Carbon stable isotopes in estuarine sediments and their utility as migration markers for nursery studies in the Firth of Forth and Forth Estuary, Scotland

The stable carbon isotope ratios (δ¹³C) of the organic fraction of intertidal sediments in the Forth Estuary and the Firth of Forth, Scotland, were measured to determine if terrestrially derived carbon was present in the estuarine sediments. It was hypothesised that differences in the inputs from marine vs. terrestrial sources to the organic carbon of estuarine and marine sediments, as well as differences in ambient seawater stable oxygen isotope (δ¹⁸O) ratios between the estuary and the Outer Firth, would allow the use of these two stable isotopes as habitat markers for juvenile plaice (Pleuronectes platessa), to allow determination of nursery habitats. Muddy and sandy sediments from the estuary and sandy sediments from the Outer Firth were sampled and δ¹³C measured. Juvenile plaice were caught at two estuarine sites and at two Outer Firth sites and otoliths were removed for δ¹³C and δ¹⁸O analysis. The sandy sediments in the estuary showed a strong gradient of δ¹³C enrichment with distance down the estuary, while the muddy sediments showed a much shallower gradient. δ¹³C and δ¹⁸O measured in the carbonate of juvenile plaice otoliths showed no clear difference between otoliths of fish caught at one of the estuarine sites and at the two Outer Firth sites. However, the isotope ratios of both carbon and oxygen in plaice otoliths from the other estuarine site showed the expected trend of depletion in the heavier isotopes. While the measurements recorded here did not conclusively distinguish between otoliths from juveniles caught in the estuarine site and those caught in the other three sites, they show that stable isotopes have potential to distinguish between estuarine habitats with terrestrial carbon inputs, and coastal marine habitats with predominantly marine carbon inputs.     

Nature and role of CO2 in some hot and cold HCO3/Na/CO2-rich Portuguese mineral waters: a review and reinterpretation

 At the northern part of the Portuguese mainland, the upflow zone of several hot and cold HCO₃/Na/CO₂-rich mineral waters is mainly associated with important NNE–SSW faults. Several geochemical studies have been carried out on thermal and non-thermal hydromineral manifestations that occur along or near these long tectonic alignments. The slight chemical differences that exist between these meteoric hot and cold HCO₃/Na/CO₂-rich mineral waters seem to be mainly caused by CO₂. δ¹³C_(TIDC) values observed in these groundwaters range between –6.00 and –1.00‰ versus V-PDB (V denotes Vienna, the site of the International Atomic Energy Agency; PDB originates from the CaCO₃ of the rostrum of a Cretaceous belemnite, Belemnitella americana, collected in the Peedee formation of South Carolina, USA) indicating a deep-seated (mantle) origin for most of the CO₂. Nevertheless, in the case of the heavier δ¹³C_(TIDC) values, the contribution of metamorphic CO₂ or the dissolution of carbonate rock levels at depth cannot be excluded. Concerning the hot waters, the lack of a positive ¹⁸O-shift should be attributed to water-rock interaction in a low temperature environment, rather than to the isotopic influence of CO₂ on the δ¹⁸O-value of the waters. Received: 9 August 1999 · Accepted: 8 March 2000     

Sequence stratigraphy of Holocene incised-valley fills and coastal evolution in the Gulf of Cádiz (southern Spain)

This first sedimentary interpretation of two incised-valley fills in the Gulf of Cádiz (southern Spain), which accumulated during the last fourth-order eustatic cycle in response to fluvial incision, changes of sea level, and correlative deposition, relates the filling of the estuarine basins and their barriers with four regional progradation phases, H₁ to H₄. The cases studied are the wave-dominated Guadalete, and the mixed, tide and wave-dominated Odiel-Tinto estuaries. The sequence boundary is a type-1 surface produced during the lowstand of the Last Glacial period ca. 18 000 ¹⁴C yr BP. No fluvial lowstand deposits were found in the area. Due to rapid transgression the valley fills consist of transgressive and highstand sediments. The maximum landward advance of the estuarine barriers occurred ca. 6500–6000 ¹⁴C yr BP during the maximum of the Flandrian transgression, but there is no evidence of sea level rising appreciably above the present. A large part of the estuaries was filled during H₁ (ca. 6500–4400 ¹⁴C yr BP) but ravinement by shifting tidal inlets destroyed most of the coeval barriers. During the H₂ phase (ca. 4200–2550 ¹⁴C yr BP) sedimentation was favoured by arid conditions and concentrated in the axial estuarine zones and the barriers. Between H₂ and H₃ prevailing winds changed from W to WSW, increasing spit growth to the east and south-east. Progradation of bay-head deltas and flood-plains during H₃ (ca. 2300–800 ¹⁴C yr BP) and H₄ (500 yr ago to the present) further reduced the accommodation space in the largely-filled valleys, and sediment by-passed the estuaries and accumulated in the estuarine barriers as fast-growing spits. Arid conditions and increasing human activity have caused rapid coastal modifications.     

Geochemical evidence of the 8.2 ka event and other Holocene environmental changes recorded in paleolagoon sediments,southeastern Brazil

The paleoclimatic record of Juréia Paleolagoon, coastal southeastern Brazil, includes cyclic and gradual changes with different intensities and frequencies through geological time, and it is controlled by astronomical, geophysical, and geological phenomena. These variations are not due to one single cause, but they result from the interaction of several factors, which act at different temporal and spatial scales. Here, we describe paleoenvironmental evidence regarding climatic and sea level changes from the last 9400 cal yr BP at the Juréia Paleolagoon — one of the main groups of protected South Atlantic ecosystems. Geochemical evidences were used to identify anomalies from multi-proxy analyses of a paleolagoon sediment core. The anomalies of centennial scale were correlated to climate and transgression–regression cycles from the Holocene period. Decadal scale anomalous oscillations in the Quaternary paleolagoon sediments occur between 9400 and 7500 cal yr BP, correlated with long- and short-term natural events, which generated high sedimentation rates, mainly between 8385 and 8375 cal yr BP (10 cm/yr). Our results suggest that a modern-day short-duration North Atlantic climatic event, such as the 8.2 ka event, could affect the environmental equilibrium in South America and intensify the South American Summer Monsoon.     

A mass‐balance approach to estimate in‐stream processes in a large river

A mass‐balance approach was used to estimate in‐stream processes related to inorganic nitrogen species (NH₄⁺, NO₂^? and NO₃^?) in a large river characterized by highly variable hydrological conditions, the Garonne River (south‐west France). Studies were conducted in two consecutive reaches of 30 km located downstream of the Toulouse agglomeration (population 760 000, seventh order), impacted by modification of discharge regime and high nitrogen concentrations. The mass‐balance was calculated by two methods: the first is based on a variable residence time (VRT) simulated by a one‐dimensional (1‐D) hydraulic model; the second is a based on a calculation using constant residence time (CRT) evaluated according to hydrographic peaks. In the context of the study, removal of dissolved inorganic nitrogen (DIN) for a reach of 30 km is underestimated by 11% with the CRT method. In sub‐reaches, the discrepancy between the two methods led to a 50% overestimation of DIN removal in the upper reach (13 km) and a 43% underestimation in the lower reach (17 km) using the CRT method. The study highlights the importance of residence time determination when using modelling approaches in the assessment of whole stream processes in short‐duration mass‐balance for a large river under variable hydrological conditions. Copyright © 2007 John Wiley & Sons, Ltd.     

Phénomènes karstiques fossiles et actuels au sein des formations métamorphiques silico-alumineuses de la nappe pan-africaine de Yaoundé (Sud-Cameroun)Fossil and present-time karstic phenomena in silico-aluminous metamorphic formations of the Pan-African nappe of Yaoundé (South-Cameroon)

Numerous karstic features have been recognised in the non-carbonaceous micaschists and gneisses of the Yaoundé Pan-African nappe, south of Cameroon. It is shown that their formation was controlled by the structural features of the rocks. The wells and the pipes in the bedrock outcrops point out a current karstification process, resulting from the plagioclase dissolution by the acid rain waters. Hill wall alveoli and caves, of pre-Miocene age, are exhumed features that were done by dissolution in the aquiferous underground. To cite this article: J.-P. Vicat et al., C. R. Geoscience 334 (2002) 545–550.     

Terrestrial photogrammetric techniques applied to the control of a parabolic dune in the Liencres dune system,Cantabria (Spain)

The spatial–temporal variations of a dune system can be determined by using diverse ‘geomatic’ methodologies: geodesy, global positioning system (GPS) and photogrammetry. In the case of the Liencres dune system, a study will be carried out using the ‘close‐range’ photogrammetry technique and the topography technique (total station and GPS). In order to determine the dynamic of the dune system it is necessary to repeat the process of study after a specific interval of time. For this reason, three dimensional data should be available in two different time periods, between which the displacement of the object of analysis (the front portion of the dune) will be significant enough to evaluate its magnitude. This work analyses the viability of photogrammetry for the determination of the spatial–temporal changes of a coastal parabolic dune. Two factors have been analysed: first, the comparison of the photogrammetric results with the results obtained from topographic methods (total station and GPS), and second, the quantification of the displacement of the dune system. The analysis of the correspondence between the movement of different parts of the dune and the influence of the intensity and direction of the prevailing wind in the area is also desired. The dune advanced 12·15 ± 0·06 m (an average of 8·5 m/yr), and the partial implications for the dynamic of human modified processes on the natural park have been established. Copyright © 2008 John Wiley & Sons, Ltd.     

Multi‐temporal Mapping of Burned Forest over Canada Using Satellite‐based Change Metrics

Abstract

A procedure for continental‐scale mapping of burned boreal forest at 10‐day intervals was developed for application to coarse resolution satellite imagery. The basis of the technique is a multiple logistic regression model parameterized using 1998 SPOT‐4 VEGETATION clear‐sky composites and training sites selected across Canada. Predictor features consisted of multi‐temporal change metrics based on reflectance and two vegetation indices, which were normalized to the trajectory of background vegetation to account for phenological variation. Spatial‐contextual tests applied to the logistic model output were developed to remove noise and increase the sensitivity of detection. The procedure was applied over Canada for the 1998‐2000 fire seasons and validated using fire surveys and burned area statistics from forest fire management agencies. The area of falsely mapped burns was found to be small (3.5% commission error over Canada), and most burns larger than 10 km2 were accurately detected and mapped (R² = 0.90, P<0.005, n = 91 for burns in two provinces). Canada‐wide satellite burned area was similar, but consistently smaller by comparison to statistics compiled by the Canadian Interagency Forest Fire Centre (by 17% in 1998, 16% in 1999, and 3% in 2000).     

Radiative Feedbacks and Monsoon Circulations: A View from Simplified Models

The modulation of radiative processes by changes in water vapor and cloudiness is at the origin of important feedbacks which control climate variability as well as climate changes. These feedbacks are especially active in the intertropical area, where it is possible to diagnose a combination of partially compensating positive and negative feedbacks. The characteristics and the strength of those feedbacks is closely associated with the dynamical regimes in which they develop. Reverse changes in dynamical patterns may cause a modulation of the radiative processes. A first approach to these problems is to distinguish between two ascending and subsiding circulation patterns. This bimodality of the circulation is well established in the tropical area, and favors the use of simplified models as an appropriate tool to carry out a first-order quantification of these processes. In particular, this combination of radiative and dynamical feedbacks characterizes the development of the monsoons and their variability. Simple conceptual models can thus serve to characterize some of the factors which will affect the intraseasonal variations of the monsoon.     

Structural complexity in space–time seismic event data

Different approaches and tools have been adopted for the analysis and characterization of regional seismicity based on spatio–temporal series of event occurrences. Two main aspects of interest in this context concern scaling properties and dimensional interaction. This paper is focused on the statistical use of information-theoretic concepts and measures in the analysis of structural complexity of seismic distributional patterns. First, contextual significance is motivated, and preliminary elements related to informational entropy, complexity and multifractal analysis are introduced. Next, several technical and methodological extensions are proposed. Specifically, limiting behaviour of some complexity measures in connection with generalized dimensions is established, justifying a concept of multifractal complexity. Under scaling behaviour, a mutual-information-related dependence coefficient for assessing spatio–temporal interaction is defined in terms of generalized dimensions. Also, an alternative form of generalized dimensions based on Tsallis entropy convergence rates is formulated. Further, possible incorporation of effects, such as earthquake magnitude, is achieved in terms of weighted box-counting distributions. Different aspects in relation to the above elements are analyzed and illustrated using two well-known series of seismic event data of an underlying different nature, occurred in the areas of Agrón (Granada, Spain) and El Hierro (Canary Islands, Spain). Finally, various related directions for continuing research are indicated.