Potentiometric and F nuclear magnetic resonance spectroscopic study of fluoride substitution in the GaAl12 polyoxocation: implications for aluminum (hydr)oxide mineral surfaces

Fluoride replacement of oxygens in the GaO₄Al₁₂(OH)₂₄(H₂O)127+(aq) molecule [GaAl₁₂] was studied via ¹⁹F nuclear magnetic resonance (NMR) at 4 < pH < 5 and 278 K in order to elucidate similar reactions at the surfaces of clays. Peaks are identified in the ¹⁹F-NMR spectra that correspond to both terminal and bridging fluorides on the GaAl₁₂ molecule, with relative peak positions similar to those previously identified in fluoridated aluminum (hydr)oxide mineral surfaces (Nordin, J. P., Sullivan, D. J., Phillips, B. L., and Casey, W. H. [1999], “Mechanisms for fluoride-promoted dissolution of bayerite [β-Al(OH)₃(s)] and boehmite [γ-AlOOH(s)]-¹⁹F-NMR spectroscopy and aqueous surface chemistry,” Geochim. Cosmochim. Acta63, 3513-3524). Fluoride substitutes for oxygen at three different sites in the GaAl₁₂ molecule, but at dramatically different rates.The kinetics of fluoride substitution follow a rate law that includes parallel and reversible transfer of fluoride from nonbridging sites to the two bridging sites. The essential features of the rate law are as follows: (1) fluoride replaces bound water molecules (η-OH₂) within minutes at 278 K at rates that are quantitatively similar to fluoride uptake by Al(H₂O)63+(aq) to form AlF²⁺(aq) at similar conditions; (2) fluoride substitutes onto the two topologically distinct μ₂-OH sites at different rates, as was previously observed for oxygen exchange, but here, the reaction is complete in hours to days at 278 K. Most importantly, rates of fluoride substitution onto μ₂-OH sites are 10² times more rapid than the corresponding rates of oxygen exchange with bulk waters, indicating that fluoride considerably labilizes the molecule, as is also observed at the surfaces of minerals. The largest cause of this labilization is the reduced molecular charge on the GaAl₁₂ upon replacement of bound waters by fluoride, which for mineral surfaces corresponds to a reduction in surface charge density.     

Models of the dust envelope of the unique object FG Sagittae

We use JHKLM photometric data obtained in 1998–2001 to model the dust envelope of the unique object FG Sge, which formed around the star after several consecutive cycles of dust condensation beginning in Autumn 1992. Models with a spherically symmetric, extended envelope consisting of a mixture of spherical particles of amorphous carbon and silicon carbide with an MRN size distribution were fitted to match the mean observed spectral energy distributions of FG Sge during brightness maximum and minimum after 1998 for two values of the luminosity and effective temperature of the central star. The stellar-wind parameters and mass-loss rate have been estimated in each case. The observational data for the brightness maximum and minimum cannot be described by models with a fixed luminosity or fixed distance to the star. This is a consequence of the object’s unusual behavior, with synchronous flux decreases in all the observed bands. The inability of the model to adequately describe the minimum-brightness state is probably associated with the abrupt disruption of the spherical symmetry of the envelope due to the formation of a small, dense dust cloud in the line of sight.     

Spatially explicit measures of production of young alewives in Lake Michigan: Linkage between essential fish habitat and recruitment

The identification and protection of essential habitats for early life stages of fishes are necessary to sustain fish stocks. Essential fish habitat for early life stages may be defined as areas where fish densities, growth, survival, or production rates are relatively high. To identify critical habitats for young-of-year (YOY) alewives (Alosa pseud oharengus) in Lake Michigan, we integrated bioenergetics models with GIS (Geographic Information Systems) to generate spatially explicit estimates of potential population production (an index of habitat quality). These estimates were based upon YOY alewife bioenergetic growth rate potential and their salmonine predators’ consumptive demand. We compared estimates of potential population production to YOY alewife yield (an index of habitat importance). Our analysis suggested that during 1994–1995, YOY alewife habitat quality and yield varied widely throughout Lake Michigan. Spatial patterns of alewife yield were not significantly correlated to habitat quality. Various mechanisms (e.g., predator migrations, lake circulation patterns, alternative strategies) may preclude YOY alewives from concentrating in areas of high habitat quality in Lake Michigan.     

Lithospheric Tidal Effects from Observations in Deep Wells

A number of deep and superdeep wells have been drilled in Russia. The wells where all drilling activities have been finished, but the research activities still continue, are of a great scientific and practical interest for studying the present-day geological processes taking place in the Earth's interior. Vorotilovo deep well (VDW), drilled in a central part of Russian platform, is one of those wells-geolaboratories. The depth of the well is 5374 m, the temperature at the bottom is 95°C, open borehole in the range 689–5374 m.As a result of geophysical fields monitoring, the complex nature of spatio-temporal variations that depend on the influence of various natural factors was determined in the VDW.Lunar tides are one of the important factors that define the geophysical fields' variations in the VDW. The relation between temperature variations in the VDW and the tide (monthly) phase is detected. The dependence of such influence on the depth of measurement agrees with the model of 'layered' Earth where every layer has a particular response on tidal force.The continuation of the measurements, improvement of data analyses methods and extension of collaboration of specialists from different branches of science, are required in order to obtain more exact results and improve their interpretation.     

Eight new magnetic stars with large continuum depressions

Observations with the 6-m telescope revealed eight new magnetic, chemically peculiar stars: HD 29925, HD 40711, HD 115606, HD 168796, HD 178892, HD 196691, HD 209051, and BD+32°2827. Zeeman observations of all these objects have been carried out for the first time. We selected candidates by analyzing the depression profile at a wavelength of λ5200 Å. This technique for selecting candidate magnetic stars was shown to be efficient: we found magnetic fields in 14 of the 15 objects that we selected for our observations with a Zeeman analyzer. A maximum longitudinal field strength B _e exceeding 8 kG was found in HD 178892; in HD 209051 and HD196691, B _e reaches 3.3 and 2.2 kG, respectively. For the remaining stars, we obtained lower limits of the longitudinal field (more than several hundred G).     

Landslide-induced wave in a small volcanic lake: Kasu Tephra Cone,Papua New Guinea

The south crater wall of a Quaternary tephra cone in the Highlands of Papua New Guinea collapsed on 20 April 1999 and sent a 150,000-m ³ landslide into its lake. Displacing 5–10% of the lake's volume, the landslide induced a 15-m-high wave which flattened vegetation throughout the crater interior, and broke over a low saddle in the crater's east rim where it destroyed two houses and injured 11 people, killing one.     

Physical Properties of Dust in the Martian Atmosphere: Analysis of Contradictions and Possible Ways of Their Resolution

Atmospheric aerosols play an important role in forming the Martian climate. However, the basic physical properties of the Martian aerosols are still poorly known; there are many contradictions in their estimates. We present an analytical overview of the published results and potentialities of various methods. We consider mineral dust. Zonally averaged data obtained from mapping IR instruments (TES and IRTM) give the optical thickness of mineral aerosols ₉ = 0.05–0.1 in the 9-m band for quite atmospheric conditions. There is a problem of comparing these estimates with those obtained in the visible spectral range. We suggest that the commonly used ratio _vis/₉ >2 depends on the interpretation and it may actually be smaller. The ratio _vis/₉ 1 is in better agreement with the IRIS data (materials like montmorillonite). If we assume that _vis/₉ = 1 and take into account the nonspherical particle shape, then the interpretation of ground-based integrated polarimetric observations ( < 0.04) can be reconciled with IR measurements from the orbit. However, for thin layers, the sensitivity of both methods to the optical thickness is poorly understood: on the one hand, polarimetry depends on the cloud cover and, on the other hand, the interpretation of IR measurements requires that the atmospheric temperature profile and the surface temperature and emissivity be precisely known. For quite atmospheric conditions, the local optical-thickness estimates obtained by the Bouguer–Lambert–Beer method and from the sky brightness measured from Viking 1 and 2 and Mars Pathfinder landers are much larger: = 0.3–0.6. Estimates of the contrasts in images from theVikingorbiters yield the same values. Thus, there is still a factor of 3 to 10 difference between different groups of optical-thickness estimates for the quiet atmosphere. This difference is probably explained by the contribution of condensation clouds and/or by local/time variations.     

Eliminating Virtual Impactors with the Very Large Telescope: An ESO Program with the FORS2 Camera

We have used the ESO Very Large Telescope (VLT) to perform as trometric observations of Near Earth Asteroids (NEAs) having remote collision possibilities with the Earth. The observations were made for those objects which became too faint to be observed elsewhere. Using the 4 hours allocated in the semester April–September 2003, 5 faint NEAs were observed. As a result, no NEA that could impact the Earth was lost.