Numerical hindcasting of sea surface pCO2 at Weathership Station Papa

A one-dimensional model of temperature, salinity, nutrients, oxygen, carbon, and argon chemistry is used to hindcast the annual cycle of sea surface pCO₂ at weathership Station Papa in the subarctic Pacific (50°N, 145°W), based on recent biological and chemical measurements made in conjunction with the SUPER program. Heat fluxes are calculated from the meteorological time series data from the Canadian weathership program. The Price, Weller and Pinkle (1986) model is used for predicting mixed layer dynamics. The rate of new production in the model is based on sediment trap data (Welschmeyer, personal communication) and a comparison of model oxygen and argon concentrations with the recent data of Emerson, Quay, Stump, Wilbur and Knox (1991). The balances of nutrients and oxygen in the permanent halocline require isopycnal ventilation on a time frame of approximately 10 years; this estimate is consistent with estimate of Van Scoy, Fine and Ostlund (1991) based in tritium data from Geosecs and Long Lines programs. The model results are compared with the 5 year time series data presented by Wong and Chang (1990). The model appears to capture the mean sea surface pCO₂ and the magnitude and timing of the seasonal cycle. The data, howeber, contain much greater high frequency variation than the model results, which we believe is caused by patchiness in the horizontal distribution of NO₃. The model pCO₂ sensitivity to the chemistry of the upwelling water and the rate of biological new production are presented.Although the model simulation of pCO₂ is satisfactory, this study illustrates the limitations of modelling the chemistry of the upper ocean in one dimension. The slow currents and horizontally homogeneous sea surface in the subarctic Pacific make Papa one of the best available candidates for modelling in 1-D. In spite of this, a 1-D formulation is inadequate to address the chemistry of the halocline (a crucial lower boundary condition to the mixed layer) and does not constrain the transport of the nutrients by wind-driven currents in the mixed layer. We conclude that further progress in modelling the upper ocean nutrient and carbon cycles will requires simulation in three dimensions.     

Relationship between visible and heritable chromosome damage in trout cells and embryos

The disruption of chromosome segregation which is detected visually by the anaphase aberration (aa) test suggests that unequal amounts of DNA are distributed to daughter cells and possibly to subsequent cell generations. To investigate this possibility trout cell cultures and trout embryos (blastodisc) were exposed to benzo[a]pyrene (B[a]P) and the nitrosamide, MNNG, respectively. They were then examined by flow cytometry to determine if anaphase damage resulted in unequal DNA distribution to daughter cells. Both B[a]P and MNNG produced a significant increase (P < 0·01) in aa in cultured cells after 48 h exposure. These values returned to normal by 10 days in the absence of the genotoxic agents, except for the highest concentration (0·5 μg/ml MNNG), which showed only a 50% recovery by that time. Likewise, the coefficient of variation (CV) of nuclear DNA content of the cells also rose significantly after treatment and remained elevated for as long as 14 days following exposure. Experiments with rainbow trout embryos also showed a significant increase in both aa and CV following exposure to MNNG. Flow cytometric analysis of DNA content of trout cells and embryos following exposure to mutagens showed an unequal distribution of DNA that was transmissible through several cell generations. These findings indicate that visible anaphase aberrations could predict heritable genetic defects such as those associated with aneuploidy.     

A sea bottom multichannel hydrophone array

The PUMA (Pull-Up Multichannel Array) is a sea-bottom instrument for remotely recording data from a 12 channel hydrophone array. Its purpose is to achieve (i) denser data coverage, leading to (ii) improved velocity analysis and (iii) multichannel processing of wide angle seismic data collected on the continental shelf. The instrument consists of a 1.2 km array terminating with a pressure case in which 8 FM cassette recorders, a power supply, microprocessor controller and internal clock are housed. It can be pre-programmed to switch on during shot windows for a total of four hours recording time.The PUMA was successfully used in an experiment west of Lewis, Outer Hebrides, U.K. in August–September 1984. We show an example of PUMA data from this experiment. Indications are that the instrument will provide improved constraints on seismic velocities in the lower continental crust and uppermost mantle.     

Importance of organic Fe complexing ligands in the Mississippi River plume

As part of a larger program focused on understanding the biogeochemistry of large river plumes, we participated in two expeditions during 2000 to sample the Mississippi River plume. Surface water samples were collected using a trace metal clean towed fish and analyzed for total dissolved Fe, organic Fe complexing ligands and their associated conditional stability constants. The ligands in the river plume have conditional stability constants (log K′_FeL between 10.5 and 12.3 with an average of 11.2 and standard deviation of 0.6) very similar to ligands found in the open ocean. Comparison of high flow and low flow regimes indicates that variability in flow may be the main cause of the variability in Fe concentrations in the plume. The organic Fe complexing ligands are in greatest excess during a time of higher flow. These ligands are responsible for maintaining very high (5 nM) Fe concentrations throughout the plume. Due to complexation with these organic ligands, the concentration of Fe remains above the Fe-hydroxide solubility level until a salinity above 35 is reached where there appears to be a sink for Fe in the less productive waters. Therefore, Fe is transported a great distance from the river source and is available for biological utilization in the coastal zone.     

Sedimentary geology of the Columbia River Estuary

A multiyear study of the sedimentary geology of the Columbia River Estuary has provided valuable data regarding sediment distribution, bedform distribution, and suspended sediment distribution on spatial and temporal scales that permit delineation of sedimentary environments and insight into the sedimentary processes that have shaped the estuary. In comparison to other more-intensively studied estuaries in North America, the Columbia River estuary has relatively larger tidal range (maximum semidiurnal range of 3.6m) and large riverflow (6,700m³s⁻¹). Variations in riverflow, sediment supply, and tidal flow occur over a range of time scales, making the study of modern processes, as they relate to long-term effects, particularly challenging.Analyses of more than 2000 bottom-sediment grab samples indicate that the bed material of the estuary varies in a relatively narrow range between 0 and 8 phi (1.0 and 0.0039mm) with an overall mean size of 2.5 phi (0.177mm). Sediment size decreases generally in the downstream direction. Sediments from the upriver channels are coarse (1.5–2.0phi; 0.25–0.35mm) and moderately sorted; sediments in the central estuary show wider range and variation in grain size and sorting (1.75–6.0phi; 0.016–0.3mm). Sediment from the entrance region has a mean size of 2.75phi (0.149mm) and is well sorted. Seasonal changes in sediment size distributions occur and are best delineated by those samples containing more than 10% mud (silt plus clay). Sediments containing a significant fine fraction generally occur only in the peripheral bays and in channels isolated from strong currents. Thin deposits of fine sediments are occasionally found in main channels, and the ephemeral nature of these sediments suggest that they may erode and produce the silty rip-up clasts that appear intermittently in the same regions.The distribution of bedforms of various size and shape has been mapped with side-scan sonar during three seasons and at various tidal stages. The presence of bedforms with wavelengths of 6–8m and alternating slip faces about 40cm high indicates that the deeper portion of the entrance region is dominated by tidally reversing lower flow regime sediment transport. Bedforms in the upper reaches of the estuary are much larger, with heights of up to 3m and wavelengths of up to 100m. These bedforms, and the smaller, superimposed bedforms, imply downstream transport under fluvial conditions. In the central estuary, bedforms in the deep portion of the main channels are oriented upriver while those on the shallow flanks of the channels are oriented seaward. The landward limit of upriver bedform transport varies seasonally in response to riverflow fluctuations.A complex array of sedimentary environments exists in the Columbia River estuary. Each environment is influenced by the relative importance of waves, fluvial currents, and tidal currents, as modified by the presence or absence of estuarine circulation, vegetation, or human activity. The importance of these enviroments to the ecosystem of the estuary is discussed in subsequent papers in this volume.     

The sea-floor spreading history of the eastern Indian Ocean

The geologic history of the eastern Indian Ocean between northwest Australia and the Java Trench is known to involve two separate events of rifting and sea-floor spreading. Late Jurassic spreading in the Argo Abyssal Plain off northwest Australia was followed by Early Cretaceous spreading in the Cuvier and Perth Abyssal Plains off west Australia. However, the evolution and interaction of these events has not been clear. Mesozoic sea-floor spreading anomalies have been identified throughout the Argo Abyssal Plain that define a rifting event and subsequent northward spreading on the northwestern Australian margin at 155 m.y.b.p. Magnetic anomalies northwest of the Argo Abyssal Plain indicate a ridge jump to the south at about 130 m.y.b.p. that is approximately synchronous with east-west rifting along the southwestern Australian margin. The Joey Rise in the Argo Plain was probably formed by volcanism at the intersection of this new rift and the spreading ridge to the north. The southern and northern spreading systems were connected through the Exmouth Plateau which was stretched and faulted as spreading progressed. The RRR triple junction was formed at the intersection of the two spreading systems and appears to have migrated west along the northern edge of the Gascoyne Abyssal Plain. Spreading off northwest Australia cannot be easily related to simultaneous spreading in the west central Pacific via any simple tectonic scheme.     

Transition of Tidal Waves from the East to South China Seas over the Taiwan Strait: Influence of the Abrupt Step in the Topography

Observations of tidal waves between the East and South China Seas (ECS and SCS) over the Taiwan Strait (TS) suggest that the diurnal tides simply appear as one southward-propagating wave from the ECS to the SCS through the TS. The semidiurnal tides, however, behave differently in that they appear as a southward-propagating Kelvin wave in the western TS and a nearly standing wave in the eastern TS, and then diminish rapidly over the shallow shoal in the southern TS. A smaller-domain model, with sea-level boundary conditions derived from a larger-domain tidal model, was first used to simulate tides in the TS to an overall percentage of accuracy of about 90%. Subsequent numerical experiments and theoretical analysis revealed that the southward-propagating semidiurnal tides to be impeded and then reflected as they arrive at an abrupt, deepened step in the topography of the southern TS. This reflection enhances the amplitudes of the incident semidiurnal tides and contributes to the formation of a nearly standing wave in the eastern TS. The southward-propagating diurnal tides in the TS are connected by the diurnal tides in the northern SCS when the amplitudes of the two tide systems are comparable and their phases nearly equal at the step. This revised version was published online in July 2006 with corrections to the Cover Date.     

Fluid‐fluxed melting and melt loss in a syntectonic contact metamorphic aureole from the Variscan eastern Pyrenees

Open‐system behaviour through fluid influx and melt loss can produce a variety of migmatite morphologies and mineral assemblages from the same protolith composition. This is shown by different types of granulite facies migmatite from the contact aureole of the Ceret gabbro–diorite stock in the Roc de Frausa Massif (eastern Pyrenees). Patch, stromatic and schollen migmatites are identified in the inner contact aureole, whereas schollen migmatites and residual melanosomes are found as xenoliths inside the gabbro–diorite. Patch and schollen migmatites record D1 and D2 structures in folded melanosome and mostly preserve the high‐T D2 in granular or weakly foliated leucosome. Stromatic migmatites and residual melanosomes only preserve D2. The assemblage quartz–garnet–biotite–sillimanite–cordierite±K‐feldspar–plagioclase is present in patch and schollen migmatites, whereas stromatic migmatites and residual melanosomes contain a sub‐assemblage with no sillimanite and/or K‐feldspar. A decrease in X _Fe (molar Fe/(Fe + Mg)) in garnet, biotite and cordierite is observed from patch migmatites through schollen and stromatic migmatites to residual melanosomes. Whole‐rock compositions of patch, schollen and stromatic migmatites are similar to those of non‐migmatitic rocks from the surrounding area. These metasedimentary rocks are interpreted as the protoliths of the migmatites. A decrease in the silica content of migmatites from 63 to 40 wt% SiO₂ is accompanied by an increase in Al₂O₃ and MgO+FeO and by a depletion in alkalis. Thermodynamic modelling in the NCKFMASHTO system for the different types of migmatite provides peak metamorphic conditions ~7–8 kbar and 840 °C. A nearly isothermal decompression history down to 5.5 kbar was followed by isobaric cooling from 840 °C through 690 °C to lower temperatures. The preservation of granulite facies assemblages and the variation in mineral assemblages and chemical composition can be modelled by ongoing H₂O‐fluxed melting accompanied by melt loss. The fluids were probably released by the crystallizing gabbro–diorite, infiltrating the metasedimentary rocks and fluxing melting. Release of fluids and melt loss were probably favoured by coeval deformation (D2). The amount of melt remaining in the system varied considerably among the different types of migmatite. The whole‐rock compositions of the samples, the modelled compositions of melts at the solidus at 5.5 kbar and the residues show a good correlation.