Intracrystalline lipids within sulfates from the Haughton Impact Structure—Implications for survival of lipids on Mars

Lipids can be present within gypsum as intracrystalline inclusions if they become incorporated within the mineral as is it precipitates. The lipids that comprise these inclusions are protected against alteration or destruction by an external oxidising chemical environment because a protective mineral matrix surrounds them. Sulfate minerals are abundant on the surface of Mars and were present in the samples that were analysed by the Viking landers. The quantities of secondary intracrystalline fossil-lipids that are present in samples of gypsum and gypsum-rich soils from the Haughton Impact Structure, Devon Island, Canadian High Arctic are sufficient to suggest that if a similar concentration of fossil lipids was present in the sulfate-rich samples analysed by the Viking Landers then they could have been detected. Possible reasons why a secondary fossil-lipid signature was not detected include a poor rate of conversion during pyrolysis, exposure of intracrystalline lipids during periods of weathering to oxidative martian diagenesis, a low level of biological productivity or an absence of a source for lipids on the surface of Mars. Polycyclic aromatic hydrocarbons of meteoritic origin, and terpane biomarkers such as hopanes and steranes, are not present in the Haughton gypsum in sufficient quantities to have been readily detected.     

Do paleoclimate proxies agree? A test comparing 19 late Holocene climate and sea‐ice reconstructions from Icelandic marine and lake sediments

Geochemical, mineralogical and biological indicators preserved in sediments are widely used to reconstruct past climate change, but proxies differ in the degree to which their utility as climate indicators has been validated via laboratory experiments, modern spatial calibrations, or down‐core comparisons with instrumental climate data. Multi‐proxy studies provide another means of evaluating interpretations of proxies. This paper presents a multi‐proxy assessment comparing 19 sub‐centennially resolved late Holocene proxy records, covering the period 300–1900 AD, from seven Icelandic marine and lacustrine core sites. We employ simple statistical comparisons between proxy reconstructions to evaluate their correlations over time and, ultimately, their utility as proxies for regional climate. Proxies examined include oxygen isotopic composition of benthic and planktonic foraminifera, abundance of the sea‐ice biomarker IP₂₅, allochthonous quartz in marine sediments (a proxy for drift ice around Iceland), marine carbonate abundance, total organic carbon concentration, chironomid assemblages, lacustrine biogenic silica and carbon/nitrogen ratios in lake sediments. Most of the examined proxy records, including temperature and sea‐ice proxies, correlate strongly with each other over multi‐centennial timescales, and thus do appear to record changes in regional climate. Copyright © 2011 John Wiley & Sons, Ltd.     

Internal testing of a numerical model of hillslope–channel coupling using laboratory flume experiments

The numerical model COUP 2D simulates the hydrological coupling between hillslopes and the river channel during a rainfall event. In order to test the numerical model, a 1:100 scaled laboratory flume which was modified to incorporate lateral hillslope elements, was used to run a series of experiments in which hillslope angle, channel angle, hillslope discharge and channel discharge were the varying parameters. Overall, there were 18 different experimental configurations with three replicates carried out for each condition, leading to a total of 54 experiments. These conditions were then used to parameterize and run COUP 2D. Internal model outputs of flow depth and flow velocity at four cross‐sections in the channel were compared to the measurements made in the physical model for the same parameter conditions. Statistical comparisons of the measured and modelled data were carried out for each experiment and across all experiments, using two goodness‐of‐fit measures—root mean square error and Nash–Sutcliffe coefficient of efficiency—in order to assess the performance of the model over an entire simulation as well as over all the simulations. The main effects on the goodness‐of‐fit measures for flow depth of each experimental variable, as well as the interactions between variables, were evaluated using statistical modelling. The results show that the model captures flow‐depth variations in response to changing channel and hillslope parameters. Statistical modelling suggests that the main effects on model error are cross‐section position, channel angle and channel discharge. Significant interactions also occur between all the channel variables and between the channel variables and hillslope discharge. The results of the testing procedure have significant implications for the consideration of different model components and for the interaction between data‐ and model evaluation. Copyright © 2007 John Wiley & Sons, Ltd.     

Characterization of the lithological contact in the shergottite EETA79001—A record of igneous differentiation processes on Mars

Abstract— Elephant Moraine (EET) A79001 is the only Martian meteorite that consists of both an olivine‐phyric shergottite (lithology A) and a basaltic shergottite (lithology B). The presence of these lithologies in one rock has previously been ascribed to mixing processes (either magmatic or impact‐induced). Here we present data regarding phase changes across the contact between the lithologies. These data show that the contact is gradational and suggest that it is a primary igneous feature consistent with crystallization of a single cooling magma. We present a model to establish a petrogenetic connection between an olivine‐phyric and a basaltic shergottite through differentiation. The model involves the shallow or surface emplacement of a magma that contained pre‐eruptive solids (phenocrysts and minor xenocrysts). Subsequent differentiation via crystal settling and in situ crystallization (Langmuir 1989) resulted in a layered sequence of lithology A overlain by lithology B, with gradations in modal abundance of maskelynite (increasing from A to B) and pigeonite/maskelynite (decreasing from A to B), and a gradational change in pattern of pyroxene zonation (zones of magnesian augite separating magnesian and ferroan pigeonite appear and thicken into B) across the contact. A pigeonite phenocryst‐bearing zone near the contact in lithology B appears to be intermediate between lithology A and the bulk of lithology B (which resembles basaltic shergottite Queen Alexandra Range [QUE] 94201). Re‐examination of Sr isotopic compositions in lithology A and across the contact is required to test and constrain the model.     

The relationship of wind stress to heat flux divergence of Texas-Louisiana shelf waters

Monthly, multi-annual mean heat budgets are calculated for waters overlying the Texas-Louisiana shelf. Heat storage rates are calculated on the basis of a volumetric temperature-salinity census; unpublished data from Bunker are consulted to determine surface heat exchanges. Monthly heat flux divergences, calculated as residuals in the heat budget equation, show divergence of heat during the months of June and July, the upwelling season for much of the Texas-Louisiana coast, and convergence of heat during the rest of the year when winds conducive to downwelling prevail.     

Analyzing Radar Meteor Trail Echoes using the Fresnel Transform Technique: A Signal Processing Viewpoint

Several techniques have been proposed for measuring speeds of meteoroids observed using radars. A recent technique involves the use of Fresnel transforms to accurately determine the speed of a meteoroid producing the trail. We follow a numerical modeling approach to analyze this technique in detail. Our studies indicate that high sensitivity to background noise levels might be a possible shortcoming of the Fresnel transform method. A matched filtering approach is presented as an alternative to alleviate this sensitivity to the noise problem. Performance of the two techniques is compared using numerical modeling and data from a 30 MHz radar.