Large-scale floodplain modelling

A two-dimensional horizontal finite element numerical model (RMA-2) was applied to a 24 km river channel-floodplain reach in West Germany. Initial results indicate that finite element schemes may successfully estimate inundation in large-scale floodplain applications. Potentially, the resulting detailed velocity vector distributions and identification of inundation zones throughout storm events could provide an insight into the present day sedimentary environment on the floodplain.     

Two observations about low-frequency signals on accelerograms from the october 15, 1979 imperial valley,california earthquake

Accelerograms from the Imperial Valley have been integrated and baseline corrected by a simple procedure which keeps track of the signal that is removed at long periods. Specifically, acceleration is integrated once to obtain velocity, a linear baseline is subtracted from velocity, the velocity is integrated to displacement, and low order terms of a trigonometric expansion of displacement are subtracted. It is observed that even though this procedure is not suitable for routine processing, one obtains displacement traces which usually resemble the results obtained by standard methods. It is also observed that amplitudes of the trigonometric series expansions are consistent with a simple earthquake source theory for frequencies greater than 1/12 Hz, suggesting that the records are dominated by signal at those frequencies.     

Anisotropic models of the upper mantle

Long period Rayleigh wave and Love wave dispersion data, particularly for oceanic areas, have not been simultaneously satisfied by an isotropic structure. In this paper available phase and group velocity data are inverted by a procedure which includes the effects of transverse anisotropy, anelastic dispersion, sphericity, and gravity. We assume that the surface wave data represents an azimuthal average of actual velocities. Thus, we can treat the mantle as transversely isotropic. The resulting models for average Earth, average ocean, and oceanic regions divided according to the age of the ocean floor, are quite different from previous results which ignore the above effects. The models show a low-velocity zone with age dependent anisotropy and velocities higher than derived in previous surface wave studies. The correspondence between the anisotropy variation with age and a physical model based on flow aligned olivine is suggestive. For most of the Earth SH > SV in the vicinity of the low-velocity zone. Neat the East Pacific Rise, however, SV > SH at depth, consistent with ascending flow. Anisotropy is as important as temperature in causing radial and lateral variations in velocity. The models have a high velocity nearly isotropic layer at the top of the mantle that thickens with age. This layer defines the LID, or seismic lithosphere. In the Pacific, the LID thickens with age to a maximum thickness of ～50 km. This thickness is comparable to the thickness of the elastic lithosphere. The LID thickness is thinner than derived using isotropic or pseudo-isotropic procedures. A new model for average Earth is obtained which includes a thin LID. This model extends the fit of a PREM, type model to shorter period surface waves.     

Volatiles H2O,CO2, and Cl in a subduction related basalt

The products of the 1974 eruption of Fuego, a subduction zone volcano in Guatemala, have been investigated through study of silicate melt inclusions in olivine. The melt inclusions sampled liquids in regions where olivine, plagioclase, magnetite, and augite were precipitating. Comparisons of the erupted ash, groundmass, and melt inclusion compositions suggest that the inclusions represent samples of liquids present in a thermal boundary layer of the magma body. The concentrations of H₂O and CO₂ in glass inclusions were determined by a vacuum fusion manometric technique using individual olivine crystals (Fo77 to Fo71) with glass inclusion compositions that ranged from high-alumina basalt to basaltic andesite. Water, Cl, and K₂O concentrations increased by a factor of two as the olivine crystals became more iron-rich (Fo77 to Fo71) and as the glass inclusions increased in SiO₂ from 51 to 54 wt.% SiO₂. The concentration of H₂O in the melt increased from 1.6 wt.% in the least differentiated liquid to about 3.5% in a more differentiated liquid. Carbon dioxide is about an order of magnitude less abundant than H₂O in these inclusions. The gas saturation pressures for pure H₂O in equilibrium with the melt inclusions, which were calculated from the glass inclusion compositions using the solubility model of Burnham (1979), are given approximately by P(H₂O)(Pa)=(SiO₂−48.5 wt.%) × 1.45 × 10⁷. The concentrations of water in the melt and the gas saturation pressures increased from about 1.5% to 3.5% and from 300 to 850 bars, respectively, during pre-eruption crystallization.     

A universal thermal equation-of-state

Evidence has steadily accumulated to show that at high temperatures (above the Debye temperature, θ) the thermal pressure, P_TH, of solids, is linear with T to a close approximation. This empirical finding yields a simple relationship between P, V, and T quite useful for the computation of the equation-of-state (EOS). For geophysical applications, the empirical data is, so far, limited to a few minerals, all of which are important to our geophysical models of the Earth. The same results have been found for a variety of types of solids, including alkali metals, noble gas solids, alkali halides and metals in addition to minerals. It is argued that the linearity between P_TH and T is a general high-temperature property of solids. This includes minerals. Thus it is proposed that there exists a common thermal EOS which transcends the chemical bonding type and crystallographic class.     

Kolmogorov constants for CO2, wind velocity,air temperature,and humidity fluctuations over a crop surface

The Kolmogorov constants for CO₂, wind velocity, air temperature, and humidity fluctuations were evaluated from measurements made over soybean and grain sorghum fields and found to be 0.78 ± 0.11, 0.49 ± 0.08, 0.70 ± 0.15, and 0.99 ± 0.16, respectively. These results are consistent with recent observations reported in the literature.Published as Paper No. 7255, Journal Series, Nebraska Agricultural Experiment Station. The work reported here was conducted under Regional Research Project 11-33 and Nebraska Agricultural Experiment Station Project 27-003.Associate Professor and Post Doctoral Research Associate, respectively, Center for Agricultural Meteorology and Climatology, Institute of Agriculture and Natural Resources, University of Nebraska, Lincoln, NE, U.S.A., 68583-0728.     

Structure proof and significance of stereoisomeric 28,30-bisnorhopanes in petroleum and petroleum source rocks

Two C₂₈H₄₈-pentacyclic triterpanes were isolated from Monterey shale. X-ray crystallography of a crystal containing both compounds proved their structures as 17β,18α,21α(H)-28,30-bisnorhopane and 17β,18α,21β(H)-28,30-bisnorhopane. Several differences are found between 28,30-bisnorhopanes and the regular hopanes. Unlike the regular hopane epimers, for practical purposes the three epimeric 28,30-bisnorhopanes [17α,21β(H)-, 17β,21α(H)-, and 17β,21β(H)-]cannot be distinguished by their mass spectra. Special conditions are needed to separate them by gas chromatography. The diagenetically first-formed epimer is thought to be 17α,21β(H)- because it predominates in immature shales. The order of thermodynamic stability is 17β,2lα(H) < > 17α,21β(H) > 17β,21β(H), and all three epimers are present in petroleum. 25,28,30-Trisnorhopanes can be analyzed in similar fashion and are found to have similar thermodynamic characteristics. The percent of the ring D/E cis epimer of 28,30-bisnorhopane and/or 25,28,30-trisnorhopane is a useful maturation parameter similar to the 20S/20R sterane ratio. Evidence indicates 25-demethylation of 28,30-bisnorhopane to 25,28,30-trisnorhopane during advanced stages of biodegradation. Hence, percent ring $\text{D}\text{E}$cis 25,28,30-trisnorhopane has an application to maturation assessment in heavily biodegraded oils.     

OCCURRENCE OF VOLATILE ORGANIC CHEMICALS IN NEBRASKA GROUND WATER

Abstract. This report summarizes results of monitoring programs for volatile synthetic organic chemicals (VOCs) in Nebraska's private and public water-supply wells conducted by two State agencies. Of 97 community water-supply systems sampled as of June 1984, 16.5 percent (16 systems) showed quantifiable levels of at least one VOC. Detectable amounts of one or more VOCs were measured in samples from 15.9 percent (10) of 63 private wells sampled in 1982. These percentages are consistent with results of other State and national surveys.     

O, S, Sr, and Pb isotope variations in volcanic rocks from the Northern Mariana Islands: implications for crustal recycling in intra-oceanic arcs

Quaternary lavas from the Northern Mariana Islands have respective O- and S-isotope ranges ofδ¹⁸O = +5.7 to +6.6 (‰ SMOW) andδ³⁴S = +2.0to+20.7 (‰ CDT). Chemically evolved andesites and dacites with meanδ¹⁸O = +6.3 ± 0.2 are slightly enriched in¹⁸O with respect to unfractionated basalts of<53%SiO₂ with meanδ¹⁸O = +6.0 ± 0.1. This¹⁸O enrichment can be explained in terms of differentiation of parental mafic magmas havingδ¹⁸O values between +5.7 to +6.2‰ through closed-system crystal fractionation because the lavas from all nine islands of the arc define a coherentδ¹⁸OSiO₂ trend. The S-isotope composition of oxidized magmas is not modified extensively through the degassing of SO₂; therefore, the meanδ³⁴S value of ca. +11‰ for the Mariana lavas is considered to be representative of their source region.The enrichment of¹⁸O and³⁴S in Mariana Arc parental magmas relative to ocean floor basalts withδ¹⁸O ca. + 5.7‰ andδ³⁴S = ca.0.3‰ is attributed to the recycling of¹⁸O- and³⁴S-rich crustal components (sediment withδ¹⁸O = ca. + 25‰ and seawater sulfate withδ³⁴S = ca. +20‰ into the upper mantle source region for these arc magmas. This interpretation is consistent with enrichments of radiogenic Sr and Pb in the same lavas relative to ocean-floor basalts erupted either side of the arc, which are presumed to share a common upper mantle source. This enrichment is considered to reflect the mixing of two components, one having a typical upper mantle composition and the other having a more radiogenic character similar to that of western Pacific pelagic sediments.