GGR Critical Review of Analytical Developments in 2003

The articles that comprise this critical review serve to draw attention to research papers published in specific fields of interest during 2003, provide critical comment on the relevance and importance of individual publications in these fields, and offer an overview of the comparative importance of advances in particular areas. In this way, these articles aim to assist experts in the field by keeping them informed of relevant recent publications, as well as providing an important resource for students or early career researchers who are embarking on studies in an area new to them. This year, five papers provide summaries of developments in bulk sample determinations employing (1) ICP-AES and ICP-MS (trace elements), (2) XRF and atomic absorption spectrometry and INAA, (3) isotope ratio measurements (TIMS, MC-ICP-MS, ICP-MS, ToF), as well as in situ measurements conducted using (4) secondary ion mass spectrometry and (5) laser ablation ICP-MS (trace element and isotope ratio determinations).     

A multi‐method approach to dating the burial and skeleton of Kiacatoo Man,New South Wales,Australia

Kiacatoo Man, a large, rugged Aboriginal adult buried in the Lachlan riverine plains of southeastern Australia, was discovered in 2011. Laser‐ablation uranium series analysis on bone yielded a minimum age for the burial of 27.4 ± 0.4 ka (2σ). Single‐grain, optically stimulated luminescence ages on quartz sediment in which the grave had been dug gave a weighted mean age of 26.4 ± 1.5 ka (1σ). Luminescence samples from the grave infill and from sediment beneath the grave exhibit overdispersed dose distributions consistent with bioturbation or other disturbance, which has obscured the burial signal. The overlap between the minimum (U‐series) and maximum (luminescence) ages places the burial between 27.0 and 29.4 ka (2σ). Luminescence ages obtained from the channel belt of between 28 ± 2 and 25 ± 3 ka indicate that fluvial sedimentation was occurring before the Last Glacial Maximum, which is consistent with the broader geomorphic setting. Together, these results are internally and regionally consistent, and indicate that Kiacatoo Man was one of the more ancient individuals so far identified in Australia. His remains are important to our understanding of patterns of biological variation and other processes that have shaped people in the Murray‐Darling Basin through time. Copyright © 2019 John Wiley & Sons, Ltd.     

The role of prokaryotes in subsurface weathering of hydrothermal sediments: A combined geochemical and microbiological investigation

A detailed geochemical and microbiological study of a ∼2 m sediment core from the inactive Alvin mounds within the TAG hydrothermal field was conducted to examine, for the first time, the role of prokaryotes in subsurface weathering of hydrothermal sediments. Results show that there has been substantial post-depositional remobilisation of metal species and diagenetic overprinting of the original high-temperature hydrothermal minerals, and aspects have involved prokaryotic processes. Prokaryotic enumeration demonstrates the presence of a population smaller than the average for deep sea sediments, probably due to the low organic carbon content, but not inhibited by (and hence adapted to) the metal rich environment. There was a small but significant increase in population size associated with the active redox boundary in an upper metal sulphide layer (50-70 cm) around which active metal remobilisation was concentrated (Cu, Au, Cd, Ag, U, Zn and Zn). Hence, subsurface prokaryotes were potentially obtaining energy from metal metabolism in this near surface zone. Close association of numbers of culturable Mn and Fe reducing prokaryotes with subsurface Fe²⁺ and Mn²⁺ pore water profiles suggested active prokaryotic metal reduction at depth in core CD102/43 (to ∼175 cm). In addition, a prokaryotic mechanism, which is associated with bacterial sulphate reduction, is invoked to explain the U enrichment on pyrite surfaces and Zn and Pb remobilisation in the upper sediment. Although prokaryotic populations are present throughout this metalliferous sediment, thermodynamic calculations indicated that the inferred low pH of pore waters and the suboxic/anoxic conditions limits the potential energy available from Fe(II) oxidation, which may restrict prokaryotic chemolithotrophic biomass. This suggests that intense prokaryotic Fe oxidation and weathering of seafloor massive sulphide deposits may be restricted to the upper portion of the deposit that is influenced by near neutral pH and oxic seawater unless there is significant subsurface fluid flow.     

Macrocrystal phlogopite Rb–Sr dates for the Ekati property kimberlites, Slave Province, Canada: evidence for multiple intrusive episodes in the Paleocene and Eocene

New Rb–Sr age determinations using macrocrystal phlogopite are presented for 27 kimberlites from the Ekati property of the Lac de Gras region, Slave Province, Canada. These new data show that kimberlite magmatism at Ekati ranges in age from at least Late Paleocene (61 Ma) to Middle Eocene time (45 Ma). Older, perovskite-bearing kimberlites from Ekati extend this age range to Late Cretaceous time (74 Ma). Within this age range, emplacement episodes at 48, 51–53, 55–56 and 59–61 Ma can be recognized. Middle Eocene kimberlite magmatism of the previously dated Mark kimberlite (47.5 Ma) is shown to include four other pipes from the east-central Ekati property. A single kimberlite (Aaron) may be younger than the 47.5 Ma Mark kimberlite. The economically important Panda kimberlite is precisely dated in this study to be 53.3±0.6 Ma using the phlogopite isochron method, and up to six additional kimberlites from the central Ekati property have Early Eocene ages indistinguishable from that of Panda, including the Koala and Koala North occurrences. Late Paleocene 55–56 Ma kimberlite magmatism, represented by the Diavik kimberlite pipes adjacent to the southeastern Ekati property, is shown to extend onto the southeastern Ekati property and includes three, and possibly four, kimberlites. A precise eight-point phlogopite isochron for the Cobra South kimberlite yields an emplacement age of 59.7±0.4 Ma; eight other kimberlites from across the Ekati property have similar Late Paleocene Rb–Sr model ages. The addition of 27 new emplacement ages for kimberlites from the Ekati property confirms that kimberlite magmatism from the central Slave Province is geologically young, despite ages ranging back to Cambrian time from elsewhere in the Slave Province. With the available geochronologic database, Lac de Gras kimberlites with the highest diamond potential are currently restricted to the 51–53 and 55–56 Ma periods of kimberlite magmatism.     

The last erosional stage of the Molasse Basin and the Alps

We present a synoptic overview of the Miocene-present development of the northern Alpine foreland basin (Molasse Basin), with special attention to the pattern of surface erosion and sediment discharge in the Alps. Erosion of the Molasse Basin started at the same time that the rivers originating in the Central Alps were deflected toward the Bresse Graben, which formed part of the European Cenozoic rift system. This change in the drainage direction decreased the distance to the marine base level by approximately 1,000 km, which in turn decreased the average topographic elevation in the Molasse Basin by at least 200 m. Isostatic adjustment to erosional unloading required ca. 1,000 m of erosion to account for this inferred topographic lowering. A further inference is that the resulting increase in the sediment discharge at the Miocene–Pliocene boundary reflects the recycling of Molasse units. We consider that erosion of the Molasse Basin occurred in response to a shift in the drainage direction rather than because of a change in paleoclimate. Climate left an imprint on the Alpine landscape, but presumably not before the beginning of glaciation at the Pliocene–Pleistocene boundary. Similar to the northern Alpine foreland, we do not see a strong climatic fingerprint on the pattern or rates of exhumation of the External Massifs. In particular, the initiation and acceleration of imbrication and antiformal stacking of the foreland crust can be considered solely as a response to the convergence of Adria and Europe, irrespective of erosion rates. However, the recycling of the Molasse deposits since 5 Ma and the associated reduction of the loads in the foreland could have activated basement thrusts beneath the Molasse Basin in order to restore a critical wedge. In conclusion, we see the need for a more careful consideration of both tectonic and climatic forcing on the development of the Alps and the adjacent Molasse Basin.     

A review of environmental and genetic factors that affect height inSpartina alterniflora loisel. (Salt marsh cord grass)

The salt marsh cord grass,Spartina alterniflora Loisel., occurs in markedly distinct short and tall growth forms. Both forms have the same number of chromosomes, although polyploidy is well established in the genus. Previous studies have shown that height is primarily affected by nitrate availability and environmental stresses such as increased soluble salt concentrations. These studies have shown that, within a marsh, height differences cannot be attributed to genetic, chromosomal differences or electrophoretic banding. However, more subtle genetic differences may be involved. Other studies suggest that between marshes,S. alterniflora, in response to a latitudinal gradient on the Atlantic coast, has evolved ecotypes differing in height, color and flowering period. This review paper points out that plant height inS. alterniflora may be determined by a combination of environmental and genetic factors.     

Contrasting perspectives on barriers to adaptation in Australian climate change policy

Barriers to adaptation have emerged as key concerns in climate change theory and practice, however there remains little consensus about which barriers are the most significant to different groups and how competing concerns may be addressed. We investigate the significance of different barriers to adaptation for governments, the private sector, and civil society in Australia through a systematic analysis of submissions to the Australian Productivity Commission’s inquiry into barriers to adaptation. Our results show that respondents prioritise barriers differently according to their respective sectors, and that there are competing concerns about which barriers should be addressed first. Nevertheless, some barriers are more persistent in the submissions than others, with governance and policy seen by most groups as being the major impediments to adaptation. We explain the implications of our analysis for adaptation politics and policy.     

Changes in timber haul emissions in the context of shifting forest management and infrastructure

Background  

Although significant amounts of carbon may be stored in harvested wood products, the extraction of that carbon from the forest generally entails combustion of fossil fuels. The transport of timber from the forest to primary milling facilities may in particular create emissions that reduce the net sequestration value of product carbon storage. However, attempts to quantify the effects of transport on the net effects of forest management typically use relatively sparse survey data to determine transportation emission factors. We developed an approach for systematically determining transport emissions using: 1) -remotely sensed maps to estimate the spatial distribution of harvests, and 2) - industry data to determine landscape-level harvest volumes as well as the location and processing totals of individual mills. These data support spatial network analysis that can produce estimates of fossil carbon released in timber transport.