Upper Permian Main Dolomite microbial carbonates as potential source rocks for hydrocarbons (W Poland)

Various microbialite lithofacies were common in the shallow-water environments which flourished under highly saline and arid climate conditions in the Polish part of the Zechstein (Upper Permian) Main Dolomite (Ca2) carbonates. Data came from detailed analysis of 78 cores from wells located at the southern and northern margins of the Main Dolomite basin in west Poland. Microbialite lithofacies are represented by columnar, planar and domal stromatolites, clotted thrombolites and biolaminites developed in high-to-low energy environments within the upper slope, lower parts of oolitic barrier/shoal, restricted lagoon, and tidal flat and tidal channel zones. In barrier environments ooids were predominant whereas in lagoonal settings microbial oncoids and peloids were common. In basinal settings laminated dolomudstones formed which are regarded as hemipelagic and are partly pelagic microbial in origin. Microbial communities coexisted with algae and developed mainly within shallow marine environments. Microbialites are built of cyanobacterial filaments and organo-mineral coccoidal forms possibly of bacterial origin. Organic geochemistry data confirm that organic matter was transformed by cyanobacteria and bacteria which may have played a main role in hydrocarbon generation. This is confirmed by C₂₉ to C₃₅ hopanes, Pr/Ph ratio below 1.0, and the presence of gammacerane as typical for Ca2 profiles. The role and occurrence of algae, as confirmed by C₂₉-steranes, in hydrocarbon generation was possibly minor. Thus it is concluded that the Main Dolomite microbialites could be the likely source rocks for hydrocarbons, with calculated original TOC values from 0.8 to ca 2.0 wt. %. These units also form the reservoir rocks, with porosities reaching 20%.     

Coast formation in an Arctic area due to glacier surge and retreat: The Hornbreen–Hambergbreen case from Spistbergen

Glacierised coasts undergo faster geomorphic processes than unglaciated ones. We have studied changes of the coastal area in southern Svalbard with the glacier bridge between Torell Land and Sørkapp Land since the beginning of the 20th century. The existence of a continuous subglacial depression beneath the Hornbreen–Hambergbreen glacier system has been debated since the 1960s, with inconclusive results. In this study we assess both the subglacial topography and the bathymetry of Hornsund Fjord and Hambergbukta bay. This included ~40 km of radar surveys over the glacial system and sea depth sounding. The extent of the glaciers from maps and satellite images together with digital terrain models and surface elevation data based on GPS profiling were used to analyse geometry changes of the glacier surfaces. The results confirm the existence of a continuous subglacial depression below sea level (c. 40 m deep) between Hornsund and the Barents Sea. The Hornbreen‐Hambergbreen system has changed in shape over the past century, reflecting its dynamic origin and activity, also exemplified by the sequential surges identified since 1899. There was a pre‐surge build‐up event of Flatbreen causing a surge and subsequent lowering of the Hornbreen‐Hambergbreen frontal parts by the 1960s. After, the entire surface lowered, albeit with a delay in the Hornbreen terminal zone. Since the year 2000, Hornbreen terminus has retreated at an average rate of 106 m a^?1; ~50% faster than that of Hambergbreen. If the retreat continues at the 2000–2015 average rate, the ice bridge between Hornsund and Hambergbukta will be broken sometime between 2055 and 2065 and the Hornsund strait will separate Sørkapp Land from the Spitsbergen island. The processes and events described in this study, particularly the effects of the glacier surge, may provide a model for changes likely to occur in other coastal glaciated regions experiencing rapid change. Copyright © 2017 John Wiley & Sons, Ltd.     

Thermodynamic properties and phase stability of wadsleyite II

The thermodynamical stability of a newly observed wadsleyite II phase in the Mg₂SiO₄ system is studied by the density functional theory. The wadsleyite II equation of state has been derived. The phase boundaries of Mg₂SiO₄ polymorphs: wadsleyite, wadsleyite II and ringwoodite are studied using the quasi-harmonic approximation at high external pressures. Clapeyron slopes determined for wadsleyite II–ringwoodite and wadsleyite–wadsleyite II boundaries are 0.0047 and 0.0058 GPa/K, respectively. It is shown that the wadsleyite II phase is not thermodynamically preferred in the pure Mg₂SiO₄ system and will probably not occur between wadsleyite and ringwoodite phases.     

Hybrid event beds dominated by transitional‐flow facies: character,distribution and significance in the Maastrichtian Springar Formation,north‐west Vøring Basin,Norwegian Sea

Hybrid event beds comprising clay‐poor and clay‐rich sandstone are abundant in Maastrichtian‐aged sandstones of the Springar Formation in the north‐west Vøring Basin, Norwegian Sea. This study focuses on an interval, informally referred to as the Lower Sandstone, which has been penetrated in five wells that are distributed along a 140 km downstream transect. Systematic variations in bed style within this stratigraphic interval are used to infer variation in flow behaviour in relatively proximal and distal settings, although individual beds were not correlated. The Lower Sandstone shows an overall reduction in total thickness, bed amalgamation, sand to mud ratio and grain size in distal wells. Turbidites dominated by clay‐poor sandstone are at their most common in relatively proximal wells, whereas hybrid event beds are at their most common in distal wells. Hybrid event beds typically comprise a basal clay‐poor sandstone (non‐stratified or stratified) overlain by banded sandstone, with clay‐rich non‐stratified sandstone at the bed top. The dominant type of clay‐poor sandstone at the base of these beds varies spatially; non‐stratified sandstone is thickest and most common proximally, whereas stratified sandstone becomes dominant in distal wells. Stratified and banded sandstone record progressive deposition of the hybrid event bed. Thus, the facies succession within hybrid event beds records the longitudinal heterogeneity of flow behaviour within the depositional boundary layer; this layer changed from non‐cohesive at the front, through a region of transitional behaviour (fluctuating non‐cohesive and cohesive flow), to cohesive behaviour at the rear. Spatial variation in the dominant type of clay‐poor sandstone at the bed base suggests that the front of the flow remained non‐cohesive, and evolved from high‐concentration and turbulence‐suppressed to increasingly turbulent flow; this is thought to occur in response to deposition and declining sediment fallout. This research may be applicable to other hybrid event bed prone systems, and emphasizes the dynamic nature of hybrid flows.     

Strontium isotope systematics of mixing groundwater and oil-field brine at Goose Lake in northeastern Montana,USA

Groundwater, surface water, and soil in the Goose Lake oil field in northeastern Montana have been affected by Cl⁻-rich oil-field brines during long-term petroleum production. Ongoing multidisciplinary geochemical and geophysical studies have identified the degree and local extent of interaction between brine and groundwater. Fourteen samples representing groundwater, surface water, and brine were collected for Sr isotope analyses to evaluate the usefulness of ⁸⁷Sr/⁸⁶Sr in detecting small amounts of brine. Differences in Sr concentrations and ⁸⁷Sr/⁸⁶Sr are optimal at this site for the experiment. Strontium concentrations range from 0.13 to 36.9 mg/L, and corresponding ⁸⁷Sr/⁸⁶Sr values range from 0.71097 to 0.70828. The local brine has 168 mg/L Sr and a ⁸⁷Sr/⁸⁶Sr value of 0.70802. Mixing relationships are evident in the data set and illustrate the sensitivity of Sr in detecting small amounts of brine in groundwater. The location of data points on a Sr isotope-concentration plot is readily explained by an evaporation-mixing model. The model is supported by the variation in concentrations of most of the other solutes.     

Summer Floods in Central Europe – Climate Change Track?

In Central Europe, river flooding has been recently recognized as a major hazard, in particular after the 1997 Odra /Oder flood, the 2001 Vistula flood, and the most destructive 2002 deluge on the Labe/Elbe. Major recent floods in central Europe are put in perspective and their common elements are identified. Having observed that flood risk and vulnerability are likely to have grown in many areas, one is curious to understand the reasons for growth. These can be sought in socio-economic domain (humans encroaching into floodplain areas), terrestrial systems (land-cover changes – urbanization, deforestation, reduction of wetlands, river regulation), and climate system. The atmospheric capacity to absorb moisture, its potential water content, and thus potential for intense precipitation, are likely to increase in a warmer climate. The changes in intense precipitation and high flows are examined, based on observations and projections. Study of projected changes in intense precipitation, using climate models, for several areas of central Europe, and in particular, for drainage basins of the upper Labe/Elbe, Odra/Oder, and Vistula is reported. Significant changes have been identified between future projections and the reference period, of relevance to flood hazard in areas, which have experienced severe recent floodings.     

Determination of volatile concentrations in fluorapatite of Martian shergottite NWA 2975 by combining synchrotron FTIR,Raman spectroscopy,EMPA, and TEM,and inferences on the volatile budget of the apatite host‐magma

We combined the focused ion beam sample preparation technique with polarized synchrotron‐based FTIR (Fourier transform infrared) spectroscopy, laser‐Raman spectroscopy, electron microprobe analysis (EMPA), and transmission electron microscope (TEM) analysis to identify and quantify structurally bound OH, F, Cl, and CO₃ groups in fluorapatite from the Northwest Africa 2975 (NWA 2975) shergottite. In this study, the first FTIR spectra of the OH‐stretching region from a Martian apatite are presented that show characteristic OH‐bands of a F‐rich, hydroxyl‐bearing apatite. Depending on the method of apatite‐formula calculation and whether charge balance is assumed or not, the FTIR‐based quantification of the incorporated OH, expressed as wt% H₂O, is in variably good agreement with the H₂O concentration calculated from electron microprobe data. EMP analyses yielded between 0.35 and 0.54 wt% H₂O, and IR data yielded an average H₂O content of 0.31 ± 0.03 wt%, consistent with the lower range determined from EMP analyses. The TEM observations implied that the volatiles budget of fluorapatite is magmatic. The water content and the relative volatile ratios calculated for the NWA 2975 magma are similar to those established for other enriched or intermediate shergottites. It is difficult to define the source of enrichment: either Martian wet mantle or crustal assimilation. Comparing the environment of parental magma generation for NWA 2975 with the terrestrial mantle in terms of water content, it displays a composition intermediate between enriched and depleted MORB.     

Prospects for Solar and Space Weather Research with Polish Part of the LOFAR Telescope

The LOw-Frequency ARray (LOFAR) is a new radio interferometer that consists of an array of stations. Each of them is a phase array of dipole antennas. LOFAR stations are distributed mostly in the Netherlands, but also throughout Europe. In the article we discuss the possibility of using this instrument for solar and space weather studies, as well as ionosphere investigations. We are expecting that in the near future the LOFAR telescope will bring some interesting observations and discoveries in these fields. It will also help to observe solar active events that have a direct influence on the near-Earth space weather.     

The heat goes on—changes in indices of hot extremes in Poland

Theoretical and Applied Climatology - On the basis of temperature observations at 60 meteorological stations in Poland, changes in the indices associated with the presence of extremely high air...     

The sanitary state of Pomeranian Bay and Gulf of Gdańsk waters during the flood of 1997

Summary Due to the 1997 summer flood, the Pomeranian and Gdańsk Bays were polluted with a significant amount of bacteriologically contaminated Oder and Vistula rivers waters. The purpose of this study was to determine the sanitary state of both bays during the flood and directly after it, the range of direction of distribution of the bacteriological contamination brought in by Vistula and Oder waters. On the basis of examination results, the sanitary state of the bays waters was found to be worse, particularly with regard to indicators: total bacterial number (at 20 °C and 37 °C) and Most Probable Number (MPN) of coliform and faecal coliform bacteria. Bacteria of the Pseudomonas group(Pseudomonas aeruginosa, Pseudomonas fluorescens), Enterobacteriaceae group (m.in.Proteus vulgaris), as well as enterococci(Streptoccus) and staphylococci(Staphylococcus) were found in water samples from Pomeranian and Gdańsk Bays. In the Pomeranian Bay the waters spread to the west (due to weather conditions), whereas in Gdańsk Bay they remained mainly in the coastal zone and then moved to the east. An improvement in the sanitary state of both bay waters was observed at the end of August. Zusammenfassung W?hrend des Sommer-Hochwassers 1997 wurden die Gew?sser der Pommerschen und der Danziger Bucht mit kontaminiertem Wasser aus den Flüssen Oder und Weichsel verunreinigt. Ziel dieser Arbeit ist es, den Grad der bakteriellen Verunreinigungen durch einstr?mendes Flu?wasser aus Oder und Weichsel in die Pommersche und die Danziger Bucht w?hrend des Hochwassers und direkt danach zu bestimmen. Auf der Basis von Messungen wurde eine Vermehrung von Colibakterien im Wasser beider Buchten unter Berücksichtigung folgender Indikatoren festgestellt: 1. Gesamtzahl an Bakterien (Wassertemperatur 20 °C and 37 °C) und 2. vermuteter Anteil von gesamtcoliformen und f?kalcoliformen Bakterien. Die Wasserproben aus der Danziger und der Pommerschen Bucht enthielten sowohl F?ulnisbakterien(Pseudomonas aeruginosa, Pseudomonas fluorescens) als auch Bakterien aus der Gruppe der Enterobacteriaceae(Proteus vulgaris), Staphylokokken(Staphylococcus) und F?kalstreptokokken(Streptococcus). Infolge Wetterver?nderung verlagerte sich das kontaminierte Wasser aus der Pommerschen Bucht nach Westen. In der Danziger Bucht hingegen blieb das kontaminierte Wasser zun?chst im Küstenbereich und verlagerte sich dann ostw?rts. Ende August wurde eine Verbesserung der Wasserqualit?t in beiden Buchten ermittelt.