Interpretation of crystalline spheroidal structures in igneous rocks

Attention is drawn to the nomenclature of spheroidal structures, and the textures are interpreted in terms of central, marginal or disseminated crystal nucleation. The essential physical characteristics of the nucleation and growth of crystals, bubbles of a low density gaseous phase, and globules of liquid with a density comparable with that of the magma are described. It seems likely that crystallization within an immiscible liquid fraction would proceed from disseminated nuclei thus producing a rock texture, rather than a cavity filling texture developed from marginal nucleation which is a characteristics of crystallization within gas cavities. Structures of mineralogical features which clearly indicate early liquid immiscibility or subsequent retrograde boiling are rarely preserved because of the nature of the processes, but it is suggested that both processes play a greater part in the formation of certain igneous rocks than in generally realized.     

On the electrical conductivity of air inside buildings

Summary Simultaneous measurements of the electrical conductivity of air inside and outside of buildings have been performed with continuously recording electronic instruments of high sensitivity and short time constant. It appears that the electrical conductivity, a measure of the natural ionization of air, is one atmospheric-electric parameter that can manifest itself inside occupied buildings without appreciable difference in physical character from outside values.The probable importance of these experimental results for the field of bioclimatology is pointed out and the possibility is discussed that the electrical conductivity of air might be one of the searched—for parameters in associating physiological phenomena with weather changes.

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Zusammenfassung Gleichzeitige Messungen der luftelektrischen Leitfähigkeit im Freien und innerhalb von Gebäuden wurden mit kontinuierlich registrierenden Röhreninstrumenten von großer Empfindlichkeit und kurzer Zeitkonstante durchgeführt. Es wurde gefunden, daß die Leitfähigkeit als Maß der natürlichen Luftionisierung eine luftelektrische Größe darstellt, die ohne wesentliche physikalische Beeinflussung in bewohnte Gebäude einzudringen vermag.Die mögliche Bedeutung dieser experimentellen Ergebnisse für das Gebiet der Bioklimatologie wird angedeutet und die Wahrscheinlichkeit diskutiert, daß die luftelektrische Leitfähigkeit einen der noch unbestimmten Faktoren des Zusammenhanges physiologischer Erscheinungen mit Wetterveränderungen darstellen könnte.

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Résumé Des instruments électroniques à enregistrement continu de haute fidelité et ayant une constante de courte durée ont permis de prendre des mesures simultanées de la conductivité électrique de l'air à l'intérieur et à l'extérieur de bâtiments. Il semble que la conductivité électrique, mesure de l'ionisation naturelle de l'air, soit un paramètre de l'électricité atmosphérique qui peut se manifester à l'intérieur de bâtiments habités sans différence appréciable de caractéristiques physiques avec celles des valeurs extérieures.L'importance probable de ces résultats expérimentaux dans le champ de la bioclimatologie est indiquée, et la possibilité que la conductivité atmosphérique puisse être un des paramètres recherchés dans l'association des phénomènes physiologiques avec des changements du temps est étudiée.

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With 1 Figure.

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Publication No. 25 of the Institute of Geophysics, University of California at Los Angeles. The research reported in this paper has been sponsored in part by the Geophysics Research Directorate of the Air Force Cambridge Research Center, Air Research and Development Command, under Contract No. AF 19(122)-254.     

Observing total solar eclipses from near the edge of the predicted path

Suitable observations from various locations in the predicted path of a total solar eclipse can provide information about the relative positions and shapes of the Sun and Moon to about ±0.02. The total solar eclipse of 1972, July 10 was observed from locations near the edges of its predicted path. The durations of the limb phenomena were greatly enhanced. Preliminary analysis of the observations shows that the eclipse shadow passed 3 km northeast of its predicted path.Communication presented at the conference on Lunar Dynamics and Observational Coordinate Systems held January 15–17, 1973 at the Lunar Science Institute, Houston, Tex., U.S.A.     

X-radiation (E > 10keV), Hα and microwave emission during the impulsive phase of solar flares

A study has been made of the variation in hard (E 10 keV) X-radiation, H and microwave emission during the impulsive phase of solar flares. Analysis shows that the rise-time in the 20–30-keV X-ray spike depends on the electron hardness, i.e., t _rise exp (0.87 ). The impulsive phase is also marked by an abrupt, very intense increase in H emission in one or more knots of the flare. Properties of these H kernels include: (1) a luminosity several times greater than the surrounding flare, (2) an intensity rise starting about 20–30 s before, peaking about 20–25 s after, and lasting about twice as long as the hard spike, (3) an effective diameter of 3000–6000 km for class 1 flares, representing less than 1/8-1/2 of the main flare, (4) a location lower in the chromosphere than the remaining flare, (5) essentially no expansion prior to the hard spike, (6) a position within 6000 km of the boundary separating polarities, usually forming on both sides of the neutral line near both feet of the same tube of force, (7) a shape often resembling isogauss contours of the photospheric field indicated on magnetograms and (8) total radiated energy less than l/50 that of the hard electrons. Correspondingly, impulsive microwave events are characterized by: (1) the detection of a burst at 8800 MHz for every X-ray spike ifthe number of electrons above 100 keV is greater than 10³³, (2) great similarity in burst structure with 20–32 keV X-rays but only at f > 5000 MHz, (3) typical low frequency burst cutoff between 1400–3800 MHz, and (4) maximum emission at f > 7500 MHz. Finally the H, X-ray and microwave data are combined to present a picture of the impulsive phase consistent with the above observations.     

Potentiometric and F nuclear magnetic resonance spectroscopic study of fluoride substitution in the GaAl12 polyoxocation: implications for aluminum (hydr)oxide mineral surfaces

Fluoride replacement of oxygens in the GaO₄Al₁₂(OH)₂₄(H₂O)127+(aq) molecule [GaAl₁₂] was studied via ¹⁹F nuclear magnetic resonance (NMR) at 4 < pH < 5 and 278 K in order to elucidate similar reactions at the surfaces of clays. Peaks are identified in the ¹⁹F-NMR spectra that correspond to both terminal and bridging fluorides on the GaAl₁₂ molecule, with relative peak positions similar to those previously identified in fluoridated aluminum (hydr)oxide mineral surfaces (Nordin, J. P., Sullivan, D. J., Phillips, B. L., and Casey, W. H. [1999], “Mechanisms for fluoride-promoted dissolution of bayerite [β-Al(OH)₃(s)] and boehmite [γ-AlOOH(s)]-¹⁹F-NMR spectroscopy and aqueous surface chemistry,” Geochim. Cosmochim. Acta63, 3513-3524). Fluoride substitutes for oxygen at three different sites in the GaAl₁₂ molecule, but at dramatically different rates.The kinetics of fluoride substitution follow a rate law that includes parallel and reversible transfer of fluoride from nonbridging sites to the two bridging sites. The essential features of the rate law are as follows: (1) fluoride replaces bound water molecules (η-OH₂) within minutes at 278 K at rates that are quantitatively similar to fluoride uptake by Al(H₂O)63+(aq) to form AlF²⁺(aq) at similar conditions; (2) fluoride substitutes onto the two topologically distinct μ₂-OH sites at different rates, as was previously observed for oxygen exchange, but here, the reaction is complete in hours to days at 278 K. Most importantly, rates of fluoride substitution onto μ₂-OH sites are 10² times more rapid than the corresponding rates of oxygen exchange with bulk waters, indicating that fluoride considerably labilizes the molecule, as is also observed at the surfaces of minerals. The largest cause of this labilization is the reduced molecular charge on the GaAl₁₂ upon replacement of bound waters by fluoride, which for mineral surfaces corresponds to a reduction in surface charge density.     

A comparison of sediment microbial communities associated with<Emphasis Type="Italic">Phragmites australis</Emphasis> and<Emphasis Type="Italic">Spartina alterniflora</Emphasis> in two brackish wetlands of New Jersey

The extensive spread ofPhragmites australis throughout brackish marshes on the East Coast of the United States is a major factor governing management and restoration decisions because it is assumed that biogeochemical functions are altered by the invasion. Microbial activity is important in providing wetland biogeochemical functions such as carbon and nitrogen cycling, but there is little known about sediment microbial communities inPhragmites marshes. Microbial populations associated with invasivePhragmites vegetation and with native salt marsh cordgrass,Spartina alterniflora, may differ in the relative abundance of microbial taxa (community structure) and in the ability of this biota to decompose organic substrates (community biogeochemical function). This study compares sediment microbial communities associated withPhragmites andSpartina vegetation in an undisturbed brackish marsh near Tuckerton, New Jersey (MUL), and in a brackish marsh in the anthropogenically affected Hackensack meadowlands (SMC). We use phospholipid fatty acid (PLFA) analysis and enzymataic activity to profile sediment microbial communities associated with both plants in each site. Sediment analyses include bulk density, total organic matter, and root biomass. PLFA profiles indicate that the microbial communities differ between sites with the undisturbed site exhibiting greater fatty acid richness (62 PLFA recovered from MUL versus 38 from SMC). Activity of the 5 enzymes analyzed (β-glucosidase, acid phosphatase, chitobiase, and 2 oxidases) was higher in the undisturbed site. Differences between vegetation species as measured by Principal Components Analysis were significantly greater at the undisturbed MUL site than at SMC, and patterns of enzyme activity and PLFAs did not correspond to patterns of root biomass. We suggest that in natural wetland sediments, macrophyte rhizosphere effects influence the community composition of sediment microbial populations. Physical and chemical site disturbances may impose limits on these rhizosphere effects, decreasing sediment microbial diversity and potentially, microbial biogeochemical functions.     

Preliminary evidence for human fecal contamination in corals of the Florida Keys,USA

Corals and reef environments are under increased stress from anthropogenic activities, particularly those in the vicinity of heavily populated areas such as the Florida Keys. The potential adverse impacts of wastewater can affect both the environment and human health; however, because of the high decay rate of bacterial indicators in coral reef waters it has been difficult to document the presence of microbial contaminants and to assign risks in these environments. Here we show initial evidence that microorganisms associated with human feces are concentrated along the surface of coral heads relative to the overlying water column in the Florida Keys. Bacterial indicators (fecal coliform bacteria, enterococci or Clostridium perfringens) were detected in 66.7% of the coral surface microlayer (CSM) samples at levels between five and 1000 CFU/100 ml, but were found infrequently and at low numbers in the overlying water column ( < or = 2.5 CFU/100 ml). Similarly, enterovirus nucleic acid sequences, an indicator of human-specific waste, were detected in 93.3% of the CSM samples and only once in the water column by cell culture. Results show that coral mucus may accumulate enteric microorganisms in reef environments, and may indicate a risk to public and environmental health despite low indicator levels in the surrounding water.     

SECIS: The Solar Eclipse Coronal Eclipse Imaging System

The Solar Eclipse Coronal Imaging System (SECIS) is an instrument designed to search for short-period modulations in the solar corona seen either during a total eclipse or with a coronagraph. The CCD cameras used in SECIS have the capability of imaging the corona at a rate of up to 70 frames a second, with the intensities in each pixel digitised in 12-bit levels. The data are captured and stored on a modified PC. With suitable optics it is thus possible to search for fast changes or short-period wave motions in the corona that will have important implications for the coronal heating mechanism. The equipment has been successfully tested using the Evans Solar Facility coronagraph at National Solar Observatory/Sacramento Peak and during the 11 August 1999 eclipse at a site in north-eastern Bulgaria. The instrument is described and preliminary results are outlined.     

Multi-wavelength observations of the 1998 September 27 flare spray

We report on observations of a large eruptive event associated with a flare that occurred on 27 September 1998 made with the Richard B. Dunn Solar Telescope at Sacramento Peak Observatory (several wave bands including off-line-center H), in soft and hard X-rays (GOES and BATSE), and in several TRACE wave bands (including Feix/x 171 Å, Fexii 195 Å, and Civ 1550 Å). The flare initiation is signaled by two H foot-point brightenings which are closely followed by a hard X-ray burst and a subsequent gradual increase in other wavelengths. The flare light curves show a complicated, three-component structure which includes two minor maxima before the main GOES class C5.2 peak after which there is a characteristic exponential decline. During the initial stages, a large spray event is observed within seconds of the hard X-ray burst which can be directly associated with a two-ribbon flare in H. The emission returns to pre-flare levels after about 35 min, by which time a set of bright post-flare loops have begun to form at temperatures of about 1.0–1.5 MK. Part of the flare plasma also intrudes into the penumbra of a large sunspot, generally a characteristic of very powerful flares, but the flare importance in GOES soft X-rays is in fact relatively modest. Much of the energy appears to be in the form of a second ejection which is observed in optical and ultraviolet bands, traveling out via several magnetic flux tubes from the main flare site (about 60° from Sun center) to beyond the limb.     

Winter daily precipitation variability over the South West Peninsula of England

Summary Daily precipitation totals for five consecutive winters (1995–99) were obtained for 127 stations in Devon and Cornwall to explore spatial variations in rainfall. This dataset was assembled with the explicit aim of assessing the appropriateness of current arrangements for daily rainfall forecasts in the SW Peninsula of England. Firstly, the extent to which fundamental geographic variables determine precipitation was investigated by correlating each station’s mean wet day amount (WDA) and percentage of wet days (PERWET) with altitude, latitude, longitude and distance from the coast. Altitude emerged as the most important control on precipitation, with a two-variable multiple linear regression model containing altitude and latitude being able to explain 39.3% (29.8%) of the variance in WDA (PERWET) values. The main spatial modes of variability in the region’s precipitation field were identified by using S mode principal components analysis (PCA). Six PCs were statistically significant and explained 83.4% of the geographic variance in precipitation over Devon and Cornwall. The components were interpreted physically by examining the synoptic flow environment (pressure and wind anomalies) on days with high positive and negative PC scores. Explaining 25.1% of the variance, the most important pattern (PC1) depicts a location’s degree of exposure or shelter in a moist, unstable W–NW airflow. The higher PCs describe modes of variability that accentuate rainfall in East Devon (PC2), Cornwall (PC3), Dartmoor and Bodmin Moor (PC4), South Devon (PC5), and North Cornwall and NW Devon (PC6) relative to other areas of the Peninsula. Finally, a winter precipitation regionalisation was derived by applying agglomerative hierarchical cluster analysis to the PC loadings of the significant components. In most cases, the six coherent precipitation regions do not reflect the familiar administrative or topographic areas used for forecasting, suggesting that forecasts issued on such a basis are likely to be insufficiently detailed and misleading.