximum selenium and antimony contents were found in the eastern part of the area, while molybdenum distribution does not show any relationship with the other two groups. In addition, the geographic distribution of the trace elements seems to be related to the subsurface structure, which has been inferred using interactive digital analysis of Landsat imagery. The movements of the subsoil have disturbed surface and subsurface drainage influencing the water salinity and trace element contents.In order to investigate the origin of the contamination, 54 loess samples were collected in wells at depths ranging from the surface down to the water table. This loess, which has a high proportion of volcanic components, mainly rhyolitic glass, exhibits a chemical composition corresponding to that of a dacite.The loess and the volcanic glass show anomalous contents of all contaminant trace elements, mainly arsenic and selenium. For this reason loess is considered the most important contamination source in the groundwater under study.     

Trends in the frequency of synoptic types in central-southern Chile in the period 1961–2012 using the Jenkinson and Collison synoptic classification

Atmospheric circulation patterns in southern Chile (42° 30′ S) were studied in order to determine and analyse the most characteristic synoptic types and their recent trends, as well as to gain an understanding of how they are associated with low-frequency variability patterns. According to the Jenkinson and Collison (J&C) classification method, a 16-point grid of sea-level pressure data was employed. The findings reveal that some synoptic types show statistically significant trends with a 95% confidence level, positively for anticyclonic westerly hybrids (AW) and advective types for third and fourth quadrant wind flows (W, NW, and N) and negatively for SW and cyclonic hybrids (CS and CSW). A model has been constructed of the linear regression of some weather types with teleconnections that most affect Chile: the undetermined types (U), AW were associated with El Niño or the warm phase of the Pacific Decadal Oscillation (PDO), whereas the cyclonic northerly and cyclonic northeasterly types (CN and CNE) were associated with La Niña or cool phase of the PDO. The weather types associated with Antarctic Oscillation (AAO) in its positive phase are anticyclonic northerly and northeasterly and northerly advection types, while in its negative phase are cyclonic southwesterly and advection types.     

Future regional projections of extreme temperatures in Europe: a nonstationary seasonal approach

This paper analyzes changes of maximum temperatures in Europe, which are evaluated using two state-of-the-art regional climate models from the EU ENSEMBLES project. Extremes are expressed in terms of return values using a time-dependent generalized extreme value (GEV) model fitted to monthly maxima. Unlike the standard GEV method, this approach allows analyzing return periods at different time scales (monthly, seasonal, annual, etc). The study focuses on the end of the 20th century (1961?C2000), used as a calibration/validation period, and assesses the changes projected for the period 2061?C2100 considering the A1B emission scenario. The performance of the regional models is evaluated for each season of the calibration period against the high-resolution gridded E-OBS dataset, showing a similar South-North gradient with larger values over the Mediterranean basin. The inter-RCM changes in the bias pattern with respect to the E-OBS are larger than the bias resulting from a change in the boundary conditions from ERA-40 to ECHAM5 20c3m. The maximum temperature response to increased green house gases, as projected by the A1B scenario, is consistent for both RCMs. Under that scenario, results indicate that the increments for extremes (e.g. 40-year return values) will be two or three times higher than those for the mean seasonal temperatures, particularly during Spring and Summer in Southern Europe.     

A simple model accounting for the uptake,transport, and deposition of wind‐eroded mineral particles in the hyperarid coastal Atacama Desert of northern Chile

As previously observed in marine sediments collected downwind of African or South American continental sources, recent studies of sediment cores collected at the bottom of Mejillones Bay in north Chile (23°S) show a laminated structure in which the amount of particles of aeolian origin and their size create significant differences between the layers. This suggests inter‐annual to inter‐decadal variations in the strength of the local southerly winds responsible for (1) the erosion of the adjacent hyperarid surface of the Mejillones Pampa, and (2) the subsequent transport of the eroded particles towards the bay. A simple model accounting for the vertical uptake, transport, and deposition of the particles initially set into motion by wind at the surface of the pampa is proposed. This model, which could be adapted to other locations, assumes that the initial rate of (vertical) uptake is proportional to the (horizontal) saltation flux quantified by means of White's equation, that particles are lifted to a height (H), increasing with the magnitude of turbulence, and that sedimentation progressively removes the coarsest particles from the air column as it moves towards the bay. In this model, the proportionality constant (A) linking the vertical flux of particles with the horizontal flux, and the injection height (H) control the magnitude and size distribution of the deposition flux in the bay. Their values are determined using the wind speed measured over the pampa and the size distribution of particles collected in sediment traps deployed in the bay as constraints. After calibration, the model is used to assess the sensitivity of the deposition flux to the wind intensity variations. The possibility of performing such quantitative studies is necessary for interpreting precisely the variability of the aeolian material in the sediment cores collected at the bottom of Mejillones Bay. Copyright © 2010 John Wiley & Sons, Ltd.     

Mid‐Holocene vegetation dynamics in the Tejo River estuary based on palaeobotanical records from Ponta da Passadeira (Barreiro–Setúbal,Portugal)

This paper presents the results of pollen and charcoal analyses carried out in the sedimentary formation of Ponta da Passadeira, south of the Tejo River estuary, Portugal. The data provide information regarding the evolution of the coastline and ecosystem of the estuary during the mid and late Holocene. The study focuses on a group of upright woody fossilized tree remains that, together with those identified earlier by García‐Amorena et al. (2007), form part of the fossil forest of Ponta da Passadeira. Eight remains were identified as Pinus pinaster, four as Pinus pinea and one as Pinus sp. Two specimens of these species were dated to 6523 and 5805 cal. a BP. Pollen analysis was undertaken in a clay layer located at the same point as the fossil forest, which is currently below sea level; the base of the clay layer was dated to 4906 cal. a BP. The pollen spectra reflect the dynamics of the vegetation that grew on this deposit, whereas the sporopollinic input masks the contribution of the regional vegetation. Wood charcoal remains recovered at an adjacent Final Neolithic settlement were also analysed, and a Pinus sp. specimen was radiocarbon dated to 5050 cal. a BP. The correlation amongst the three records provides key ecological markers for the understanding of the evolution of coastline ecosystems, and helps to clarify and understand the Holocene sea rise on the Atlantic seaboard of Iberia. The geographical location of Ponta da Passadeira is strategic because it enables a more clear definition of the configuration of landscapes that show an inflection point in this area of central Portugal.     

Tide-induced head fluctuations in coastal aquifers of variable thickness

In this work, a new analytical solution to describe tide-induced head fluctuations in aquifers of variable thickness is presented. The proposed model assumes a finite and confined aquifer with a thickness that increases or decreases quadratically with the distance to the coast. A closed-form analytical solution is obtained by solving a boundary-value problem with both a separation of variables method and a change of variables method. This solution is a generalization of the solution obtained by Cuello et al., Hydrogeological Journal, 2017, 25, 1509–1515. The analytical solution is expressed in terms of the wedging parameter, a parameter that depends on the length and thicknesses at the coast and at the inland edge of the aquifer. Positive values of the wedging parameter describe aquifers with increasing thickness towards land and negative values describe aquifers with a decreasing thickness in the inland direction. The comparison of the new solution and the solution for a finite aquifer with constant thickness indicates that the sign of the wedging parameter enhances or decreases the amplitude of the tide-induced signal. However, the differences in time-lag between both solutions are negligible near the coast. The slope factor, which quantifies the inconsistencies between aquifer diffusivities estimated from attenuation and time-lag data, is computed and analysed. Near the coast, slope factor values greater than one are obtained for negative wedging parameters while slope factor values less than one are obtained for positive wedging parameters. The analysis of the new solution also indicates that more reliable estimates of the hydraulic diffusivity can be obtained from time-lag data.     

“Low-State” Black Hole Accretion in Nearby Galaxies

I summarize the main observational properties of low-luminosity AGNs in nearby galaxies to argue that they are the high-mass analogs of black hole X-ray binaries in the “low/hard” state. The principal characteristics of low-state AGNs can be accommodated with a scenario in which the central engine is comprised of three components: an optically thick, geometrically accretion disk with a truncated inner radius, a radiatively inefficient flow, and a compact jet.     

The unusual supernova 1987A

V andB light curves for supernova 1987A covering some 120 days from the outburst are here presented and discussed; they are shown to be rather atypical for a type II supernova. The absolute magnitude at maximum brightness is also analyzed, and after applying a correction for interstellar absorption we obtainM _{V, max, 0} =–16.1, andM _{B, max, 0} =–14.7; is is then concluded that 1987A is a supernova quite fainter than average. A comparison with other known supernova is made and some similarity is found with peculiar objects such as 1948B in NGC 6946, and probably, 1909 A in M 101.Research supported in part by SECyT and CONICOR.     

Simulations of strong ground motion for earthquakes in the Mexicali–Imperial Valley region

Summary. In this paper computer modelling is used to test simple approximations for simulating strong ground motions for moderate and large earthquakes in the Mexicali–Imperial Valley region. Initially, we represent an earthquake rupture process as a series of many independent small earthquakes distributed in a somewhat random manner in both space and time along the rupture surface. By summing real seismograms for small earthquakes (used as empirical Green's functions), strong ground motions at specific sites near a fault are calculated. Alternatively, theoretical Green's functions that include frequencies up to 20 Hz are used in essentially similar simulations. The model uses random numbers to emulate some of the non-deterministic irregularities associated with real earthquakes, due either to complexities in the rupture process itself and/or strong variations in the material properties of the medium. Simulations of the 1980 June 9 Victoria, Baja California earthquake ( M _L= 6.1) approximately agree with the duration of shaking, the maximum ground acceleration, and the frequency content of strong ground motion records obtained at distances of up to 35 km for this moderate earthquake. In the initial stages of modelling we do not introduce any scaling of spectral shape with magnitude, in order to see at what stage the data require it. Surprisingly, such scaling is not critical in going from M = 4–5 events to the M = 6.1 Victoria earthquake. However, it is clearly required by the El Centro accelerogram for the Imperial Valley 1940 earthquake, which had a much higher moment ( Ms ∼ 7). We derive the spectral modification function for this event. The resulting model for this magnitude ∼ 7 earthquake is then used to predict the ground motions at short distances from the fault. Predicted peak horizontal accelerations for the M ∼ 7 event are about 25–50 per cent higher than those observed for the M = 6.1 Victoria event.