Kinetic studies of the rate of dissolution of silica and diatom tests in sea water

Kinetic studies have been carried out on the dissolution of 10μm beads of silica and of the siliceous tests of two species of diatoms (Thalassiosira fluviatus andSkeletonema costatum) in sea water at 10–50°C and over the pH range 6–9. At all temperatures dissolution of the biogenous silica occurred most rapidly at pH 8 and most slowly at pH 6. First order kinetics were closely followed when the silica was present in a considerable excess over that required for saturation, the rate being proportional to the area of the silica. Apparent deviation from this type of kinetics occurred when there was insufficient silica to bring about saturation. This was undoubtedly due to the progressive decrease in the surface area which takes place as the particle dissolves. Application of the rather simplistic model developed by Kamataniet al. (1980), which makes allowance for this decrease, gave a close correspondence with the data until ∼ 90% of the silica had dissolved.     

Hypothesis for a submarine landslide and cohesionless sediment flows resulting from a 17th century earthquake-triggered landslide in Quebec,Canada

Textural isotopic and microfossil data from two gravity cores obtained in Saguenay Fjord, Quebec, suggest that a distinctive sandy clay bed was deposited as the result of a major landslide in the Saguenay River basin. Pb-210 dating of the cores indicate that the bed is of similar age to the magnitude 7 earthquake of February 5, 1663. The slide involved sensitive marine clays and may have occurred in two stages. Slide sediments carried into the Saguenay River channel were probably reworked and subsequently transported down the Fjord basin as two distinct cohesionless mass flows. Fine clay laminae that overlie the older mass flow bed record the modulation of depositional processes by tidal currents for several weeks after this event.     

Hurricane effects on surface gulf stream currents

A 3-dimensional model methodology for predicting the upper ocean currents under the combined influence of Gulf Stream and hurricane is described. Predicted currents are highly dependent on the turbulence closure scheme and nonlinear interactions. New field data will be required to determine the appropriate formulation for turbulent momentum transfer. However, the model points out the importance of nonlinear terms in the equations of motions for preserving the jet-like structure of the Gulf Stream and for properly accounting for interaction between the Gulf Stream and a hurricane. A potentially worst case condition is obtained for the so-called resonant hurricane.     

Multi-proxy evidence of long-term changes in ecosystem structure in a Danish marine estuary, linked to increased nutrient loading

This paper presents a study of changes in eutrophication over the past 100 years in a fertile estuary. The Danish estuary Mariager Fjord is a long, narrow sill-fjord with a permanently anoxic basin. In 1997 anoxia spread from the basin to the entire inner estuary, killing almost all eukaryotes and prompting debate on the causes. This paper reports a multi-proxy survey of ²¹⁰Pb-dated sediment cores from the anoxic basin. Analyses of diatoms, dinoflagellates, pigments and geochemical proxies were used to determine changes in ecosystem structure over the past 100 years. The aim was to establish ‘base-line conditions’, for management purposes, of the biological structure prior to 1900, and to examine possible causes of changes observed. Geochemical proxies total nitrogen (TN), total carbon (TC) and biogenic silica (BSi) were consistently high throughout the sediment record. Increased concentrations of pigments and natural isotopes (δ¹³C, δ¹⁵N) suggested increasing production and nutrient loading. The main changes in the biological proxies occurred between 1915 and the 1940s, and indicated that the estuary has been somewhat eutrophic since 1900, but that the eutrophication process increased over the past 100 years. A reconstruction of TN concentration by a diatom-based transfer function supports this interpretation, with inferred TN ca. 1900 around 60 μmol l⁻¹, and an increase in TN concentration over the past century to ca. 130 μmol l⁻¹ by 1995. Inferred TN decreased to ca. 100 μmol l⁻¹ by 2001, similar to present day monitoring data.     

Baroclinic Buoyancy-Inertia Joint Stability Parameter

At present, the barotropic buoyant stability parameter has been derived from a vertical virtual displacement of a water parcel. The barotropic inertial stability parameter in the eccentrically cyclogeostrophic, basic current field was derived in 2003 from a horizontal cross-stream virtual displacement of a parcel. By expressing acceleration of a parcel due to a virtual displacement, which is arbitrarily sloping within a vertical section across the basic current, in terms of natural coordinates, we derived the vertical component of baroclinic buoyant stability parameter B ₂ ², the horizontal component of baroclinic inertial stability parameter I ₂ ², the baroclinic joint stability parameter J ², its buoyant component B ² and its inertial component I ². B ² is far greater than I ₂ ², and when neglecting relative vorticity except for vertical shear, a downward convex curve of J ² plotted against the slope of a virtual displacement follows a trend of B ² curve. If a parcel displaces along a horizontal surface or an isopycnal surface, however, B ² vanishes, and J ² becomes equal to I ². Actual parcel is apt to displace not only along the bottom slope, but also along the sea surface and an isopycnal interfacial surface, which is approximately equivalent to an isentropic surface, preferred by lateral mixing and exchange of momentum. Such actual displacement makes B ² vanishing, and grants I ² an important role. The present analysis of I ² examining effects due to curvature and horizontal and vertical shear vorticities are useful in deepening our understanding of baroclinic instability in actual oceanic streams.     

Preconditioned Optimizing Utility for Large-dimensional analyses (POpULar)

I present the derivation of the Preconditioned Optimizing Utility for Large-dimensional analyses (POpULar), which is developed for adopting a non-diagonal background error covariance matrix in nonlinear variational analyses (i.e., analyses employing a non-quadratic cost function). POpULar is based on the idea of a linear preconditioned conjugate gradient method widely adopted in ocean data assimilation systems. POpULar uses the background error covariance matrix as a preconditioner without any decomposition of the matrix. This preconditioning accelerates the convergence. Moreover, the inverse of the matrix is not required. POpULar therefore allows us easily to handle the correlations among deviations of control variables (i.e., the variables which will be analyzed) from their background in nonlinear problems. In order to demonstrate the usefulness of POpULar, we illustrate two effects which are often neglected in studies of ocean data assimilation before. One is the effect of correlations among the deviations of control variables in an adjoint analysis. The other is the nonlinear effect of sea surface dynamic height calculation required when sea surface height observation is employed in a three-dimensional ocean analysis. As the results, these effects are not so small to neglect.     

Imposex still evident in eastern Australia 10 years after tributyltin restrictions

A survey of imposex in Thais orbita (Neogastropoda) along the New South Wales (NSW) coast, Australia, found imposex was still widespread 10 years after a partial ban on tributyltin (TBT) based antifouling paints. Transplant experiments also revealed that imposex was induced in T. orbita over a period of 9 weeks in Sydney Harbour, NSW. A comparison of the imposex data with that collected shortly after the introduction of restrictions on TBT revealed a general decline in imposex frequency occurring at open coast sites, an exception being the site at South West Rocks. Sites located within harbour/bay areas did not display a decline in imposex frequency but a decline in the severity of imposex was apparent. The observed decrease in imposex values in T. orbita may reflect a general decrease of butyltin contamination within the coastal environment. However, the persistence of contamination "hotspots" within harbours and bays remains a concern.     

GEBCO Centennial Special Issue – Charting the Secret World of the Ocean Floor: The GEBCO Project 1903–2003

This special issue of Marine Geophysical Researches presents five papers dealing with GEBCO, the General Bathymetric Chart of the Oceans, which celebrated its Centennial in April 2003, hosted by the International Hydrographic Bureau and the Principality of Monaco. Over the past 103 years GEBCO has been the sole body dedicated to compiling all available data to produce standardized maps of the oceans and seas covering 71% of planet Earth. Over time GEBCO has undergone a complete transformation as sparse 500 m contours on paper charts were replaced by digital grids with ever-increasing resolution. The 2003 Centennial saw the release on two CDROMS with the first global 1′ grid, produced by methods unheard of in 1984, when GEBCO’s last 6th Edition paper chart set was published. In GEBCO’s second century, the thrust is towards global grids that will capture the resolutions available with evolving deep-water swath mapping technologies, as well as vast improvement in the details of the shallow continental shelves that have traditionally been the preserve of the hydrographic community. As little more than 10% of the oceans have been mapped to the desired level of detail, there is much to be done. However refinements in satellite altimetry appear to offer an interim stop-gap as more multi-beam sonars ply the oceans and as the littoral countries of the world map their adjacent marine areas for submission under Article 76 of UNCLOS (United Nations, 1983, 1999). In addition GEBCO is becoming increasingly proactive, with outreach to the public via the internet and a new GEBCO Map of the World, active data-scrounging, and encouraging development of the first drifting buoys for acquiring data in the inaccessible areas of the Antarctic, SW Pacific, and Arctic Oceans.