Development of the Wink Sink in west Texas,U.S.A., due to salt dissolution and collapse

The Wink Sink, in Winkler County, Texas, is a collapse feature that formed in June 1980 when an underground dissolution cavity migrated upward by successive roof failures until it breached the land surface. The original cavity developed in the Permian Salado Formation salt beds more than 400 m (1,300 ft) below ground level. Natural dissolution of salt occurred in the vicinity of the Wink Sink in several episodes that began as early as Salado time and recurred in later Permian, Triassic, and Cenozoic times. Although natural dissolution occurred in the past below the Wink Sink, it appears likely that the dissolution cavity and resultant collapse described in this report were influenced by petroleum-production activity in the immediate area. Drilling, completion, and plugging procedures used on an abandoned oil well at the site of the sink appear to have created a conduit that enabled water to circulate down the borehole and dissolve the salt. When the dissolution cavity became large enough, the roof failed and the overlying rocks collapsed into the cavity. Similar collapse features exist where underground salt beds have been intentionally dissolved during solution mining or accidentally dissolved as a result of petroleum-production activity.     

Wind-forced dispersion of blue crab larvae in the Middle Atlantic Bight

Blue crab larvae are advected out of Middle Atlantic Bight estuaries immediately after spawning occurs in the estuary entrance. For the next 30 to 50 days the larvae are found offshore and mainly at the surface where they are influenced by wind-driven currents. Using a previously derived circulation model and winds from Norfolk (VA) airport, a backward trace is made from where relatively dense concentrations of megalopae were found in the Chesapeake Bight during 1983 to a point of origin (spawning).During 1983, the megalopae encountered on the shelf had their origin in Chesapeake Bay and took, at minimum, 31 to 36 days to grow to the megalopae stage. Wind forcing dominated the inner shelf region in the summer of 1983 and the resulting dispersion of Chesapeake Bay megalopae occurred briefly in the southern sector early in the season, but toward the northern sector over most of the season. Although no firm conclusions could be drawn regarding the mechanism for return, it did not seem likely that wind advection back to the point of origin would be effective.     

Reconstruction of long-term time series for commercial fisheries abundance and estuarine pollution loadings

Time series from 1880–1980 for the commercial landings of 35 species and associated fishing effort were reconstructed for the Hudson-Raritan Estuary, Potomac River, Delaware River, Connecticut River and Narragansett Bay. Time series for the same period were developed for indices representing pollutant loadings, developmental activities and habitat alterations for the five target river basins. These indices included representations of demography, sewage and industrial loadings, habitat factors, and nutrient, carbon, and sediment inputs. These data were the result of intensive data collection effort using county, state, and federal records to ascertain activities along individual water basins through time. Direct measures of loadings were used when available, and indirect indicators of loadings were implemented where appropriate. Missing data points from climatic and pollution time series were estimated by statistical modeling, interpolation, and assumption. A probabilistic method was developed to estimate relative stock abundance for each target species-estuary combination using estuarine-specific landings, regional landings, regional catch-by-gear, and regional effort.     

Effect of monochloramine on isolated fulvic acid

Monochloramine is interesting both as a selective oxidant of fulvic acid and as a drinking water disinfectant. In this study, the controlled reaction of aquatic fulvic acid with monochloramine did not result in products detectable by ether extraction-gas chromatography-flame ionization detection techniques. Evidence of a reaction was shown by bleaching of the fulvic acid solution (decreased absorbance at 465 nm) and chlorine substitution. Chlorine-containing products were quantified by the total carbon adsorbable organic halide (TOX) parameter. Bleaching and organic chlorine formation were much less extensive than in the reaction of free chlorine with fulvic acid. Monochloramine was shown to produce an organic chlorine fraction more hydrophilic and with higher molecular size than that produced by chlorine and fulvic acid. Results suggest that monochloramine may be useful tool for the investigation of certain humic functionalities because it reacts rather selectively and to a small extent with aquatic fulvic acid.     

Geochemistry of phonolites and trachytes from the summit region of Mt. Kenya

Two suites of felsic eruptives and intrusives are represented in a set of samples from the summit region of the Plio-Pleistocene volcano, Mt. Kenya. Most of the samples are moderately or strongly undersaturated and have ⁸⁷Sr/⁸⁶Sr initial ratios in the range 0.70360–0.70368 (mean=0.70362). Members of this phonolitic suite are phonolites, nepheline syenites or kenytes and as a group they show a wide variation in TiO₂, FeO, P₂O₅, Sr, Ba, Zr and Nb. The minor and trace element geochemistry reflect variation in the nature of the parental basaltic magmas from which the phonolitic rocks evolved and variation in the crystal fractionation process in individual cases. Crystal fractionation involving plagioclase, alkali feldspar, clinopyroxene, olivine and magnetite is the process by which most of the phonolitic rocks evolved and variation in the relative proportions of these phases in individual cases has led to a broad spectrum of trace and minor element behaviour. The second suite of felsic samples is critically saturated and consists of trachytes showing either slight oversaturation or slight undersaturation with respect to SiO₂. This trachyte suite has lower initial ⁸⁷Sr/⁸⁶Sr ratios (mean=0.70355) and is derived from transitional alkalic basalts by low pressure (crustal) crystal fractionation involving feldspar, clinopyroxene, magnetite and olivine. The range in minor and trace element chemistry observed among the felsic rocks is a consequence of variation in the parental basalts which is related to mantle source variation and to the specific nature of the crystal fractionation process.     

An equivalent layer magnetization model for Australia based on Magsat data

An equivalent layer magnetization model for Australia and adjacent oceanic areas is presented. The model is obtained by linear inversion of Magsat anomaly data measured in the altitude range 325–550 km. The anomaly data set has been isolated from the raw data set by use of models of the core field and very long wavelength external fields, and is internally consistent. Certain major structural features of the Australian continent are geographically associated with magnetization anomalies. A first-order difference is seen between the Tasman Zone and the Precambrian cratonic areas: magnetization anomalies are much more subdued in the former, possibly reflecting a shallowing of the Curie isotherm within the crust. A profile of the vertical integral of magnetization is presented for a crustal section extending from the Gawler Block to the southeast coast. It is shown that the magnetization variations are probably due partly, but not wholly, to depth to Curie isotherm variations; gross magnetization variations among at least three distinct crustal units must be involved.