Paleoclimate reconstruction using carbonate clumped isotope thermometry

Carbonate clumped isotope thermometry is a relatively new paleotemperature proxy based on measurements of the degree of ordering of ¹³C and ¹⁸O into bonds with each other (making the ¹³C¹⁸O¹⁶O₂^?2 ion group) in lattices of carbonate minerals. This technique has several unusual properties that complement existing methods of paleoclimate reconstruction. Most importantly, it is based on a homogeneous isotope exchange equilibrium and thus constrains temperature independent of the isotopic composition of waters from which carbonates grew. This method also appears to be generally insensitive to ‘vital effects’ that compromise many other paleothermometers based on the chemical properties of biominerals or organic matter, at least for those organisms that have been subjected to systematic study to-date (corals and foraminifera); however, discrepancies among some calibrations, particularly at low temperatures, may point toward the existence of vital effects in mollusks and other organisms. This review discusses the principles and calibrations of the technique, its uses in combination with conventional stable isotope measurements to constrain the δ¹⁸O of past waters, preservation of paleotemperatures in ancient materials, as well as current problems in our understanding of calibrations and interlaboratory data comparisons.     

Analytical solutions for advective–dispersive solute transport in double‐layered finite porous media

Analytical solutions for advection and dispersion of a conservative solute in a one‐dimensional double‐layered finite porous media are presented. The solutions are applicable to five scenarios that have various combinations of fixed concentration, fixed flux and zero concentration gradient conditions at the inlet and outlet boundaries that provide a wide number of options. Arbitrary initial solute concentration distributions throughout the media can be considered via explicit formulations or numerical integration. The analytical solutions presented have been verified against numerical solutions from a finite‐element‐based approach and an existing closed‐form solution for double‐layered media with an excellent correlation being found in both cases. A practical application pertaining to advective transport induced by consolidation of underlying sediment layers on contaminant movement within a capped contaminated sediment system is presented. Comparison of the calculated concentrations and fluxes with alternative approaches clearly illustrates the need to consider advection processes. Consideration of the different features of contaminant transport due to varying pore‐water velocity fields in primary consolidation and secondary consolidation stages is achieved via the use of non‐uniform initial concentration distributions within the proposed analytical solutions. Copyright © 2010 John Wiley & Sons, Ltd.     

The synoptic‐ and planetary‐scale signatures of precipitating systems over the Mackenzie River Basin

Abstract

The synoptic‐ and planetary‐scale signatures of precipitating systems over the Mackenzie River Basin (MRB) are elucidated using composites based on a 28‐year sample of widespread precipitation events. These wet events are defined as days on which 5 or more of 12 surface stations in the MRB receive at least 2.5 mm of precipitation. Seasonal composites based on a total of 600 wet events reveal a sequence of statistically significant flow anomalies. Examination of individual wet events motivates stratification of the seasonal samples according to sea‐level pressure distribution. One evolution that is particularly common during fall, winter and spring involves lee cyclogenesis over the southern MRB in association with a strong cyclone over the Gulf of Alaska; such events are dubbed Gulf Redevelopment (GR) cases. A composite based on 59 wintertime GR events indicates upslope flow north of the lee cyclone and warm advection along an east‐west oriented warm front during the precipitation event. Composites of the Q‐vector and the divergence of this field confirm the presence of quasigeostrophic (QG) forcing for ascent over the MRB during this period. A thermally indirect “topographic tilting” mechanism, involving downs‐lope warming over the southern MRB and upslope cooling to the north, is hypothesized to increase warm‐frontal baroclinicity over the MRB. The GR composite 500 hPa geopotential height anomaly pattern is characterized by a series of anomalies extending from the Bering Sea to the Gulf of Mexico. The western (eastern) anomalies tend to decay (amplify) with time. The composite exhibits a positive anomaly over the Bering Sea, a negative anomaly over the Gulf of Alaska that moves eastward into the MRB during the precipitation event, and a positive anomaly that moves eastward over western and central North America. The presence of large, slow‐moving flow anomalies and an extended period of enhanced southwesterly geostrophic flow over the MRB in the composite suggests that a persistent influx of Pacific moisture is required to moisten the atmosphere over the MRB sufficiently for widespread precipitation. An independent composite of dry MRB cyclone events exhibits substantially weaker southwesterly geostrophic flow into the MRB relative to the wet GR composite.     

Selection and quality assessment of Landsat data for the North American forest dynamics forest history maps of the US

Using the NASA Earth Exchange platform, the North American Forest Dynamics (NAFD) project mapped forest history wall-to-wall, annually for the contiguous US (1986–2010) using the Vegetation Change Tracker algorithm. As with any effort to identify real changes in remotely sensed time-series, data gaps, shifts in seasonality, misregistration, inconsistent radiometry and cloud contamination can be sources of error. We discuss the NAFD image selection and processing stream (NISPS) that was designed to minimize these sources of error. The NISPS image quality assessments highlighted issues with the Landsat archive and metadata including inadequate georegistration, unreliability of the pre-2009 L5 cloud cover assessments algorithm, missing growing-season imagery and paucity of clear views. Assessment maps of Landsat 5–7 image quantities and qualities are presented that offer novel perspectives on the growing-season archive considered for this study. Over 150,000+ Landsat images were considered for the NAFD project. Optimally, one high quality cloud-free image in each year or a total of 12,152 images would be used. However, to accommodate data gaps and cloud/shadow contamination 23,338 images were needed. In 220 specific path-row image years no acceptable images were found resulting in data gaps in the annual national map products.     

Growth mechanisms and geochemistry of carbonate concretions from the Cambrian Wheeler Formation (Utah,USA)

Carbonate concretions provide unique records of ancient biogeochemical processes in marine sediments. Typically, they form in organic‐rich mudstones, where a significant fraction of the bicarbonate required for carbonate precipitation is supplied from the decomposition of organic matter in the sediments. As a result, carbonates that comprise concretions are usually characterized by broad ranges in δ¹³C and include values that are significantly depleted relative to seawater. This article reports results from a physical, petrographic and geochemical analysis of 238 concretions from the Wheeler Formation (Cambrian Series 3), Utah, USA, which are unusual in several respects. Most prominently, they formed in organic‐poor mudstones (total organic carbon = 0·1 to 0·5%) and are characterized by a narrow range of δ¹³C that onlaps the range of contemporaneous seawater values. Subtle centre to edge trends in δ¹³C demonstrate that concretion precipitation was initiated by local chemical gradients set up by microbial activity in the sediments, but was sustained during growth by a large pool of inorganic bicarbonate probably derived from alkaline bottom waters. The large inorganic pool appears to have been important in facilitating rapid precipitation of the concretion matrix, which occurred via both displacive and replacive carbonate precipitation during early diagenesis. Stable isotope data from cogenetic pyrite (δ³⁴S) and silica (δ¹⁸O) phases provide insight into the evolution of biogeochemical processes during concretion growth, and suggest that concretions were formed almost entirely during sulphate reduction, with only minor modification thereafter. Concretions of the Wheeler Formation appear to represent an end‐member system of concretion formation in which rapid growth was promoted by ions supplied from sea‐water. As such, they offer insight into the spectrum of processes that may influence the growth of carbonate concretions in marine sediments.     

Geomorphic observations from southwestern terminus of Palghat Gap,south India and their tectonic implications

The region around Wadakkancheri, Trichur District, Kerala is known for microseismic activity, since 1989. Studies, subsequent to 2nd December 1994 (M =4.3) earthquake, identified a south dipping active fault (Desamangalam Fault) that may have influenced the course of Bharathapuzha River. The ongoing seismicity is concentrated on southeast of Wadakkancheri and the present study concentrated further south of Desamangalam Fault. The present study identifies the northwestern continuity of NW–SE trending Periyar lineament, which appears to have been segmented in the area. To identify the subtle landform modifications induced by ongoing tectonic adjustments, we focused on morphometric analysis. The NW–SE trending lineaments appear to be controlling the sinuosity of smaller rivers in the area, and most of the elongated drainage basins follow the same trend. The anomalies shown in conventional morphometric parameters, used for defining basins, are also closely associated with the NW–SE trending Periyar lineament/s. A number of brittle faults that appear to have been moved are consistent with the present stress regime and these are identified along the NW–SE trending lineaments. The current seismic activities also coincide with the zone of these lineaments as well as at the southeastern end of Periyar lineament. These observations suggest that the NW–SE trending Periyar lineaments/faults may be responding to the present N–S trending compressional stress regime and reflected as the subtle readjustments of the drainage configuration in the area.     

A diatom‐inferred record of lake variability during the last 900 years in Lützow–Holm Bay,East Antarctica

Decadal–centennial‐scale climate variability in coastal Antarctica remains poorly understood due to the limited number of highly resolved, well‐dated records. We present a 900‐year, decadal‐scale reconstruction based on sedimentary diatoms from Lake Abi in Lützow–Holm Bay, East Antarctica. Hydrological change is inferred from diatom ecological preferences in conjunction with an existing regional training set and implies that lake water specific conductivity, depth and nitrogen availability are the key drivers of diatom assemblage change. Lake Abi underwent a series of subtle environmental changes related to these environmental variables, possibly driven by changes in catchment snow melt and the duration of seasonal ice cover. Ordination is used to trace the major patterns of change in the diatom community, with notable shifts identified between 470 and 400 and at ～350 cal a BP (where present = CE 1950). The frequency of environmental variability at Lake Abi is broadly consistent with a record of the Interdecadal Pacific Oscillation during the last millennium, but contrasts with the apparent climate stability elsewhere in eastern Antarctica. Further research is required to constrain the limnological and ecological responses of lakes in coastal Antarctica to obtain more rigorous palaeoclimate reconstructions from these sites of immense potential.