Direct Conversion of Food Waste into 3D Porous Carbon Traps for Selective Adsorption of Cationic Dyes

Conversion of waste biomass into valuable functional materials accomplishes the concept of circular economy in the development of sustainable waste management, and also recovery of such resources possibly reduces the requirement of feedstocks. In this scenario, the development of methodologies toward the direct conversion of the raw biomass into solid adsorbent materials without the use of any templates is highly desirable, but exceptionally challenging due to the complexity of the process. Here the direct synthesis of 3D porous carbon traps by a simple, cost-effective, and template-free process starting from a kitchen-based recipe and fermented food waste is described. Precisely, a robust carbon trap is formed with a spongy structure and highly interconnected hierarchical pores after the pyrolysis of a rice-based foam in the air. The developed materials float on water and interact efficiently with cationic dyes at static conditions. Importantly, such performance of the 3D carbon traps is not affected in the presence of anionic dyes, indicating the excellent selectivity towards the adsorption of cationic dyes. The adsorbent can be easily recovered and reused for up to 3 cycles without releasing any byproducts, thus, without causing hazardous risk of any secondary pollution to the environment.     

Comparative study of As,Cd, Cu,Cr, Mg,Mn, Ni,Pb and Zn concentrations between sediment and water from estuary and port

The contents of As, Cd, Cu, Cr, Mg, Mn, Ni, Pb and Zn have been determined in sediment and water samples from Valle de las Garzas estuary and Port Manzanillo (Colima, Mexico) using ICP-AES. The concentrations of these elements were used for a comparative study to determine the distribution of heavy metals and to evaluate which elements reflect natural or anthropogenic backgrounds. For this purpose, seven sampling points were selected: Four of them correspond to the lagoon, and three were situated in the port. Statistical analysis of the mineral content was assessed. Initially, data comparison was assessed by statistical tests for each variable. Principal component analysis was then applied considering the influence of all variables at the same time by obtaining the distribution of samples according to their scores in the principal component space. In this way, four studies were carried out: (1) study of sediments collected during the dry season; (2) study of sediments collected during the rainy season; (3) comparative study between sediments from rainy and dry season; and (4) study of water composition collected during rainy season. From the results of the performed analyses, it can be concluded that metals distribution pattern reflected natural and anthropogenic backgrounds (e.g., sediments from the lagoon, situated at the beginning of the rain channel, presented high contents of Zn and Cu, perhaps related to anthropogenic activities or the influence of igneous sediments).     

Pesticides Removal by Filtration over Cactus Pear Leaves: A Cheap and Natural Method for Small‐Scale Water Purification in Semi‐Arid Regions

This study aims to examine the efficiency of Opuntia ficus‐indica for removing organochlorine pesticides from surface waters. Adsorption properties such as size, dose, and time of O. ficus‐indica for aldrin, dieldrin, and dichlorodiphenyltrichloroethane (DDT) were studied through stirring and column methods. Because of their high affinity and swelling characteristics, dried O. ficus‐indica was studied in stirring while fresh unpeeled O. ficus‐indica was applied in both stirring and column experiments and proved to be well‐suited to column application. Before removing pesticides, the column was flashed with distilled water eliminate the turbidity and smell from fresh unpeeled cactus. The removal of pesticides increased with an increasing adsorbent dose and decreased with adsorbent particle sizes. The optimum adsorbent dose is 10 g for dried and 15 g for fresh unpeeled O. ficus‐indica. The experimental results show that O. ficus‐indica possesses strong adsorption ability for aldrin, dieldrin, and DDT, and the adsorption isotherm data obeyed the Freundlich model. The results of our small‐scale experiments suggest a strong potential to develop local small‐scale water treatment units that can be used at the level of individual households or local communities, using a widely available adsorbent.     

Environmental Radioxenon Levels in Europe: a Comprehensive Overview

Activity concentration data from ambient radioxenon measurements in ground level air, which were carried out in Europe in the framework of the International Noble Gas Experiment (INGE) in support of the development and build-up of a radioxenon monitoring network for the Comprehensive Nuclear-Test-Ban Treaty verification regime are presented and discussed. Six measurement stations provided data from 5 years of measurements performed between 2003 and 2008: Longyearbyen (Spitsbergen, Norway), Stockholm (Sweden), Dubna (Russian Federation), Schauinsland Mountain (Germany), Bruyères-le-Châtel and Marseille (both France). The noble gas systems used within the INGE are designed to continuously measure low concentrations of the four radioxenon isotopes which are most relevant for detection of nuclear explosions: ^131mXe, ^133mXe, ¹³³Xe and ¹³⁵Xe with a time resolution less than or equal to 24 h and a minimum detectable concentration of ¹³³Xe less than 1 mBq/m³. This European cluster of six stations is particularly interesting because it is highly influenced by a high density of nuclear power reactors and some radiopharmaceutical production facilities. The activity concentrations at the European INGE stations are studied to characterise the influence of civilian releases, to be able to distinguish them from possible nuclear explosions. It was found that the mean activity concentration of the most frequently detected isotope, ¹³³Xe, was 5–20 mBq/m³ within Central Europe where most nuclear installations are situated (Bruyères-le-Châtel and Schauinsland), 1.4–2.4 mBq/m³ just outside that region (Stockholm, Dubna and Marseille) and 0.2 mBq/m³ in the remote polar station of Spitsbergen. No seasonal trends could be observed from the data. Two interesting events have been examined and their source regions have been identified using atmospheric backtracking methods that deploy Lagrangian particle dispersion modelling and inversion techniques. The results are consistent with known releases of a radiopharmaceutical facility.     

The continental record of Ediacaran volcano‐sedimentary successions in southern Brazil and their global implications

The Ediacaran is one of the most important periods on Earth evolution, including the first appearance of soft‐bodied macrofossils, major climatic changes and a supposed rise in free oxygen. In southernmost Brazil, this period is represented by Camaquã Supergroup, including the Bom Jardim Group and the Acampamento Velho Formation, both of which record continental palaeoenvironmental changes in a more than 5000 m thick stratigraphic succession. Age constraints are given by seven Ar‐Ar and U‐Pb determinations on volcanic rocks, which bracket these units between c. 605 and 574 Ma, revealing the best dated and most continuous documented Ediacaran continental succession to date. Depositional systems evolution supports a Phanerozoic‐type glacial context during the last Neoproterozoic glacial event and presents the Picada das Graças Formation (580 ± 3.6 Ma) as the first dated non‐glacial unit coeval to the Gaskiers Formation.     

Accumulation,solid partitioning and remobilisation of 99Tc in subtidal and intertidal sediments in the Irish Sea

Recent studies have shown that accumulation of ⁹⁹Tc in seabed sediments labelled by authorised radioactive liquid discharges into the NE Irish Sea from the Sellafield reprocessing complex is greater than previously thought. In this paper, new data on ⁹⁹Tc concentration profiles in subtidal and intertidal sediments from the eastern and western Irish Sea are provided with a view to elucidating the processes responsible for the incorporation and retention of ⁹⁹Tc in the seabed. The data show that substantial amounts of ⁹⁹Tc have accumulated in the fine-grained subtidal sediments off the Cumbrian coast, particularly after increased releases from Sellafield following the commissioning of the Enhanced Actinide Removal Plant (EARP) in 1994. In all the cores taken in this area, ⁹⁹Tc has been found to be present to depths in excess of 30 cm. Analysis of ¹³⁷Cs and ²⁴¹Am profiles, together with other supporting geochemical data, show a high degree of homogenisation of the sediments down to these depths as a result of physical and biological processes, and confirm that incorporation of ⁹⁹Tc into the sediment compartment is actually the result of mixing and reworking, rather than active sediment accumulation. In contrast, active deposition of material transported from this mixed pool of sediment appears to be the dominant mechanism controlling ⁹⁹Tc profiles in intertidal areas close to the Sellafield discharge outfall.Data obtained from the analysis of subtidal sediment cores from the western Irish Sea mud basin suggest that similar mixing processes to those occurring in the subtidal sediments of the eastern Irish Sea are also active in this area. Time-series data on ⁹⁹Tc concentrations in surficial sediments from this basin, gathered in the period 1988–2004, inclusive, show a clear increase in concentrations, by a factor of ～2, between samples collected pre-EARP and post-EARP. The constancy of ⁹⁹Tc concentrations in surface sediments throughout the 1980s and the early-1990s suggests that little redissolution and export of ⁹⁹Tc occurred over this extended period. A similar observation applies to the post-EARP period, when concentrations remained relatively constant despite the reported steady decrease in ⁹⁹Tc concentrations in the overlying waters.This apparent lack of remobilisation is consistent with data from sequential extraction analyses, which indicate that the bulk of the ⁹⁹Tc is strongly bound to non-labile geochemical phases, with only a small proportion associated with exchangeable and acido-soluble phases. Further, these analyses show that ⁹⁹Tc is not associated with oxygen-sensitive and highly-reactive acid-volatile sulphides (AVS) to any significant extent.     

Pliocene extensional tectonics in the Eastern Central Patagonian Cordillera: geochronological constraints and new field evidence

Recent field work and review of radiometric data obtained from Neogene lavas and plutonic rocks exposed in the Eastern Central Patagonian Cordillera (46–48ºS), which overlie subducted segments of the South Chile Ridge, suggest important Late Miocene to Pleistocene morphological changes in relation to base level variations and/or tectonic events. We present new field observations from a region south of Lago General Carrera‐Buenos Aires, between the main Cordillera and the Meseta del Lago Buenos Aires, demonstrating that normal faulting controlled valley incisions and occurred during lava emplacement at 5–4 Ma and after 3 Ma. We also show that the 12 Ma basaltic flows of the Meseta del Lago Buenos Aires (∼2000 m a.s.l.) have been subjected to deep incision, with younger lavas dated at 1.2 Ma partially filling the valleys. These incisions are thought to reflect progressive eastward tilting of the entire meseta. Our new observations, together with additional features from Central Patagonia, strongly suggest that tectonic events led to a regional widespread morphological change after 5 Ma. The coincidence in time and space between the subduction of segments of the South Chile Ridge at 6 and 3 Ma causing opening of a slab window, and strong base level variations in the studied area, suggests a cause‐and‐effect relationship. In Central Patagonia, compressional tectonics ended well before extensional events reported here. Causes of uplift and further extension are probably completely disconnected. The uplift is purely tectonic in origin and occurred prior to the subduction of the South Chile Ridge. Extension should be a consequence of this subduction.     

On the sublimation of ice particles on the surface of Mars; with applications to the 2007/8 Phoenix Scout mission

Experimental studies related to the sublimation of ice, in bulk or as small particles, alone or mixed with dust similar to that expected on the surface of Mars, are reported. The experiments, a cloud physics particle sublimation model, and a convection model presented by Ingersoll, all indicate a strong dependence of sublimation rate on temperature, and this appears to be the dominant factor, assuming that the relative humidity of the air is fairly low. In addition the rate of loss of water vapour appears to depend primarily on exposed surface area and less on particle size and the total mass of the sample, or the mass of ice in the sample. The 2007/8 Phoenix Scout mission plans to obtain and analyse samples of sub-surface ice from about 70° N on Mars. A concern is that these samples, in the form of ice chips of size about 1 mm diameter, could be prone to sublimation when exposed for prolonged periods (many hours) to a relatively warm and dry atmosphere. Our laboratory simulations confirm that this could be a problem if particles are simply left lying on the surface, but also indicate that samples kept suitably cold and collected together in confined piles will survive long enough for the collection and delivery (to the analysis instruments) procedure to be completed.     

Carbon isotopes and iodine concentrations in a Mississippi River delta core recording land use, sediment transport, and dam building in the river's drainage basin

Sedimentary material from coastal and nearshore areas in the Mississippi Delta region are comprised of different organic carbon sources with diverse ages that require isotopic and elemental records for resolving the various sources of plant residues. Carbon isotopic ((13)C, (14)C) values were used to differentiate contributions from plants using the C3, C4, and/or CAM (crassulacean acid metabolism) carbon fixation pathways., and iodine concentrations indicated that wetland plant residues are a significant source of organic carbon in a sediment core from the Mississippi River delta region collected at a 60 m water depth. This sediment core had been extensively described in Oktay et al. [Oktay, S.D., Santschi, P.H., Moran, J.E., Sharma, P., 2000. The (129)Iodine Bomb Pulse Recorded in Mississippi River delta Sediments: Results from Isotopes of I, Pu, Cs, Pb, and C. Geochim. Cosmochim. Acta 64 (6), 989-996.] and significantly, includes unique features that had not previously been seen in the marine environment. These special features include a plutonium isotopic close-in fallout record that indicates a purely terrestrial source for these sediment particles and the elements associated with it, and a distinct iodine isotopic peak (as well as peaks for plutonium and cesium isotopes) that indicate little bioturbation in this core. Our carbon isotopic and iodine data can thus be compared to published records of changes in drainage basin land use, river hydrology, and hydrodynamic sorting of suspended particles to elucidate if these changes are reflected in nearshore sediments. This comparison suggests a significant contribution for organic carbon (OC) from C4 plants to these sediments during the 1950's to early 1960's. Relative older carbon isotopes, and episodically high iodine concentrations (up to 34 ppm) were observed during this time period that (1) indicate sediment deposition that is coincident with the times of major hydrological changes induced from dam and levee building in both the upper and lower reaches of the Mississippi River drainage basin, and (2) suggest episodic organic carbon deposition from wetland plant residues.