Origin of the high variability of water mineral content in the bedrock aquifers of Southern Madagascar

This study assesses the causes of the high spatial variability of the mineral content of groundwater in crystalline bedrock of Southern Madagascar. Although many kilometres from the coast and at a mean altitude of 400 m a.s.l, wells drilled in this area produce water with electrical conductivities in the range of 300–30,000 μS cm⁻¹ with a high spatial variability. Chemical and isotopic data are used to identify the processes involved in the groundwater mineralization. It is shown that the chemical composition of the groundwater in this region has its origin in (i) normal silicate and carbonate weathering reactions and (ii) input of marine salts, probably via rainfall recharge, modified by evapo-concentrative processes probably including precipitation and re-dissolution of secondary evaporites in the unsaturated zone. To obtain a better understanding of the spatial salinity distribution, well parameters such as yields, weathered zone thickness, weathered materials and morphological positions (upper slope, mid-slope, lower slope or valley bottom) are scrutinized.

A correlation was found between high salinity and low flow, shallow groundwater environments (flat hill tops, valley bottoms, weakly developed and clayey weathered zones) and between low salinity and high flow environments (granular, well-developed weathered zones and situation on valley slopes).     

Copper partitioning between olivine and melt inclusions and its content in primitive island-arc magmas of Kamchatka

Melt inclusions and hosting them highly magnesian olivine from rocks of Kamchatka and the Western Aleutian island arc were analyzed for copper content by LA-ICP-MS to determine the copper partition coefficient in primitive island-arc magmas. Based on measurements of 45 olivine–melt pairs, this coefficient was determined to be 0.028 ± 0.009 (2σ), which is the lowest value among previously published data. Mass-balance calculations of copper in a typical mantle peridotite using obtained partition coefficient indicate that its content in peridotite and primary mantle magmas is mainly determined by mantle sulfide. The Cu partition coefficient was also used to calculate the copper content in parental magmas of volcanoes of the Central Kamchatka Depression. Estimates obtained using copper content in phenocrysts of primitive olivine (Fo > 88 mol %) from these rocks are, on average, 139 ± 58 ppm (2σ), which exceed copper contents in primitive basalts (MgO > 8.5 wt %) of mid-ocean ridges (MORB 93 ± 31 ppm). This suggests the primary enrichment of Central Kamchatka magmas in copper and correlates with their more oxidizing conditions of formation as compared to MORB.     

Investigation into wave properties of the atlantic surface temperature spatial variability on interannual scales

The results of investigations into the spatial variability of the Atlantic Ocean surface temperature field on interannual scales are presented. The analysis is based on monthly mean satellite data of the AVHRR Pathfinder Data JPL NOAA/NASA over 1985–2001. Specific features of the structure of the sea surface temperature (SST) fields averaged over 17 years, as well as fields of the gradient and variance of the SST time series, are described for each node of the data grid. It is shown with the use of the rhythmodynamic approach that spatial heat waves exist in the interannual variability of the SST field in two directions: zonal and meridional.     

Global stability of the ballooning mode in a cylindrical model

Ballooning disturbances in a finite-pressure plasma in a curvilinear magnetic field are described by the system of coupled equations for the Alfvén and slow magnetosonic modes. In contrast to most previous works that locally analyzed the stability of small-scale disturbances using the dispersion relationship, a global analysis outside a WKB approximation but within a simple cylindrical geometry, when magnetic field lines are circles with constant curvature, is performed in the present work. This model is relatively simple; nevertheless, it has the singularities necessary for the formation of the ballooning mode: field curvature and non-uniform thermal plasma pressure. If the disturbance finite radial extent is taken into account, the instability threshold increases as compared to a WKB approximation. The simplified model used in this work made it possible to consider the pattern of unstable disturbances at arbitrary values of the azimuthal wavenumber (k _y ). Azimuthally large-scale disturbances can also be unstable, although the increment increases with decreasing azimuthal scale and reaches saturation when the scales are of the order of the pressure nonuniformity dimension.     

Long-Term Geochemical Monitoring of the Source of the Angara River (Runoff from Lake Baikal)

The long-term data (1950–2017) on the chemical composition of the water from the source of the Angara River, which is the only run-off from Lake Baikal, a large and clean fresh water reservoir, are presented. The absence of water contamination despite the anthropogenic influence is shown. The similarity and constancy of the current composition of the waters in the lake and the Angara River are recorded. It is recommended to continue geochemical studies of this unique world heritage site.     

Thermodynamic model for sorption of bivalent heavy metals on calcite in natural-technogenic environments

Approaches to the construction of thermodynamic models for sorption of trace-element cations on carbonates are considered. To calculate thermodynamic equilibria by the method of Gibbs free-energy minimization, the existing database of reaction constants and thermodynamic potentials was extended. Different types of models are illustrated by the example of precipitation of Cd, Cu, Pb, and Zn from the water of a drainage stream flowing out of the impoundment of barite-polymetallic ore-dressing wastes. It is shown that the mobility of metals in such cases can be controlled by their sorption by calcite present in bottom sediments and suspension. Any approach can be successfully applied to both the modeling of experimental data on cation sorption and the prediction of the ecologo-geochemical situation in the districts of dressing works.     

The origin of intergalactic stars in galaxy clusters

The paper analyzes possible origins of stars located in intergalactic space that are not bound to specific galaxies, which comprise 15–50% of all stars in galaxy clusters. Some such stars can form in streams of intergalactic gas flowing around gas-rich disk galaxies moving in the cluster. Others may be the products of the decay of young, low-mass, spheroidal galaxies after the loss of their gaseous components during an initial burst of star formation. The decay of low-mass disk galaxies moving at high speeds after they have lost their gaseous components due to the pressure of the incident flow of dense intergalactic gas is possible in the cluster core. The largest fraction of intergalactic stars are probably produced by the partial disruption of galaxies as a result of close passages, collisions, or mergers. Collisions of low-mass, gas-rich galaxies are especially good suppliers of intergalactic stars. Both stars from decaying stellar components of galaxies and stars arising in the gaseous components of colliding galaxies can be supplied to the intergalactic medium. The merger of galaxies harboring supermassive black holes in their nuclei could lead to the partial or total disruption of these galaxies during the deceleration of the binary black hole that is formed during the merger. An enhanced density of intergalactic stars is observed in the cores of galaxy clusters, underscoring the role of galaxy collisions in the formation of the intergalactic stellar population, since the frequency of galaxy collisions grows with their density.     

Arctic sea ice long-term dynamics according to the satellite microwave data

The main results of processing the long-term satellite data in different spectral ranges and with different spatial resolutions used to map Arctic sea ice parameters are presented. The advantages of the methods developed in order to estimate these parameters on the basis of microwave sensor measurements are indicated. The specific features of the long-term dynamics of the main sea ice geophysical parameters (the sea ice area and distribution during the summer minimum, ice age structure and thickness, multiyear ice concentration, times of ice melt and freeze onset, etc.) are presented. The effect of changes in sheet ice on the status of large Arctic mammals is estimated.     

Simulation of the impact of thunderstorm activity on atmospheric gas composition

A chemistry-climate model of the lower and middle atmosphere has been used to estimate the sensitivity of the atmospheric gas composition to the rate of thunderstorm production of nitrogen oxides at upper tropospheric and lower stratospheric altitudes. The impact that nitrogen oxides produced by lightning have on the atmospheric gas composition is treated as a subgrid-scale process and included in the model parametrically. The natural uncertainty in the global production rate of nitrogen oxides in lightning flashes was specified within limits from 2 to 20 Tg N/year. Results of the model experiments have shown that, due to the variability of thunderstorm-produced nitrogen oxides, their concentration in the upper troposphere and lower stratosphere can vary by a factor of 2 or 3, which, given the influence of nitrogen oxides on ozone and other gases, creates the potential for a strong perturbation of the atmospheric gas composition and thermal regime. Model calculations have shown the strong sensitivity of ozone and the OH hydroxyl to the amount of lightning nitrogen oxides at different atmospheric altitudes. These calculations demonstrate the importance of nitrogen oxides of thunderstorm origin for the balance of atmospheric odd ozone and gases linked to it, such as ozone and hydroxyl radicals. Our results demonstrate that one important task is to raise the accuracy of estimates of the rate of nitrogen oxide production by lightning discharges and to use physical parametrizations that take into account the local lightning effects and feedbacks arising in this case rather than climatological data in models of the gas composition and general circulation of the atmosphere.     

Does lunisolar gravitational tide affect the activity of animals?

Multiyear time series obtained by the continuous instrumental monitoring of the electrical activity (EA) of weakly electric fish Gnathonemus leopoldianus and the motor activity (MA) of the freshwater catfish Hoplosternum thoracatum and the cockroach Blaberus craniifer are compared to the parameters of the lunisolar gravitational tide. These curves are observed to be very similar for a large number of time intervals. However, a more detailed analysis shows this to be only a superficial resemblance caused by the closeness of the periods of diurnal and semidiurnal rhythms of bioindicator activity (the dominant rhythms in EA and MA patterns) and the periods of main gravitational tidal waves. It is concluded that the lunisolar gravitational tide has no significant effect on animal behavior in our experiment.