Thermodynamics of selected trace elements in the Jovian atmosphere

The thermochemistry of several hundred compounds of twelve selected trace elements (Ge, Se, Ga, As, Te, Pb, Sn, Cd, Sb, Tl, In, and Bi) has been investigated for solar composition material along a Jupiter adiabat. The results indicate that AsF₃, InBr, TlI, and SbS, in addition to CO, PH₃, GeH₄, AsH₃, H₂Se, HCl, HF, and H₃BO₃ proposed by Barshay and Lewis (1978), may be potential chemical tracers of atmospheric dynamics. The reported observations of GeH₄ is interpreted on the basis of new calculations as implying rapid vertical transport from levels where T ? 800°K. Upper limits are also set on the abundances of many gaseous compounds of the elements investigated.     

Mass-radius relationships and constraints on the composition of Pluto,II

A new estimate of Pluto's mass within the range of possible masses considered in an earlier work has enabled us to refine our model of Pluto's interior.     

Numerical simulation of the final stages of terrestrial planet formation

Three representative numerical simulations of the growth of the terrestrial planets by accretion of large protoplanets are presented. The mass and relative-velocity distributions of the bodies in these simulations are free to evolve simultaneously in response to close gravitational encounters and occasional collisions between bodies. The collisions between bodies, therefore, arise in a natural way and the assumption of expressions for the relative velocity distribution and the gravitational collision cross section is unnecessary. These simulations indicate that the growth of bodies with final masses approaching those of Venus and the Earth is possible, at least for the case of a two-dimensional system. Simulations assuming an initial uniform distribution of orbital eccentricities on the interval from 0 to e_max are found to produce final states containing too many bodies with masses which are too small when e_max < 0.10, while simulations with e_max > 0.20 result in too many catastrophic collisions between bodies thus preventing rapid accretion of planetary-size bodies. The e_max = 0.15 simulation ends with a state surprisingly similar to that of the present terrestrial planets and, therefore, provides a rough estimate of the range of radial sampling to be expected for the terrestrial planets.     

Stable isotope (O and C) and pollen trends in eastern Lake Erie,evidence for a locally-induced climatic reversal of Younger Dryas age in the Great Lakes basin

A cool period from about 11000 to 10 500 BP (11 to 10.5 ka) is recognized in pollen records from the southern Great Lakes area by the return of Picea and Abies dominance and by the persistence of herbs. The area of cooling appears centred on the Upper Great Lakes. A high-resolution record (ca. 9 mm/y) from a borehole in eastern Lake Erie reveals, in the same time interval, this pollen anomaly, isotope evidence of meltwater presence (a — 3 per mil shift in ¹⁸O and a +1.1 per mil shift in ¹³C), increased sand, and reduced detrital calcite content, all suggesting concurrent cooling of Lake Erie. The onset of cooling is mainly attributed to the effect of enhanced meltwater inflow on the relatively large upstream Main Lake Algonquin during the first eastward discharge of glacial Lake Agassiz. Termination of the cooling coincides with drainage of Lake Algonquin, and is attributed to loss of its cooling effectiveness associated with a substantial reduction in its surface area. It is hypothesized that the cold extra inflow effectively prolonged the seasonal presence of lake ice and the period of spring overturn in Lake Algonquin. The deep mixing would have greatly increased the thermal conductive capacity of this extensive lake, causing suppression of summer surface lakewater temperatures and reduction of onshore growing-degree days. Alternatively, a rapid flow of meltwater, buoyed on sediment-charged (denser) lakewater, may have kept the lake surface cold in summer. Other factors such as wind-shifted pollen deposition and possible effects from the Younger Dryas North Atlantic cooling could have contributed to the Great Lakes climatic reversal, but further studies are needed to resolve their relative significance.Contribution to Climo Locarno — Past and Present Climate Dynamics; Conference September 1990, Swiss Academy of Sciences — National Climate ProgramGeological Survey of Canada Contribution 58 890     

Noble gases in the Allende and Abee meteorites and a gas-rich mineral fraction: investigation by stepwise heating

Noble gases in three meteoritic samples were examined by stepwise heating, in an attempt to relate peaks in the outgassing curves to specific minerals: NeKrXe in Allende (C3V) and an Allende residue insoluble in HF-HCl, and Xe in Abee (E4). In Allende, chromite and carbon contain most of the trapped Ne (²⁰Ne/²²Ne ≈ 8.7) and anomalous Xe enriched in light and heavy isotopes, and release it at ~850°C (bulk meteorite) or 1000°C (residue). Mineral Q, containing most of the trapped Ar, Kr, Xe as well as some Ne (²⁰Ne/²²Ne ≈ 10.4), releases its gases mainly between 1200 and 1600°C, well above the release temperatures of organic polymers (300–500°) or amorphous carbon (800–1000°). The high noble-gas release temperature, ready solubility in oxidizing acids, and correlation with acid-soluble Fe and Cr all point to an inorganic rather than carbonaceous nature of Q.All the radiogenic ¹²⁹Xe is contained in HCl, HF-soluble minerals, and is distributed as follows over the peaks in the release curve: Attend 1000° (75%), 1300° (25%); Abee (data of Hohenberg and Reynolds, 1969) ~850° (15%), 1100° (60%), 1300° (25%). No conclusive identifications of host phases can yet be given; possible candidates are troilite and silicates for Allende, and djerfisherite, troilite and silicates for Abee.Mineral Q strongly absorbs air xenon, and releases some of it only at 800–1000°C. Dilution by air Xe from Q and other minerals may explain why temperature fractions from bulk meteorites often contain less ^124–130Xe for a given enrichment in heavy isotopes than does xenon from etched chromitecarbon samples, although chromite-carbon is the source of the anomalous xenon in either case. Air xenon contamination thus is an important source of error in the derivation of fission xenon spectra.     

Evolution of the Bonneville shoreline scarp in west-central Utah: Comparison of scarp-analysis methods and implications for the diffusion model of hillslope evolution

Wave-cut pluvial shoreline scarps are ideal natural experiments in hillslope evolution because the ages of these scarps are often precisely known and because they form with a range of heights, alluvial textures, and microclimates (i.e., orientation). Previous work using midpoint-slope methods on pluvial scarps in the Basin and Range concluded that scarp evolution is nonlinear and microclimatically controlled. The purpose of this study was to further examine the influence of scarp height, texture and microclimate in an attempt to calibrate a nonlinear model of scarp evolution. To do this, over 150 profiles of the Bonneville shoreline in the adjacent Snake and Tule Valleys, west-central Utah were collected and analyzed by fitting the entire scarp profile to diffusion-equation solutions, taking into account uncertainty in the initial scarp angle. In contrast to previous studies, this analysis revealed no evidence for nonlinearity or microclimatic control. To understand the reason for this discrepancy, we undertook a systematic study of the accuracy of each scarp-analysis method. The midpoint-slope-inverse method was found to yield biased results, with systematically higher diffusion ages for young, tall scarps. The slope-offset method is unbiased but has limited resolution because it requires many scarp profiles to yield a single diffusion age. A method that incorporates the full scarp profile and uncertainty in the initial scarp angle was found to be the most accurate technique. The application of the full-scarp method to the Bonneville shoreline supports the use of a linear diffusion model for scarps up to 20 m in height. Scarp orientation had no discernable effect on diffusivity values. Soil texture was found to have a weak but significant inverse relationship with diffusivity values.     

Virtual vegetables and adopted sheep: ethical relation, authenticity and Internet-mediated food production technologies

Associating ideas related to cultural geographies of 'quality' food production and consumption with recent discussion of Internet technologies, virtuality and simulation, this paper examines two newly constituted Internet enterprises offering customers 'virtual' experiences of food production, and 'quality' food products in which they have invested. The paper shows how these enterprises are associated with particular types of geographical and ethical relation, and a search for 'authentic', connected, relationships with food, farming, locality and 'nature'. These relationships are constituted in an assemblage of things held together by flows of food, products, money and electronic communication. The paper ends by suggesting a number of theoretical ideas that might usefully be explored in empirical research into Internet-mediated food production.     

Paleohydrology of arid southeastern maui, hawaiian islands, and its implications for prehistoric human settlement

Arid slopes on the southeastern side of Maui are densely covered with archaeological remains of Hawaiian settlement from the late prehistoric to early postcontact period (ca. A.D. 1500-1860). Permanent habitation sites, agricultural features, and religious structures indicate perennial occupation and farming in a subregion called Kahikinui, yet there is presently no year-round water source. We explore the possibility that postcontact deforestation led to the loss of either (1) perennial channel flow or (2) perennial springs or seeps. To investigate the first possibility, we estimated ancient peak flows on 11 ephemeral channels in Kahikinui using field measurements and paleohydrology. Peak-flow estimates (3-230 m³/s) for a given drainage area are smaller than those for current perennial Maui streams, but are equivalent to gauged peak flows from ephemeral and intermittent streams in the driest regions of Hawai’i and Maui islands. This is consistent with the long-term absence of perennial channel flow in Kahikinui. On the other hand, others have shown that canopy fog-drip in Hawai’i can be greater than rainfall and thus a large part of groundwater recharge. Using isolated live remnants and snags, we estimate the former extent of the forest upstream from archaeological sites. We use rough estimates of the loss of fog-drip recharge caused by deforestation and apply a simple, steady-state hydrologic model to calculate potential groundwater table fall. These order-of-magnitude estimates indicate that groundwater could have fallen by a minimum of several meters, abandoning perennial seeps. This is consistent with archaeological evidence for former perennial seeps, such as stonewalls enclosing potential seeps to protect them. Although longer-term reductions in rainfall cannot be ruled out as a factor, deforestation and loss of fog-drip recharge are obvious and more immediate reasons for a recent loss of perennial water in Kahikinui, Maui.     

The shifting territory of government: some insights from the Rural White Paper

Summary In this paper it is proposed that the territory of governance is currently being reconfigured by the state. The state is pulling back from a universalist, welfare role, which entailed comprehensive governance of the whole national territory. Now a much more selective form of government is coming into being, concerned with 'community', 'diversity' and 'locality'. This is not, however, simply a belated recognition by the state that these are ever more important features of socio-spatial life: rather, it is part of the reconfiguration of the territory of government as the state invokes these characteristics in order to modify its ways of governing. Using Foucault's concept of governmentality–that is the means used by the state to 'problematise' life within its territorial borders and then act on the basis of these problematisations—the recent case of the Rural White Paper is examined. It is proposed that this is a very clear example of a governmental retreat from a comprehensive role in the governance of rural areas and shows how the state now seeks to govern 'through communities'.     

Fluvial process and the establishment of bottomland trees

The effects of river regulation on bottomland tree communities in western North America have generated substantial concern because of the important habitat and aesthetic values of these communities. Consideration of such effects in water management decisions has been hampered by the apparent variability of responses of bottomland tree communities to flow alteration. When the relation between streamflow and tree establishment is placed in a geomorphic context, however, much of that variability is explained, and prediction of changes in the tree community is improved.The relation between streamflow and establishment of bottomland trees is conditioned by the dominant fluvial process or processes acting along a stream. For successful establishment, cottonwoods, poplars, and willows require bare, moist surfaces protected from disturbance. Channel narrowing, channel meandering, and flood deposition promote different spatial and temporal patterns of establishment. During channel narrowing, the site requirements are met on portions of the bed abandoned by the stream, and establishment is associated with a period of low flow lasting one to several years. During channel meandering, the requirements are met on point bars following moderate or higher peak flows. Following flood deposition, the requirements are met on flood deposits ;high above the channel bed. Flood deposition can occur along most streams, but where a channel is constrained by a narrow valley, this process may be the only mechanism that can produce a bare, moist surface high enough to be safe from future disturbance. Because of differences in local bedrock, tributary influence, or geologic history, two nearby reaches of the same stream may be dominated by different fluvial processes and have different spatial and temporal patterns of trees. We illustrate this phenomenon with examples from forests of plains cottonwood (Populus deltoides ssp. monilifera) along meandering and constrained reaches of the Missouri River in Montana.