Mineralogy and origin of stichtite in chromite-bearing serpentinites

Stichtite, a rare (14 known localities worldwide) hydrated carbonate-hydroxide of Mg and Cr with ideal formula Mg₆Cr₂ (OH)₁₆ CO₃ · 4H₂O, occurs exclusively in Cr-rich serpentinites of ophiolites or greenstone belts. Physical properties (hardness = 1.5–2, specific gravity = 2.16–2.2, perfect basal [0001] cleavage, grain size commonly < 100 μm) resemble talc, but the mineral has an attractive purple to lilac color; chemical analyses demonstrate it to be a non-silicate. Stichtite generally occurs as irregular to rounded masses (< 1 cm – 30 cm across) and as veinlets (< 1 mm – > 2 cm wide) within serpentinite. Macroscopic and microscopic textures, such as crosscutting veinlets and stringers, demonstrate that stichtite formation invariably post-dated serpentinization. In some specimens stichtite surrounds relict grains of Cr-rich spinel; in others stichtite has completely replaced euhedral or subhedral chromites. Chemical analyses of stichtites reveal substantial substitution of Al and Fe³⁺ for Cr in specimens from many localities, reflecting a possible compositional continuum between stichtite and rhombohedral polymorphs hydrotalcite (Mg₆Al₂ (OH)₁₆ CO₃ · 4H₂O) and pyroaurite (Mg₆Fe₂ (OH)₁₆ CO₃ · 4H₂O). We report the first electron microprobe analyses of stichtites from seven localities, and summarize all available published chemical data. Stichtites very likely inherited part of their trivalent cation chemistry from precursor Cr-rich spinels, but stichtite growth apparently post-dated characteristic “ferritchromit” alteration, as demonstrated by the depletion of Al and enrichment in Fe³⁺ in stichtite relative to primary chromite core compositions. Stichtite appears to form by reaction between serpentine and altered chromite, during addition of substantial fluid, either as separate H₂O and CO₂ phases, or as a mixed volatile phase. Such reactions must involve removal of substantial SiO₂, possibly by transport and remote deposition of silica by throughgoing aqueous and carbonic fluid. Received: 4 April 1996 / Accepted: 16 September 1996     

Time-dependent, coupled, Ekman boundary layer solutions incorporating Stokes drift

Recent technological advances in current measuring devices has resulted in a large observational database related to wind-driven motions in the upper ocean mixed layer. This has served to highlight the fact that transient motions make up a substantial contribution of the resulting Ekman currents. At the same time, certain discrepancies have emerged between the observed angular deflections of the steady-state currents from the surface wind stress, both at the surface and at sub-surface depths, which cannot be reconciled using the classical Ekman model. This paper seeks to tackle these two issues.First a general analytical method is presented for solving the time dependent horizontal momentum Ekman equations. Analysis of the unsteady terms that arise from simple special cases shows how the evolution proceeds through three stages. At early times, the Coriolis acceleration is insignificant, and the current is unidirectional and deepens through downward diffusion of momentum. Later Coriolis acceleration deflects the current vectors in the upper layers, whilst downward diffusion of momentum continues to deepen the layer. Finally, once diffusion has penetrated down to the depth of the steady-state current, then the transients decay on the inertial or diffusive timescale, depending upon the boundary conditions of the particular problem.In the second half of the paper, a new steady-state model is developed that includes the effects of wind-generated waves, through the action of their Stokes drift on the planetary vorticity. Comparisons between observations and the theoretical predictions, demonstrate that inclusion of the Stokes drift is the key to reconciling the discrepancies in the angular deflections of the steady-state currents. This leads to the conclusion that Ekman layer currents are significantly influenced by the surface waves.     

Channel adjustments of the lower Trinity River,Texas, downstream of Livingston Dam

Channel cross‐sectional changes since construction of Livingston Dam and Lake Livingston in 1968 were studied in the lower Trinity River, Texas, to test theoretical models of channel adjustment, and to determine controls on the spatial extent of channel response. High and average flows were not significantly modified by the dam, but sediment transport is greatly reduced. The study is treated as an opportunistic experiment to examine the effects of a reduction in sediment supply when discharge regime is unchanged. Channel scour is evident for about 60 km downstream, and the general phenomena of incision, widening, coarsening of channel sediment and a decrease in channel slope are successfully predicted, in a qualitative sense, by standard models of channel response. However, there is no consistent channel response within this reach, as various qualitatively different combinations of increases, decreases or no change in width, depth, slope and roughness occur. These multiple modes of adjustment are predicted by the unstable hydraulic geometry model. Between about 60 km and the Trinity delta 175 km downstream of the dam, no morphological response to the dam is observed. Rather than a diminution of the dam's effects on fluvial processes, this is due to a fundamental change in controls of the fluvial system. The downstream end of the scour zone corresponds to the upstream extent of channel response to Holocene sea level rise. Beyond 60 km downstream, the Trinity River is characterized by extensive sediment storage and reduced conveyance capacity, so that even after dam construction sediment supply still exceeds transport capacity. The channel bed of much of this reach is near or below sea level, so that sea level rise and backwater effects from the estuary are more important controls on the fluvial system than upstream inputs. Copyright © 2005 John Wiley & Sons, Ltd.     

The effective number of cycles of earthquake ground motion

The seismic response of any system that accumulates damage under cyclic loading is dependent not only on the maximum amplitude of the motion but also its duration. This is explicitly recognized in methods for estimating the liquefaction potential of soil deposits. Many researchers have proposed that the effective number of cycles of the ground motion is a more robust indicator of the destructive capacity of the shaking than the duration. However, as is the case with strong‐motion duration, there is no universally accepted approach to determining the effective number of cycles of motion, and the different methods that have been proposed can give widely varying results for a particular accelerogram. Definitions of the effective number of cycles of motion are reviewed, classified and compared. Measurements are found to differ particularly for accelerograms with broad‐banded frequency content, which contain a significant number of non‐zero crossing peaks. The key seismological parameters influencing the number of cycles of motion and associated equations for predicting this quantity for future earthquakes are identified. Correlations between cycle counts and different duration measures are explored and found to be rather poor in the absence of additional parameters. Copyright © 2004 John Wiley & Sons, Ltd.     

Entropy Analysis of Multiple Scale Causality and Qualitative Causal Shifts in Spatial Systems*

Spatial systems are typically characterized by multiple controlling factors and processes operating at different spatial and temporal scales (multiple scale causality [MSC]). An entropy decomposition‐based approach to MSC is presented here in two contexts. First, given maps or distributions of an observed phenomenon at two or more scales, the contribution at more local or global (relative to the primary scale of observation) controls to the observed entropy can be estimated. Second, a theoretical treatment of the entropy decomposition equations shows that as the range of scale is increased by broadening or narrowing resolutions or by incorporating more controls, the influence of larger or smaller‐scale influences not only changes, but may change qualitatively, e.g., in terms of having positive (entropy‐increasing) or negative (information‐increasing) effects. Such qualitative causal shifts have implications for efforts to use any single causal explanation across the molecular to planetary spatial and instantaneous to geological range of scales relevant to physical geography. The entropy decomposition method is illustrated with an application to soil landscapes in the Ouachita Mountains, Arkansas.     

Devon's desert ‘worms’

Worm‐like trace fossils, sometimes of large size, have regularly been reported from the otherwise generally poorly‐fossiliferous Permo‐Triassic continental red beds of the East Devon coast, southwest England. Selected examples are discussed here to outline the difficulties involved in elucidating the true producers of these burrows and interpreting their significance in the local palaeoenvironment.     

Characterizing and classifying urban watersheds with compositional and structural attributes

Current land-use classifications used to assess urbanization effects on stream water quality date back to the 1980s when limited information was available to characterize watershed attributes that mediate non-point source pollution. With high resolution remote sensing and widely used GIS tools, there has been a vast increase in the availability and precision of geospatial data of built environments. In this study, we leverage geospatial data to expand the characterization of developed landscapes and create a typology that allows us to better understand the impact of complex developed landscapes across the rural to urban gradient. We assess the ability of the developed landscape typology to reveal patterns in stream water chemistry previously undetected by traditional land-cover based classification. We examine the distribution of land-cover, infrastructure, topography and geology across 3876 National Hydrography Dataset Plus catchments in the Piedmont region of North Carolina, USA. From this dataset, we generate metrics to evaluate the abundance, density and position of landscape features relative to streams, catchment outlets and topographic wetness metrics. While impervious surfaces are a key distinguishing feature of the urban landscape, sanitary infrastructure, population density and geology are better predictors of baseflow stream water chemistry. Unsupervised clustering was used to generate a distinct developed landscape typology based on the expanded, high-resolution landscape feature information. Using stream chemistry data from 37 developed headwater catchments, we compared the baseflow water chemistry grouped by traditional land-cover based classes of urbanization (rural, low, medium and high density) to our composition and structure-based classification (a nine-class typology). The typology based on 22 metrics of developed landscape composition and structure explained over 50% of the variation in NO₃⁻-N, TDN, DOC, Cl⁻, and Br⁻ concentration, while the ISC-based classification only significantly explained 23% of the variation in TDN. These results demonstrate the importance of infrastructure, population and geology in defining developed landscapes and improving discrete classes for water management.