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81.
Janet M. Hergt L. Paul Bédard Etienne Deloule Klaus Peter Jochum Kathryn L. Linge Paul J. Sylvester Matthias Willbold Jon D. Woodhead 《Geostandards and Geoanalytical Research》2006,30(3):141-142
In 2005 Geostandards and Geoanalytical Research embarked upon a new initiative for its readers. Key researchers in various fields of geoanalytical technique development and their application were identified and invited to provide reviews pertinent to their expertise. As noted in the first of these publications "…instead of revisiting the historical context or decades of development in each analytical technique, the goal here has been to capture a snapshot of "hot topics" across a range of fields as represented in the… literature" (Hergt et al . 2005). Rather than prepare an annual review, a decision was taken earlier this year to provide a biennial summary of progress and accomplishments, in this case for the years 2004–2005. The principal techniques employed in Earth and environmental sciences are covered here, and include laser ablation and multicollector ICP-MS, ICP-AES, thermal ionisation and secondary ion mass spectrometry, as well as neutron activation analysis, X-ray fluorescence and atomic absorption spectrometry. A comprehensive review of the development of reference materials, often essential to these techniques, is also provided. The contributions assembled serve both to keep readers informed of advances they may be unfamiliar with, but also as a means of showcasing examples of the breadth and depth of work being conducted in these fields. 相似文献
82.
Uranium(VI), which is often elevated in granitoidic groundwaters, is known to adsorb strongly to Fe (hydr)oxides under certain conditions. This process can be used in water treatment to remove U(VI). To develop a consistent geochemical model for U(VI) adsorption to ferrihydrite, batch experiments were performed and previous data sets reviewed to optimize a set of surface complexation constants using the 3-plane CD-MUSIC model. To consider the effect of dissolved organic matter (DOM) on U(VI) speciation, new parameters for the Stockholm Humic Model (SHM) were optimized using previously published data. The model, which was constrained from available X-ray absorption fine structure (EXAFS) spectroscopy evidence, fitted the data well when the surface sites were divided into low- and high-affinity binding sites. Application of the model concept to other published data sets revealed differences in the reactivity of different ferrihydrites towards U(VI). Use of the optimized SHM parameters for U(VI)-DOM complexation showed that this process is important for U(VI) speciation at low pH. However in neutral to alkaline waters with substantial carbonate present, Ca–U–CO3 complexes predominate. The calibrated geochemical model was used to simulate U(VI) adsorption to ferrihydrite for a hypothetical groundwater in the presence of several competitive ions. The results showed that U(VI) adsorption was strong between pH 5 and 8. Also near the calcite saturation limit, where U(VI) adsorption was weakest according to the model, the adsorption percentage was predicted to be >80%. Hence U(VI) adsorption to ferrihydrite-containing sorbents may be used as a method to bring down U(VI) concentrations to acceptable levels in groundwater. 相似文献
83.
The saltmarsh sharp-tailed sparrow (Ammodramus caudacutus) and the morphologically similar seaside sparrow (Ammodramus maritimus) occur together in Atlantic coast salt marshes. Over 2 yr we examined food exploitation patterns to gain an understanding
of how these species coexist and to characterize the trophic conditions that allow the maintenance of different mating systems
within the same habitat. In the promiscuous saltmarsh sharp-tailed sparrow, only females feed the young, while the young of
the socially monogramous seaside sparrow are fed by both parents. To determine dietary patterns, we used a nonlethal method
(throat constriction) to obtain food samples from nestlings. Resource states were determined by sweep-netting the vegetation
and by taking cores from the marsh surface. Based on volume, the same 4 prey groups (flies, amphipods, grasshoppers, moths)
composed > 80% of each species diet. The main food of both sparrows was adult and juvenile (larval and pupal) soldier flies
(Stratiomyidae:Odontomyia microstomata). Measures of dietary overlap, based on resource states, indicated that nestling diets did not differ between species on
a seasonal basis or over 2-wk intervals. As the season progressed, each species tracked in parallel changes in resource abundance.
Diets did not diverge from what was expected if food was exploited randomly; diets frequently overlapped significantly more
than expected. Interspecific resource-use patterns were congruent over 2 yr. Based on the results of this study, and on an
evaluation of hypotheses based on life history information from previously published work, we conclude that food usually is
not limiting for these sparrows and that resource abundance has fostered behavioral and dietary opportunism. 相似文献
84.
Recharge estimation for transient ground water modeling 总被引:11,自引:0,他引:11
Reliable ground water models require both an accurate physical representation of the system and appropriate boundary conditions. While physical attributes are generally considered static, boundary conditions, such as ground water recharge rates, can be highly variable in both space and time. A practical methodology incorporating the hydrologic model HELP3 in conjunction with a geographic information system was developed to generate a physically based and highly detailed recharge boundary condition for ground water modeling. The approach uses daily precipitation and temperature records in addition to land use/land cover and soils data. The importance of the method in transient ground water modeling is demonstrated by applying it to a MODFLOW modeling study in New Jersey. In addition to improved model calibration, the results from the study clearly indicate the importance of using a physically based and highly detailed recharge boundary condition in ground water quality modeling, where the detailed knowledge of the evolution of the ground water flowpaths is imperative. The simulated water table is within 0.5 m of the observed values using the method, while the water levels can differ by as much as 2 m using uniform recharge conditions. The results also show that the combination of temperature and precipitation plays an important role in the amount and timing of recharge in cooler climates. A sensitivity analysis further reveals that increasing the leaf area index, the evaporative zone depth, or the curve number in the model will result in decreased recharge rates over time, with the curve number having the greatest impact. 相似文献
85.
Michael W. Busch Steven J. Ostro Jon D. Giorgini Ellen S. Howell Alice A. Hine Irwin I. Shapiro 《Icarus》2007,186(2):581-584
In November 2005, we observed the moons of Mars using the Arecibo 2380-MHz (13-cm) radar, obtaining a result for the OC radar albedo of Phobos (0.056±0.014) consistent with its previously reported radar albedo and implying an upper bound on its near-surface bulk density of . We detected Deimos by radar for the first time, finding its OC radar albedo to be 0.021±0.006, implying an upper bound on its near-surface density of , consistent with a high-porosity regolith. We briefly discuss reasons for these low radar albedos, Deimos' being possibly the lowest of any Solar System body yet observed by radar. 相似文献
86.
George Xian Collin Homer Brett Bunde Patrick Danielson Jon Dewitz Joyce Fry 《国际地球制图》2013,28(6):479-497
We estimated urbanization rates (2001–2006) in the Gulf of Mexico region using the National Land Cover Database (NLCD) 2001 and 2006 impervious surface products. An improved method was used to update the NLCD impervious surface product in 2006 and associated land cover transition between 2001 and 2006. Our estimation reveals that impervious surface increased 416 km2 with a growth rate of 5.8% between 2001 and 2006. Approximately 1110.1 km2 of non-urban lands were converted into urban land, resulting in a 3.2% increase in the region. Hay/pasture, woody wetland, and evergreen forest represented the three most common land cover classes that transitioned to urban. Among these land cover transitions, more than 50% of the urbanization occurred within 50 km of the coast. Our analysis shows that the close-to-coast land cover transition trend, especially within 10 km off the coast, potentially imposes substantial long-term impacts on regional landscape and ecological conditions. 相似文献
87.
Jon Loveday 《Monthly notices of the Royal Astronomical Society》2000,312(3):557-566
We present a measurement of the K -band luminosity function (LF) of field galaxies obtained from near-infrared imaging of a sample of 345 galaxies selected from the Stromlo-APM Redshift Survey. The LF is reasonably well fitted over the 10-mag range −26 M K −16 by a Schechter function with parameters α =−1.16±0.19, M *=−23.58±0.42 and φ *=0.012±0.008 Mpc−3 , assuming a Hubble constant of H 0 =100 km s−1 Mpc−1 . We have also estimated the LF for two subsets of galaxies subdivided by the equivalent width of the H α emission line at EW(H α )=10 Å. There is no significant difference in LF shape between the two samples, although there is a hint (∼1 σ significance) that emission-line galaxies (ELGs) have M * roughly 1 mag fainter than non-ELGs. Contrary to the optical LF, there is no difference in faint-end slope α between the two samples. 相似文献
88.
Taro Takahashi Stewart C. Sutherland Rik Wanninkhof Colm Sweeney Richard A. Feely David W. Chipman Burke Hales Gernot Friederich Francisco Chavez Christopher Sabine Andrew Watson Dorothee C.E. Bakker Ute Schuster Nicolas Metzl Hisayuki Yoshikawa-Inoue Masao Ishii Takashi Midorikawa Yukihiro Nojiri Arne Krtzinger Tobias Steinhoff Mario Hoppema Jon Olafsson Thorarinn S. Arnarson Bronte Tilbrook Truls Johannessen Are Olsen Richard Bellerby C.S. Wong Bruno Delille N.R. Bates Hein J.W. de Baar 《Deep Sea Research Part I: Oceanographic Research Papers》2009,56(11):2075-2076
89.
This article provides an analysis of a wetland site in southern Illinois from presettlement to the present. The study area is part of the Cache River‐Cypress Creek Wetland, which has international importance, as recognized by the Ramsar Convention on Wetlands. Land‐cover data for 1807, 1938, and 1993 were created and analyzed with a geographic information system (GIS). Land‐use change by topographic setting (uplands, transitional, and bottomlands) and soil productivity was quantified and studied. Interviews with local experts informed this analysis. Results illustrate the complexity of environmental change and its driving forces. First, notable forest and swamp acreage was converted to cropland between 1807 and 1938 and, to a lesser degree, from 1938 to 1993. Second, there were land‐use variations by topographic region. Between 1807 and 1938, the largest transformation occurred in the uplands, with substantial acreage converted from forest to cropland. Between 1938 and 1993, however, agriculture decreased in the upland areas as hilly areas reverted to forest cover. At the same time, agriculture expanded in the bottomlands as this land was drained for farming. Third, there are interesting patterns within these categories of land‐use change, as soil productivity is an indicator of what lands were taken out of cropland and converted back to grassland and forest. 相似文献
90.
Sediment fingerprinting in fluvial systems: review of tracers,sediment sources and mixing models 总被引:3,自引:0,他引:3
Suspended sediments in fluvial systems originate from a myriad of diffuse and point sources, with the relative contribution from each source varying over time and space. The process of sediment fingerprinting focuses on developing methods that enable discrete sediment sources to be identified from a composite sample of suspended material. This review identifies existing methodological steps for sediment fingerprinting including fluvial and source sampling, and critically compares biogeochemical and physical tracers used in fingerprinting studies. Implications of applying different mixing models to the same source data are explored using data from 41 catchments across Europe, Africa, Australia, Asia, and North and South America. The application of seven commonly used mixing models to two case studies from the US (North Fork Broad River watershed) and France (Bldone watershed) with local and global (genetic algorithm) optimization methods identified all outputs remained in the acceptable range of error defined by the original authors. We propose future sediment fingerprinting studies use models that combine the best explanatory parameters provided by the modified Collins (using correction factors) and Hughes (relying on iterations involving all data, and not only their mean values) models with optimization using genetic algorithms to best predict the relative contribution of sediment sources to fluvial systems. 相似文献