Carry-over effects of the membrane interface probe

The membrane interface probe (MIP) is widely used to characterize the subsurface distribution of volatile organic compounds (VOCs). One problem that arises during MIP application is that disproportionately high MIP signals are obtained after passing source zones which contain mobile or residual phases. This serious problem occurs because of a carry-over effect, in particular caused by compound-specific retention times in the conventional unheated transfer line, commonly used during such an investigation. The objective of this study was to perform a qualitative methodical field evaluation of the carry-over effect of a conventional MIP system with a conventional unheated transfer line. This was achieved by coupling a mobile mass spectrometer to the MIP device. Results obtained were then further compared with those achieved using a laser induced fluorescence (LIF) system. Because of this coupling, time- and depth-dependent signals for different substances became known. Field evaluation data obtained showed complex superpositions of compounds with MIP system results. As a result of this superposition, MIP signals from the saturated zone beneath the source zone (zone with free and/or residual phase) are blurred and are therefore not representative of particular depths. However, utilizing multidirectional probing alongside conventional MIP probing (forwards and backwards), it was possible to detect the upper and lower phase boundary of the source zone. These MIP results correlated excellently with the LIF results. An important conclusion that can be drawn from the field investigation is that coupling a mobile mass spectrometer to the MIP system enables advanced MIP signal interpretation to be successfully achieved.     

The coast between Cabo de Santa Maria (Portugal) and Rabat (Morocco): a mega-size headland-bay shoreline under control of the North Atlantic swell?

Equilibrium headland-bay beach systems have been mathematically described by logarithmic, parabolic and hyperbolic curve functions. The largest system of this type reported to date has a shoreline length of about 62 km. In the present study, an apparent headland-bay system is presented which has a shoreline length of about 500 km. It was discovered on satellite images, and is located between Cabo de Santa Maria in Portugal and the coastal city of Rabat in Morocco. It appears to be controlled by long-period North Atlantic swells diffracting around Cabo São Vicente at the south-western tip of Portugal, in combination with SW–SE wind wave climates impinging on the northern shoreline of Cádiz Bay. The coast shows two marked departures from the equilibrium shoreline along its central section north and south of the Strait of Gibraltar, which are easily explained. Thus, the promontories to the north of the strait still exist because there has not been sufficient time to erode these back to the equilibrium shoreline since postglacial sea-level recovery. The coastal indentation to the south is explained by an insufficient sediment supply from terrestrial sources to facilitate the required beach accretion. Perfectly adjusted planimetric headland-bay shoreline shapes represent situations where wave orthogonals approach the coast at right angles everywhere, i.e. there is no longer any alongshore sediment transport. Equilibrium shorelines form independently of the grain size of the beach sediment, whereas morphodynamic beach states are indirectly affected by the shoreline shapes because the latter are modulated by wave period and breaker height which also control the morphodynamic response of the beach in combination with the local grain size.     

I Zwicky 1: Decomposition and dynamics of the nearby QSO host

We address current theories of research on morphology, environment and evolution of active galaxies in the form of a detailed case study of the nearby QSO host I Zw 1. This study is based on sub-kpc resolution ¹²CO(1-0) observations with the BIMA mm-interferometer and on near-infrared imaging with ISAAC at the VLT. The ¹²CO(1-0) maps reveal a circumnuclear molecular gas ring with a radius of 0.9 kpc. The imaging data in the J-band are analyzed with respect to a disk-bulge decomposition. Together with a model of the gas rotation curve, the radial profile of the dynamical J-band mass-to-light ratio (M/L) is discussed. The J-band images give new evidence for an interaction between I Zw 1 and its nearby companion. First results from a sequence of N-body simulations for an extensive test of the parameter space of the interaction are presented. This revised version was published online in August 2006 with corrections to the Cover Date.     

Glacier change in Garibaldi Provincial Park, southern Coast Mountains, British Columbia, since the Little Ice Age

Fluctuations of glaciers during the 20th century in Garibaldi Provincial Park, in the southern Coast Mountains of British Columbia, were reconstructed from historical documents, aerial photographs, and fieldwork. Over 505 km², or 26%, of the park, was covered by glacier ice at the beginning of the 18th century. Ice cover decreased to 297 km² by 1987–1988 and to 245 km² (49% of the early 18th century value) by 2005. Glacier recession was greatest between the 1920s and 1950s, with typical frontal retreat rates of 30 m/a. Many glaciers advanced between the 1960s and 1970s, but all glaciers retreated over the last 20 years. Times of glacier recession coincide with warm and relatively dry periods, whereas advances occurred during relatively cold periods. Rapid recession between 1925 and 1946, and since 1977, coincided with the positive phase of the Pacific Decadal Oscillation (PDO), whereas glaciers advanced during its negative phase (1890–1924 and 1947–1976). The record of 20th century glacier fluctuations in Garibaldi Park is similar to that in southern Europe, South America, and New Zealand, suggesting a common, global climatic cause. We conclude that global temperature change in the 20th century explains much of the behaviour of glaciers in Garibaldi Park and elsewhere.     

On Flare-CME Characteristics from Sun to Earth Combining Remote-Sensing Image Data with <Emphasis Type="Italic">In Situ</Emphasis> Measurements Supported by Modeling

We analyze the well-observed flare and coronal mass ejection (CME) from 1 October 2011 (SOL2011-10-01T09:18) covering the complete chain of effects – from Sun to Earth – to better understand the dynamic evolution of the CME and its embedded magnetic field. We study in detail the solar surface and atmosphere associated with the flare and CME using the Solar Dynamics Observatory (SDO) and ground-based instruments. We also track the CME signature off-limb with combined extreme ultraviolet (EUV) and white-light data from the Solar Terrestrial Relations Observatory (STEREO). By applying the graduated cylindrical shell (GCS) reconstruction method and total mass to stereoscopic STEREO-SOHO (Solar and Heliospheric Observatory) coronagraph data, we track the temporal and spatial evolution of the CME in the interplanetary space and derive its geometry and 3D mass. We combine the GCS and Lundquist model results to derive the axial flux and helicity of the magnetic cloud (MC) from in situ measurements from Wind. This is compared to nonlinear force-free (NLFF) model results, as well as to the reconnected magnetic flux derived from the flare ribbons (flare reconnection flux) and the magnetic flux encompassed by the associated dimming (dimming flux). We find that magnetic reconnection processes were already ongoing before the start of the impulsive flare phase, adding magnetic flux to the flux rope before its final eruption. The dimming flux increases by more than 25% after the end of the flare, indicating that magnetic flux is still added to the flux rope after eruption. Hence, the derived flare reconnection flux is most probably a lower limit for estimating the magnetic flux within the flux rope. We find that the magnetic helicity and axial magnetic flux are lower in the interplanetary space by ～?50% and 75%, respectively, possibly indicating an erosion process. A CME mass increase of 10% is observed over a range of \({\sim}\,4\,\mbox{--}\,20~\mathrm{R}_{\odot }\). The temporal evolution of the CME-associated core-dimming regions supports the scenario that fast outflows might supply additional mass to the rear part of the CME.     

The radio frequency dielectric properties of the stratified UG1–UG2 geological unit in the Bushveld Complex

A new measurement technique enables the complex dielectric properties of the geological strata comprising the UG1–UG2 (Upper Group 1–Upper Group 2) unit of the Bushveld Complex in South Africa to be determined with unprecedented detail at radio frequencies (RF). Results of non-destructive laboratory measurements of representative diamond drill core samples from the UG1–UG2 unit are presented at 25 MHz. These data establish that the UG1 and UG2 chromitite layers are embedded in rock strata (norite, pyroxenite and anorthosite) which are translucent in the HF spectral band, whereas the chromitite layers themselves exhibit significant velocity contrast, making them good radar reflectors. The data presented here is useful for calibration of the radar system, and for predicting the range and resolution performance of borehole radars operating in both the hanging and footwalls of the economically important platiniferous UG2 reef.     

Stress anisotropy in natural debris flows during impacting a monitoring structure

Landslides - The frictional resistance of rock and debris is supposed to induce stress anisotropy in the unsteady, non-uniform flow of gravitational mass flows, including debris flows. Though...     

Siberian river run-off and Late Quaternary glaciation in the southern Kara Sea, Arctic Ocean: preliminary results

The extent of the Barents-Kara Ice Sheet during the eastern Last Glacial Maximum (LGM) is not yet fully known. A detailed echo-sounding survey performed during the Boris Petrov Expedition 2001 permitted the detailed mapping of part of it. Based on the profiling results, a southern connection between the LGM Barents-Kara Ice Sheet and a local ice sheet on Taymyr Peninsula appears to be unlikely. Based on sediment core data and profiling results, most of the terrigenous river-derived material accumulated in the estuaries during late Holocene times, whereas during early Holocene times of lowered sea level major amounts were transported further offshore and accumulated on the shelf. During the post-glacial sea level rise, the main depocentre migrated southward, reaching its present position no earlier than about 6 cal. Ky BP (or 5.2 Kya). Future studies of accelerator mass spectrometry (AMS) ¹⁴C-dated sediment cores will allow a detailed reconstruction of the variability of fluvial sediment discharge and the history of glaciation in the Kara Sea during late Quaternary times.     

The simulation of Arctic clouds and their influence on the winter surface temperature in present-day climate in the CMIP3 multi-model dataset

We investigate the influence of clouds on the surface energy budget and surface temperature in the sea-ice covered parts of the ocean north of the Arctic circle in present-day climate in nine global climate models participating in the Coupled Model Intercomparison Project phase 3, CMIP3. Monthly mean simulated surface skin temperature, radiative fluxes and cloud parameters are evaluated using retrievals from the extended AVHHR Polar Pathfinder (APP-x) product. We analyzed the annual cycle but the main focus is on the winter, in which large parts of the region experience polar night. We find a smaller across-model spread as well as better agreement with observations during summer than during winter in the simulated climatological annual cycles of total cloudiness and surface skin temperature. The across-model spread in liquid and ice water paths is substantial during the whole year. These results qualitatively agree with earlier studies on the present-day Arctic climate in GCMs. The climatological ensemble model mean annual cycle of surface cloud forcing shows good agreement with observations in summer. However, during winter the insulating effect of clouds tends to be underestimated in models. During winter, most of the models as well as the observations show higher monthly mean total cloud fractions, associated with larger positive surface cloud forcing. Most models also show good correlation between the surface cloud forcing and the vertically integrated ice and liquid cloud condensate. The wintertime ensemble model mean total cloud fraction (69%) shows excellent agreement with observations. The across-model spread in the winter mean cloudiness is substantial (36?C94%) however and several models significantly underestimate the cloud liquid water content. If the two models not showing any relationship between cloudiness and surface cloud forcing are disregarded, a tentative across-model relation exists, in such a way that models that simulate large winter mean cloudiness also show larger surface cloud forcing. Even though the across-model spread in wintertime surface cloud forcing is large, no clear relation to the surface temperature is found. This indicates that other processes, not explicitly cloud related, are important for the simulated across-model spread in surface temperature.     

Systematic under- and overestimation of GHG reductions in renewable biomass systems

This paper identifies a critical systematic error in greenhouse gas accounting in renewable biomass systems. While CO₂ emissions from renewable biomass energy systems are generally considered to have a net impact of 0, no similar adjustment is made for carbon-based products of incomplete combustion, such as methane, in renewable systems. This results in an under- or overestimation of the impact of CH₄ by 12.3% and CO by ∼478% in renewable systems. This error is propagated both in scientific studies and in carbon accounting policies. We advocate first for full-carbon accounting of biomass-derived emissions, but also provide adjusted global warming impacts for emissions from proven renewable systems.