Tectonically dewatered slates in the Ludlovian of the Lake District,England

Multiple siltstone dykes intruded parallel to cleavage in the Ludlovian argillites and graywackes of the Lake District throw new light on the origin of slaty cleavage. Pore pressures equalling lithostatic pressure developed during the Caledonian orogeny and caused tectonic dewatering of the partially lithified sediments. Slaty cleavage was initiated as an essentially planar structure by the intrusion of thin pelitic folia during the escape of the pore water. Cleavage folia and fold axial planes may have a common geometric relationship to the deforming stresses, but are independent of each other in origin. Continued deformation after tectonic dewatering refracted the cleavage by rotation of competent layers. Critical examination of evidence supporting traditional theories of slaty-cleavage formation shows that all observed relationships are compatible with the tectonic-dewatering theory.     

Sources and preservation of organic matter in the Cretaceous Toolebuc Formation, eastern Australia

The organic matter-rich Toolebuc Formation of eastern Australia was deposited in a Lower Cretaceous epicontinental sea. Parameters from biological marker studies indicate that the organic matter is immature to marginally mature for hydrocarbon generation. The occurrence of abundant coccoliths and the distribution of alkane biomarkers suggest that the organic matter (Type II) is largely of planktonic origin and only in the southeastern part of the depositional area can a terrestrial influence be discerned. Variations in kerogen composition can be attributed to the extent of the oxidation of the source materials and the degree of incorporation of sulphur. The atomic H/C ratios (c. 1.1) are remarkably constant for most of the Toolebuc Formation. Atomic O/C ratios vary from 0.1 and 0.4 and can be related both to depth and paleogeographic position. Kerogen sulphur contents range up to 7%, and the highest values occur in the most carbonate-rich sediments. Total sulphur (inorganic + organic) to carbon ratios in the sediments vary from 1 to <0.2 and are a function of paleogeographic position and lithology. Most of the sulphur in the sediments is in the form of pyrite, but the proportion of sulphur in organic form increases as the total sulphur content decreases. The evidence for oxidation of the organic matter and incorporation of sulphur into it during deposition suggests that bituminite, which is the dominant organic maceral in the Toolebuc Formation, was formed from an organic gel derived by decay of predominantly algal material. These data support a modified gyttja model (Kauffman, 1981) for the deposition of organic matter in the Toolebuc Formation.     

Preparation and Measurement of Cassiterite for Sn Isotope Analysis

Increased interest in the fractionation of Sn isotopes has led to the development of several techniques for preparing cassiterite (SnO₂, the primary ore of Sn) for isotopic analysis. Two distinct methods have been applied in recent isotopic studies of cassiterite: (a) reduction to tin metal with potassium cyanide (KCN) at high temperature (800 °C), with subsequent dissolution in HCl, and (b) reduction to a Sn solution with hydriodic acid (HI) at low temperature (100 °C). This study compares the effectiveness and accuracy of these two methods and contributes additional methodological details. The KCN method consistently yielded more Sn (> 70% in comparison with < 5%), does not appear to fractionate Sn isotopes at high temperatures over a 2‐hour period and produced consistent Sn isotope values at flux mass ratios of ≥ 4:1 (flux to mineral) with a minimum reduction time of 40 min. By means of a distillation experiment, it was demonstrated that HI could volatilise Sn, explaining the consistently low yields by this method. Furthermore, the distillation generated Sn vapour, which is up to 0.38‰ per mass unit different from the starting material, the largest induced Sn fractionation reported to date. Accordingly, the HI method is not recommended for cassiterite preparation for Sn isotopic analysis.     

Metasomatism and sulfide mobility in lithospheric mantle beneath eastern Australia: Implications for mantle Re–Os chronology

Spinel lherzolite xenoliths from Tertiary basaltic host magmas at Allyn River, eastern Australia reveal two distinct petrographic and geochemical types. One group is distinguished by xenoliths with undeformed, equilibrated microstructures and interstitial melt patches; The second group shows deformation and contains abundant fluid inclusions but no melt patches. Trace-element signatures of clinopyroxene in these xenoliths provide evidence for metasomatism by a silicate agent with hydrous component and by a carbonate-rich agent respectively.

Melt patches in the undeformed xenoliths contain secondary minerals including clinopyroxene, olivine, feldspar, Mg- and Ca-rich carbonate, apatite, ilmenite and spinel. They are interpreted to represent volatile-rich melt captured shortly prior to entrainment in the host basalt. Sulfide globules, now recrystallised to discrete sulfide phases but inferred to be molten at lithospheric mantle T and P, are closely associated with the melt patches. The close association between sulfide and highly mobile, volatile-bearing fluid has important implications for the mobility of Re and Os, the use of their isotopes in dating mantle events, and the possible effect of volatile-bearing metasomatic agents on their composition.     

Neoglacial (<3000 years) till and flutes at Saskatchewan Glacier,Canadian Rocky Mountains,formed by subglacial deformation of a soft bed

Understanding the processes that deposit till below modern glaciers provides fundamental information for interpreting ancient subglacial deposits. A process‐deposit‐landform model is developed for the till bed of Saskatchewan Glacier in the Canadian Rocky Mountains. The glacier is predominantly hard bedded in its upper reaches and flows through a deep valley carved into resistant Palaeozoic carbonates but the ice margin rests on a thick (<6 m) soft bed of silt‐rich deformation till that has been exposed as the glacier retreats from its Little Ice Age limit reached in 1854. In situ tree stumps rooted in a palaeosol under the till are dated between ca 2900 and 2700 yr bp and record initial glacier expansion during the Neoglacial. Sedimentological and stratigraphic observations underscore the importance of subglacial deformation of glaciofluvial outwash deposited in front of the advancing glacier and mixing with glaciolacustrine carbonate‐rich silt to form a soft bed. The exposed till plain has a rolling drumlinoid topography inherited from overridden end moraines and is corrugated by more than 400 longitudinal flute ridges which record deformation of the soft bed and fall into three genetically related types: those developed in propagating incipient cavities in the lee of large subglacial boulders embedded in deformation till, and those lacking any originating boulder and formed by pressing of wet till up into radial crevasses under stagnant ice. A third type consists of U‐shaped flutes akin to barchan dunes; these wrap around large boulders at the downglacier ends of longitudinal scours formed by the bulldozing of boulders by the ice front during brief winter readvances across soft till. Pervasive subglacial deformation during glacier expansion was probably facilitated by large boulders rotating within the soft bed (‘glacioturbation’).     

A calculated petrogenetic grid for ultramafic rocks in the system CaO-FeO-MgO-Al2O3-SiO2-CO2-H2O at low pressures

Calculated phase equilibria among the minerals amphibole, chlorite, clinopyroxene, orthopyroxene, olivine, dolomite, magnesite, serpentine, brucite, calcite, quartz and fluid are presented for the system CaO–FeO–MgO–Al₂O₃–SiO₂–CO₂–H₂O (CaF-MASCH), with chlorite and H₂O–CO₂ fluid in excess and for a temperature range of 440°C–600°C and low pressures. The minerals chosen in CaFMASCH represent the great majority of phases encountered in metamorphosed ultramafic rocks. The changes in mineral compositions in terms of FeMg_-1 and (Mg, Fe)SiAl_-1Al_-1 are related to variations in the intensive parameters. For example, equilibria at high in the presence of chlorite involve minerals which are relatively aluminous compared with those at low . The calculated invariant, univariant and divariant equilibria are compared with naturally-occurring greenschist and amphibolite facies ultramafic mineral assemblages. The correspondence of sequences of mineral assemblages and the compositions of the minerals in the assemblages is very good.     

Observations of Lake-Breeze Events During the Toronto 2015 Pan-American Games

Enhanced meteorological observations were made during the 2015 Pan and Parapan American Games in Toronto in order to measure the vertical and horizontal structure of lake-breeze events. Two scanning Doppler lidars (one fixed and one mobile), a C-band radar, and a network including 53 surface meteorological stations (mesonet) provided pressure, temperature, humidity, and wind speed and direction measurements over Lake Ontario and urban areas. These observations captured the full evolution (prior, during, and after) of 27 lake-breeze events (73% of observation days) in order to characterize the convective and dynamic processes driving lake breezes at the local scale and mesoscale. The dominant signal of a passing lake-breeze front (LBF) was an increase in dew-point temperature of \(2.3 \pm 0.3 \,^{\circ }\hbox {C}\), coinciding with a \(180^{\circ }\) shift in wind direction and a decrease in air temperature of \(2.1 \pm 0.2 \,^{\circ }\hbox {C}\). Doppler lidar observations over the lake detected lake breezes 1 hour (on average) before detection by radar and mesonet. On days with the synoptic flow in the offshore direction, the lidars observed wedge-shaped LBFs with shallow depths, which inhibited the radar’s ability to detect the lake breeze. The LBF’s ground speed and inland penetration distance were found to be well-correlated (\(r = 0.78\)), with larger inland penetration distances occurring on days with non-opposing (non-offshore) synoptic flow. The observed enhanced vertical motion \(({>} 1\hbox { m s}^{-1})\) at the LBF, observed by the lidar on 54% of lake-breeze days, was greater (at times \({>} 2.5\hbox { m s}^{-1}\)) than that observed in previous studies and longer-lasting over the lake than over land. The weaker and less pronounced lake-breeze structure over land is illustrated in two case studies highlighting the lifetime of the lake-breeze circulation and the impact of propagation distance on lake-breeze intensity.     

Absolute Calibration of an Ashtech Z12-T GPS Receiver

Dual-frequency carrier phase and code measurements from geodetic type receivers are a promising tool for frequency and time transfer. In order to use them for clock comparisons, all instrumental delays should be calibrated. We have carried out the calibration of one such receiver, an Ashtech Z12-T type, by two different methods: first, by absolute calibration using a GPS simulator; second, by differential calibration with respect to a time transfer receiver that had previously been calibrated. We present the experimental set-ups and the results of the two experiments and estimate the uncertainty budget. An ultimate uncertainty of order 1 ns in the absolute calibration seems to be attainable. ? 2001 John Wiley & Sons, Inc.