Multimodal particle size distributions of fine-grained sediments: mathematical modeling and field investigation

Multimodal particle size distributions (PSDs) of fine-grained cohesive sediments are common in marine and coastal environments. The curve-fitting software in this study decomposed such multimodal PSDs into subordinate log-normal PSDs. Four modal peaks, consisting of four-level ordered structures of primary particles, flocculi, microflocs, and macroflocs, were identified and found to alternately rise and sink in a flow-varying tidal cycle due to shear-dependent flocculation. The four modal PSD could be simplified further into two discrete size groups of flocculi and flocs. This allowed the development of a two-class population balance equation (TCPBE) model with flocculi and flocs to simulate flocculation involving multimodal PSDs. The one-dimensional vertical (1-DV) TCPBE model further incorporated the Navier-Stokes equation with the k-ε turbulence closure and the sediment mass balance equations. Multimodal flocculation as well as turbulent flow and sediment transport in a flow-varying tidal cycle could be simulated well using the proposed model. The 1-DV TCPBE was concluded to be the simplest model that is capable of simulating multimodal flocculation in the turbulent flow field of marine and coastal zones.     

Genetic Environment of the Intrusion-related Yuryang Au-Te Deposit in the Cheonan Metallogenic Province, Korea

Abstract. The Yuryang gold deposit, comprising a Te‐bearing Au‐Ag vein mineralization, is located in the Cheonan area of the Republic of Korea. The deposit is hosted in Precambrian gneiss and closely related to pegmatite. The mineralized veins display massive quartz textures, with weak alteration adjacent to the veins. The ore mineralization is simple, with a low Ag/Au ratio of 1.5:1, due to the paucity of Ag‐phases. Ore mineralization took place in two different mineral assemblages with paragenetic time; early Fe‐sulfide mineralization and late Fe‐sulfide and Au‐Te mineralization. The early Fe‐sulfide mineralization (pyrite + sphalerite) occurred typically along the vein margins, and the subsequent Au‐Te mineralization is characterized by fracture fillings of galena, sphalerite, pyrrhotite, Te‐bearing minerals (petzite, altaite, hessite and Bi‐Te mineral) and electrum. Fluid inclusions characteristically contain CO₂ and can be classified into four types (Ia, Ib, IIa and IIb) according to the phase behavior. The pressure corrected temperatures (≥500d?C) indicate that the deposit was formed at a distinctively high temperature from fluids with moderate to low salinity (<12 wt% equiv. NaCl) and CH₄ (1?22 mole %). The sphalerite geo‐barometry yield an estimated pressure about 3.5 ?2.1 kbar. The dominant ore‐deposition mechanisms were CO₂ effervescence and concomitant H₂S volatilization, which triggered sulfidation and gold mineralization. The measured and calculated isotopic compositions of fluids (δ¹⁸O_H2^O = 10.3 to 12.4 %o; δD_H2^O = ‐52 to ‐77 %o) may indicate that the gold deposition originated from S‐type magmatic waters. The physicochemical conditions observed in the Yuryang gold deposit indicate that the Jurassic gold deposits in the Cheonan area, including the Yuryang gold deposit are compatible with deposition of the intrusion‐related Au‐Te veins from deeply sourced fluids generated by the late Jurassic Daebo magmatism.     

Numerical models and ductile ultimate deformation response of post‐tensioned self‐centering moment connections

New steel moment‐resisting connections that incorporate post‐tensioning elements to provide a self‐centering capacity and devices to dissipate seismic input energy have recently been proposed and experimentally validated. Experimental studies have confirmed that these connections are capable of undergoing large lateral deformations with negligible residual drifts. To facilitate their implementation, accurate modeling of the behavior of systems incorporating post‐tensioned connections must be readily available to designers and researchers. A number of simplified models have been suggested in the literature by researchers trying to capture experimental results at the beam–column connections and thereby to predict the global response of structures incorporating such connections. To provide a clear set of guidelines for the modeling of post‐tensioned steel frames, for practicing engineers as well as researchers, in this paper three types of numerical models of increasing complexity are presented: (i) a sectional analysis procedure, (ii) a lumped plasticity spring frame leveled approach and (iii) a non‐linear solid finite element analysis to predict the response at ultimate deformation levels. The analytical results obtained from the numerical models predict well the structural behavior of these connections when compared with available experimental data. Even at the ultimate deformation level, analytical results are in good agreement with test results. Furthermore, detailing requirements are proposed to assure that flexural hinges form in the beams in order to improve the cyclic response of steel self‐centering connections when drifts exceeding the design drifts are imposed to the system. Experimental and analytical studies demonstrate that steel post‐tensioned self‐centering connections incorporating the proposed detailing in the beams develop an increased deformation capacity and thereby exhibit a ductile response while avoiding a sudden loss of their strength and stiffness. Copyright © 2008 John Wiley & Sons, Ltd.     

Three-dimensional inversion of magnetotelluric data including sea effects obtained in Pohang, Korea

Magnetotelluric (MT) surveys were conducted in Pohang, Korea, for low-temperature geothermal exploration in 2002 and 2003. Pohang is located in the southeastern part of the Korean Peninsula and close to the East Sea. In the interpretation of MT data from a coastal environment, sea effects must be correctly included because seawater is a strong conductor. We first constructed a five-layered earth model with a realistic coastline and bathymetry to investigate sea effects on MT data measured in Pohang. This model clearly shows that the Pohang data are significantly influenced by sea water at frequencies blow 1 Hz at the whole measurement sites. Next, we utilized a three-dimensional inversion algorithm based on the Gauss–Newton approach to produce a reliable resistivity model. Seawater is excluded from the inversion domain to fix the resistivity, while included in the modeling domain to simulate sea effects on MT responses. Blocks for the sub-seafloor are included in unknown parameters since they are sufficiently close to the survey area to affect MT responses in Pohang. Static shifts are also considered in inversion for more accurate interpretation. The rms data misfit is smoothly reduced from 11.2 to 1.87 after 7 iterations. The resulting resistivity model shows a pattern of low–high–low resistivity with depth. The model is compatible with resistivity logs obtained from four boreholes in the survey area, and can explain major geological features in Pohang.     

Polychlorinated biphenyls (PCBs) in a benthic ecosystem in Gwangyang Bay, South Korea

Benthic ecosystem in Gwangyang Bay, a fast developing industrial area with steel production, port container handling, petroleum and other chemical processing in South Korea was studied. The average levels of polychlorinated biphenyls (ΣPCB) in the benthic components were: seawater 2.99 ± 0.13 (ng/L); sediment 294 ± 118 (ng/g TOC); [biota=ng/g lipid] starfish 92; prawn 131 ± 2; mussels 127 ± 22; crab 182 ± 114; clam 187; polychaeta 215; sea cucumber 497 ± 90; squill 603 ± 38; fish 396 ± 159. Levels in the inner bay samples were higher than the outer bay samples suggesting land based pollution. Good correlation (r(2)=0.79; p<0.05) existed between PCB concentration and lipid content indicating partitioning processes in action. PCB signature in the abiotic and biotic components shows enrichment of lower chlorinated congeners emitted by a unique source nearby, viz. steel manufacturing plant.     

Estimation of asymptotic variances of quantiles for the generalized logistic distribution

In this study, the parameter estimations for the 3-parameter generalized logistic (GL) distribution are presented based on the methods of moments (MOM), maximum likelihood (ML), and probability weighted moments (PWM). The asymptotic variances of the MOM, ML, and PWM quantile estimators for the GL distribution are expressed as functions of the sample size, return period, and parameters. A Monte Carlo simulation was performed to verify the derived expressions for variances and covariances between parameters and to evaluate the applicability of the derived asymptotic variances of quantiles for the MOM, ML and PWM methods. The simulation results generally show good agreement with the analytical results estimated from the asymptotic variances of parameters and quantiles when the shape parameter (β) of the GL distribution is between −0.10 and 0.10 for the MOM method and between −0.25 and 0.45 for the ML and PWM methods, respectively. In addition, the actual sample variances and the root mean square error (RMSE) of asymptotic variances of quantiles for various sample sizes, return periods, and shape parameters were presented. In order to evaluate the applicability of the estimation methods to real data and to compare the values of estimated parameter, quantiles, and confidence intervals based on each parameter estimation method, the GL distribution was fitted to the 24-h annual maximum rainfall data at Pohang, Korea.     

Origin of Mesozoic gold mineralization in South Korea

Abstract   The Mesozoic gold–silver deposits in South Korea are closely associated with the Mesozoic granitoids. The Jurassic gold–silver deposits can be distinguished from the Cretaceous ones in terms of occurrence, alteration style, gold fineness, associated mineral assemblage, fluid inclusion and stable isotopic compositions. The Jurassic deposits were formed in mesozonal environments related to deep-seated granitoids, whereas the Cretaceous ones were formed in epizonal environments related to shallow-level granitoids. The Jurassic auriferous deposits (about 165–145 Ma) show fluid characteristics typical of an orogenic-type gold deposit, and were probably generated in a compressional regime caused by an orthogonal convergence of the Izanagi oceanic plate into the Asiatic margin. However, strike-slip faults and caldera-related fractures, together with subvolcanic to volcanic activity, may have played an important role in the formation of Cretaceous gold–silver lode deposits (about 110–45 Ma) under a continental arc setting.     

3D magnetotelluric modelling including surface topography

An edge finite‐element method has been applied to compute magnetotelluric (MT) responses to three‐dimensional (3D) earth topography. The finite‐element algorithm uses a single edge shape function at each edge of hexahedral elements, guaranteeing the continuity of the tangential electric field while conserving the continuity of magnetic flux at boundaries. We solve the resulting system of equations using the biconjugate gradient method with a Jacobian preconditioner. The solution gives electric fields parallel to the slope of a surface relief that is often encountered in MT surveys. The algorithm is successfully verified by comparison with other numerical solutions for a 3D‐2 model for comparison of modelling methods for EM induction and a ridge model. We use a 3D trapezoidal‐hill model to investigate 3D topographic effects, which are caused mainly by galvanic effects, not only in the Zxy mode but also in the Zyx mode. If a 3D topography were approximated by a two‐dimensional topography therefore errors occurring in the transverse electric mode would be more serious than those in the transverse magnetic mode.     

Biomarker responses in pelagic and benthic fish over 1 year following the Hebei Spirit oil spill (Taean, Korea)

After the Hebei Spirit oil spill incident (7th December, 2007) in the west coast of Korea, contamination of biliary PAH metabolite and hepatic biomarkers in a pelagic and a benthic fish was monitored for 1 year. Concentrations of 16 PAHs and alkylated PAHs in fish muscle were highest (22.0 ng/g d.w. for 16 PAHs and 284 ng/g d.w. for alkylated PAHs) at 5 days after the spill and then decreased rapidly to background levels at 11 months after the spill. Fish from the oiled site had elevated biliary PAH metabolite concentrations immediately after the spill; these declined steadily in both species, but were still above reference site concentrations 2 months after the spill. Oiled-site fish showed hepatic CYP 1A induction whose trend closely followed those of biliary PAH metabolite concentrations, implying continuous exposure to PAHs. Brain acetylcholinesterase activity was not related to oil exposure.     

Biomarker responses in caged rockfish (Sebastes schlegeli) from Masan Bay and Haegeumgang, South Korea

The purpose of this study was to compare enzymatic biomarker activities in fish caged at two sites, Masan Bay (contaminated) and Haeguemgang (reference). In the present study, ethoxyresorufin O-deethylase (EROD), brain acetyl cholinesterase (bAChE), muscle acetyl cholinesterase (mAChE) and butyryl cholinesterase (mBChE) in caged rockfish (Sebastes schlegeli) were measured 0, 1, 3, 7, 14, 21 and 30 days after caging. The level of CYP1A mRNA and Protein expression was induced higher in Masan Bay at 1, 3, 7, 14 and 30 days after caging. EROD activity in the caged fish was significantly higher in Masan Bay than in Haeguemgang 3 and 7 days after caging, but not at 14 and 30 days after caging. bAChE activity was significantly inhibited at 7 and 14 days after caging in Masan Bay. However, mBChE activity was not significantly inhibited during the experiment. Taken together, the data suggest that the caged fish were exposed, at least transiently, to CYP1A inducers and ChE inhibitors, which is consistent with our previous observations.