Hiatus concretions

The term ‘hiatus concretions’ was introduced for the first time by the late Ehrhard Voigt, a well‐known German bryozoan specialist, in 1968 (originally as Hiatus‐Konkretionen). Hiatus concretions are early diagenetic bodies that formed within the host sediment. In this respect, they are similar in composition to other concretions that are very common in siliciclastic deposits of different ages, some of which are known to contain fossils or minerals. Hiatus concretions, however, differ from conventional concretions in their complex post‐diagenetic history, including exhumation on the sea‐floor, colonization by various encrusting and/or boring organisms during a break in sedimentation, and final burial. Thus, the name ‘hiatus concretions’ refers to the fact that they indicate hiatal surfaces in sedimentary sequences ( Fig. 1 ). It is known that hiatus concretions may have developed during very different time‐spans: for example, within a part of one ammonite subzone (i.e. tens of thousands to a few hundreds of thousands of years) or much longer, during a time embracing more than a stage (i.e. several millions of years). The majority of the hiatus concretions known from the fossil record have carbonate cements, usually calcite, and these are the main focus of this article. Some hiatus concretions, however, are cemented by phosphate minerals.

Figure 1 Open in figure viewer PowerPoint Hiatus concretions in the field. A. A horizon of hiatus concretions weathered out from the Middle Jurassic (Bathonian) clay sediments at Krzyworzeka, Polish Jura, Poland. B. Close‐up of the hiatus concretions.     

Changes of chromium concentration in alluvial sediments of the Obra river valley

In this research work, changes in concentration of the chosen chemical element in alluvial sediments have been used to estimate the relative age of floodplain deposits. The research concerning changes of chromium concentration in alluvial deposits was done in the Obra river valley near Międzyrzecz (Western Poland). Chromium was chosen because of its low ability to migrate in groundwater environment. Moreover, this chemical element was used in the process of dyeing textures in Międzyrzecz between the sixteenth and the nineteenth century. Confrontation of changes in chromium concentration and age of alluvial sediments (age estimated in years BP using radiocarbon method) have shown that the sediments with higher chromium contents are much older than the period of development of the weaving industry in Międzyrzecz. Therefore, it is not possible to use changes in chromium concentration to estimate relative age of floodplain sediments. Despite information in the literature about low migration ability of this chemical component (Macioszczyk and Dobrzyński in Hydrogeochemia: strefy aktywnej wymiany wód podziemnych. PWN, Warszawa, 2002; Ball and Izbicki in Appl Geochem 19:1123–1135, 2004) migration of chromium is so intensive that distinct changes in its concentration are observed even before the period of increased human activity.

Determination of particulate organic carbon (POC) in seawater: The relative methodological importance of artificial gains and losses in two glass-fiber-filter-based techniques

Particulate matter in aquatic systems is an important vehicle for the transport of particulate organic carbon (POC). Its accurate measurement is of central importance for the understanding of marine carbon cycling. Previous work has shown that GF/F-filter-based bottle-sample-derived concentration estimates of POC are generally close to or higher than large-volume in-situ-pump-derived values (and in some rare cases in subzero waters are up to two orders of magnitude higher). To further investigate this phenomenon, water samples from the surface and mid-water Northeast Atlantic and the Baltic Sea were analyzed. Our data support a bias of POC concentration estimates caused by adsorption of nitrogen-rich dissolved organic material onto GF/F filters. For surface-ocean samples the mass per unit area of exposed filter and composition of adsorbed material depended on the filtered volume. Amounts of adsorbed OC were enhanced in the surface ocean (typically 0.5 μmol cm^− 2 of exposed filter) as compared to the deep ocean (typically 0.2 μmol cm^− 2 of exposed filter). These dependencies should be taken into account for future POC methodologies. Bottle/pump differences of samples that were not corrected for adsorption were higher in the deep ocean than in the surface ocean. This discrepancy increased in summer. It is shown that POC concentration estimates that were not corrected for adsorption depend not only on the filtered volume, true POC concentration and mass of adsorbed OC, but also on the filter area. However, in all cases we studied, correction for adsorption was important, but not sufficient, to explain bottle/pump differences. Artificial formation of filterable particles and/or processes leading to filterable material being lost from and/or missed by sample-processing procedures must be considered. It can be deduced that the maximum amounts of POC and particulate organic nitrogen (PON) that can be artificially formed per liter of filtered ocean water are  3–4 μM OC (5–10% of dissolved OC) and  0.2–0.5 μM ON (2–10% of dissolved ON), respectively. The relative sensitivities of bottle and pump procedures, and of surface- and deep-ocean material, to artificial particle formation and the missing/losing of material are evaluated. As present procedures do not exist to correct for all possible biasing effects due to artificial particle formation and/or miss/loss of filterable material, uncertainties of filtration-based estimates of POC concentrations need further testing. The challenge now is to further constrain the magnitude of the biasing effects that add to the adsorption effect to reduce the uncertainties of estimates of POC concentrations, inventories and fluxes in the ocean.     

The evolution of the Onaping Formation at the Sudbury impact structure

Abstract– The 1.4–1.6 km thick Onaping Formation consists of a complex series of breccias and “melt bodies” lying above the Sudbury Igneous Complex (SIC) at the Sudbury impact structure. Based on the presence of shocked lithic clasts and various “glassy” phases, the Onaping has been described as a “suevitic” breccia, with an origin, at least in part, as fallback material. Recent mapping and a redefined stratigraphy have emphasized similarities and differences in its various vitric phases, both as clast types and discrete intrusive bodies. The nature of the Onaping and that of other “suevitic” breccias overlying impact melt sheets is reviewed. The relative thickness, internal stratigraphic and lithological character, and the relative chronology of depositional units indicate multiple processes were involved over some time in the formation of the Onaping. The Sudbury structure formed in a foreland basin and water played an essential role in the evolution of the Onaping, as indicated by a major hydrothermal system generated during its formation. Taken together, observations and interpretations of the Onaping suggest a working hypothesis for the origin of the Onaping that includes not only impact but also the interaction of sea water with the impact melt, resulting in repeated explosive interactions involving proto‐SIC materials and mixing with pre‐existing lithologies. This is complicated by additional brecciation events due to the intrusion of proto‐SIC materials into the evolving and thickening Onaping. Fragmentation mechanisms changed as the system evolved and involved vesiculation in the formation of the upper two‐thirds of the Onaping.     

Pulsar PSR B2303+30: a single system of drifting subpulses, moding and nulling

Analyses of multiple pulse sequences of the pulsar PSR B2303+30 reveal two distinct emission modes. One mode (B) follows a steady even–odd pattern and is more intense. The second mode (Q) is characteristically weak, but has intermittent drift bands with a periodicity of approximately 3 P ₁/cycle, and nulls much more frequently than the B mode. Both modes occur with roughly equal frequency, and their profiles have a similar single-humped form with a slight asymmetry. Our observations and analyses strongly suggest that the subpulse drift rates in both modes are linked in a series of cycles, which can be modelled as relaxing oscillations in the underlying circulation rate.     

Removing cosmic-ray hits from CCD images in real-time mode by means of an artificial neural network

A feed-forward artificial neural network has been implemented to the problem of removing cosmic-ray hits (CRH) from CCD images. The results of a number of tests demonstrate the effectiveness of this method especially for undersampled stellar profiles. The problem of optimal and low price preparing of training data, which could enable real-time or at least fast post-processing filtering out of CRH is discussed. The training and test ensembles were composed of a number of synthetic stellar profiles involving different S/N ratios and CRH images taken from real data. Certain aspects of the network’s architecture and its training efficiency for different modes of the back-propagation procedure as well as for the pre-process normalization of data have been examined. It is shown that for training set composed of stellar images and CRH at a ratio of 1:2 recognition can reach 99% in the case of stars and 96% for CRH. To determine the extent to which the cognition power of a network trained using an ensemble of circular symmetric stellar profiles of a given radius can be generalised the test data included stellar profiles of different radii, as well as elongated profiles. The goal was to mimic temporal changes in seeing as well as such problems as image defocusing, the lack of isoplanatism and improper sideral tracking of a telescope. The experiments provided us with the conclusion that for S/N > 10 excellent classification property is maintained in cases where the change in the radius of a circular profile is up to 30%, as well as for elongated profiles where the longest dimension is almost double that of the shortest one. Moreover, the generalization capability has been investigated for test images of synthetic pairs of overlapping stars with different distances between components. Almost 99% recognition efficiency was achieved even if the separation was nearly three times the radius of the stellar profile, a case when two stars could be analyzed by appropriate software as separate objects. The example of removal of CRH from real CCD images is presented to give an idea of how an algorithm based on a neural network can work in practice. The result of such an experiment appears fully consistent with the conclusions drawn from the tests made on synthetic data.     

Towards an Understanding of Radial Velocity Shift in Uv Spectra of Symbiotic Stars

A systematic redshift of high ionization resonance emission lines relative to the intercombination lines was found by Friedjung et al. (1883, A & A 126, 4071983) in the UV spectra of a number of symbiotic binaries. The interpretation was not then clear. We present a study of archival IUE and GHRS/HST spectra of the symbiotic binary CI Cyg. The shift varies during the orbital cycle which can be understood in terms of the presence of strong circum-binary line absorption formed in an outer expanding region.     

CHOMIK: a multi-method approach for studying Phobos

CHOMIK is the name of a penetrator constructed for sampling and retrieval of Phobos surface material. It formed an integral part of the Phobos Sample Return Mission. In this paper we present its construction and intended mode of operation, since the concept is still viable for future missions either to Phobos or to other small bodies of similar dimensions. We take Phobos as an example to describe the science case for such an instrument and how it might be utilized to resolve important open issues regarding the origin of the Martian moons. Concerning the latter, we place emphasis on measurement techniques and analysis tools for mapping trace element concentrations in returned sample.     

Pleurozium schreberi as bioindicator of mercury pollution in heavily industrialized region

This research is continuation of the investigation of metal accumulation in native and transplanted moss Pleurozium schreberi in the most industrialized and affected region in Poland (Upper Silesia). We tested the hypotheses that in Upper Silesia transplants of P. schreberi may be used in a 90 days bioindication experiment in case native specimens are absent; a 90 days exposure of transplanted P. schreberi was long enough for evaluation of Hg pollution of the environment. An assay was carried out with native mosses at 27 polluted sites and mosses from an uncontaminated control site transplanted to the same 27 polluted sites. P. schreberi collected from the same sites as classified for more and less polluted basing on Pb and Zn concentrations show quite different pattern of pollution with mercury; The accumulation of Hg by the transplants increased much faster in the first 45 days of the experiment (accumulation factor 1.5–6.7; mean 3.4?±?0.5) in comparison with the second period from day 45 to 90 (accumulation factor 1.0–1.6; mean 1.2?±?0.1). The 90 days exposure of transplanted P. schreberi was long enough for evaluation of Hg pollution of the environment. Transplants of P. schreberi may be used in a 90 days bioindication experiment in case native specimens are absent.     

Great-power politics,order transition,and climate governance: insights from international relations theory

The complex politics of climate change cannot be properly understood without reference to deeper geopolitical trends in the wider international system. Chief among these is the growing resurgence of ‘great-power politics’ between China and the US, along with failures of socialization and enmeshment into global governance structures in relation to these two powers. Traditional theoretical frameworks have failed to adequately account for these developments. Nonetheless, this current great-power contestation is at the core of an order transition that has prevented the large-scale institutional redesign required to remove deadlocks in existing global governance structures, including climate governance. Examples from the 2009 Copenhagen Climate Change Conference provide ample evidence for these claims. The slow progress of the climate change negotiations are due not just to the politics of the issue itself, but to the absence of a new political bargain on material power structures, normative beliefs, and the management of the order amongst the great powers. Without such a grand political bargain, which could be promoted through a forum of major economies whose wide-ranging remit would go beyond single issues, the climate change regime is only ever likely to progress in a piecemeal fashion.

Policy relevance

Despite the achievements of the 2012 Doha Climate Change Conference, the climate negotiations are not on course to limit warming to 2 °C, and thereby avoid ‘dangerous’ climate change. Several factors have been invoked to account for such slow progress: notably, the nature of the climate change problem itself, the institutional structure of the climate regime, and lack of political will among key players. An alternative explanation is proposed such that the failure to seriously address climate change – as well as other global problems – reflects a resurgent meta-struggle between the ‘great powers’ of China and the US over the nature of the global order. Without such a broader understanding of the deeper dynamics underlying the stalemates of the climate change negotiations, there is little chance of turning those negotiations around.