An infrared and Raman spectroscopic study of gypsum at high pressures

 We present Raman and infrared spectra of gypsum to 21 GPa at 300 K. Our measurements encompass the internal modes of the (SO₄)⁻⁴ group that lie between 400 and 1150 cm⁻¹, hydroxyl-stretching vibrations between 3200 and 3600 cm⁻¹, and a libration and bending vibrations of the molecular H₂O group. All vibrations of the sulfate group have positive pressure shifts, while the hydroxyl-stretching and -bending vibrations have a mixture of positive and negative pressure shifts: the effect of pressure on the hydrogen bonding of the water molecule thus appears to be complex. Near 5 GPa, the two infrared-active bending vibrations of the water molecule coalesce, and the morphology of the hydroxyl-stretching region of the spectrum shifts dramatically. This behavior is consistent with a pressure-induced phase transition in gypsum in the vicinity of 5–6 GPa, which is observed to be reversible on decompression to zero pressure. The spectral observations are consistent with the onset of increased disorder in the position of the water molecule in gypsum: the sulfate vibrations are largely unaffected by this transition. The Raman-active symmetric stretch of the sulfate group undergoes an apparent splitting near 4 GPa, which is interpreted to be produced by Fermi resonance with an overtone of the symmetric bending vibration. The average mode Grüneisen parameter of the 20 vibrational modes we sample is less than 0.05, in contrast to the bulk thermal Grüneisen parameter of 1.20. Accordingly, the vibrations of both water and sulfate units within gypsum are highly insensitive to volumetric compaction. Therefore, in spite of the changes in the bonding of the water unit near 5 GPa, metastably compressed gypsum maintains strongly bound molecular-like units to over 20 GPa at 300 K. Received: 31 July 2000 / Accepted: 5 April 2001     

Climate Change and Cryptosporidiosis: A Qualitative Analysis

The effects of climate change on drinking-waterborne cryptosporidiosis transmission in the United States are analyzed using an influence diagram representation of epidemic development. Results from a systematic qualitative analysis indicate that climate change will have little effect on cryptosporidiosis incidence if the United States continues to be wealthy and maintains its commitment to public health. The major impact will, instead, be the additional costs of adapting to new climate regimes in order to avoid drinking-waterborne disease risk. These costs, for the most part, will be from improved monitoring and treatment of drinking water. The consequences of disaster scenarios are also considered. These, too, suggest that climate change per se will be a poor predictor of waterborne cryptosporidiosis in countries with high standards of living. Rather, the risk of epidemics will depend on the interplay between population, public health investment, infrastructure maintenance, emergency planning/response capabilities, water-treatment technologies, drinking-water regulations, and climate.     

The relationship between synoptic scale airflow direction and daily rainfall: a methodology applied to Devon and Cornwall, South West England

Summary Trans-scale relationships are established between fluctuations in the direction of the geostrophic flow over the British Isles and spatial variations in rainfall over Devon and Cornwall, South West England. The rationale for using such an approach is to provide the basis for assessing changes to the region’s rainfall climatology that may result from possible future enhanced greenhouse effect forced alterations to large-scale wind flow patterns. A new method, the concentration factor (CF), that relates rainfall totals to the frequency of the flow, is applied to investigate spatial variations in rainfall totals at twelve stations in the two counties under eight wind direction groups (N, NE, E, SE, S, SW, W, NW). S and SW flow types are found to produce the highest daily rainfall totals at all locations, with the three easterly groups (NE, E, SE) yielding higher daily precipitation intensities than the maritime NW group. Inter-annual and seasonal variations in daily wind direction – rainfall (WD/R) relationships are then assessed at two contrasting sites in Cornwall (St. Mawgan, Culdrose) using 40 years of data (1957–96). In general, there is a trend over this period toward maritime airflows (S, SW, W, NW) producing higher daily rainfall totals, with the continental groups (N, NE, E, SE) yielding lower totals relative to their frequency of occurrence. The trend toward maritime airflows producing higher rainfall totals is in line with recent trends in the North Atlantic Oscillation (NAO). Notable seasonal variations in WD/R relationships over Cornwall are interpreted in terms of the location’s exposure to the prevailing wind, sea temperature variations and the orography of the South West Peninsula. Received October 23, 2000/Revised February 2, 2001     

Alluvial storage and the long-term stability of sediment yields

Several recent studies have shown general consistency of fluvial denudation rates over long time periods, or historical and contemporary sediment yields of the same general magnitude as sediment yields or accumulation rates over geologic time. This consistency of fluvial sediment export from some drainage basins, despite substantial climate, hydrological, ecological, base level, and other environmental changes, suggests that long‐term sediment yields may be controlled by factors that are independent of and overwhelm environmental changes (e.g. tectonics), or that the fluvial sediment system is at some level dynamically stable. The latter is explored via a model based on the notion that all debris produced by weathering within a drainage basin over any time period is either retained as part of the regolith, transported out of the basin as solid or dissolved sediment yield, or stored as alluvium within the fluvial system. This system is dynamically stable if alluvium is always potentially available for transport; e.g. to be converted to yield, and if regolith development exerts a negative feedback on weathering rates. This supports the argument that the long‐term consistency of sediment yields (where it exists) may be attributable to the storage and remobilization of alluvium, which buffers the system against environmental change. Environmental changes are manifested primarily in reorganizations within the fluvial sediment system, such as variations between net increases and decreases in alluvial storage, and changes in the spatial locus of deposition. These ideas are illustrated and tested using data from the lower Trinity River in southeast Texas.     

Paleoecology of late-glacial peats from the bering land bridge, Chukchi Sea shelf region, northwestern Alaska

Insect fossils and pollen from late Pleistocene nonmarine peat layers were recovered from cores from the shelf region of the Chukchi Sea at depths of about 50 m below sea level. The peats date to 11,300−11,000 yr B.P. and provide a limiting age for the regional Pleistocene-Holocene marine transgression. The insect fossils are indicative of arctic coastal habitats like those of the Mackenzie Delta region (mean July TEMPERATURES = 10.6–14°C) suggesting that 11,000 yr ago the exposed Chukchi Sea shelf had a climate substantially warmer than modern coastal regions of the Alaskan north slope. The pollen spectra are consistent with the age assignment to the Birch Interval (14,000–9000 yr B.P.). The data suggest a meadow-like graminoid tundra with birch shrubs and some willow shrubs growing in sheltered areas.     

Partial molal volume calculations for the dissolution of aged amorphous silica in salt water and seawater at 0–2°C

Measurement of solubility as a function of pressure allows calculation of $\text{3}\text{V}\text{?}{}_1$. Using this experimental approach, the best estimate of $\text{3}\text{V}\text{?}{}_1$ for the dissolution of aged amorphous silica in salt water or seawater at 0–2°C is ?9.9 cm³ mol^?1 (standard error = 0.4 cm³ mol^?1). This gives , which compares well with other published values of .     

Geophysical observations pertaining to solid-state convection in the terrestrial planets

We present a broad-based review of the observational evidence that pertains to or otherwise implies solid-state convection to be occurring (or have occurred) in the interiors of the terrestrial planets.For the Earth, the motion of the plates is prima facie evidence of large-scale mantle convection. Provided we understand upper-mantle thermal conductivity correctly, heat flow beneath the old ocean basins may be too high to be transported conductively from the upper mantle through the base of the lithosphere and therefore convection on a second smaller scale might be operative. The horizontal scale of plate dimensions implies, due to typical cell aspect ratios observed in convection, that the motion extends to the core-mantle boundary. Improved global data coverage and viscoelastic modeling of isostatic rebound due to Pleistocene deglaciation imply a uniform mantle viscosity, and thus indicate that whole-mantle convection could exist. Additionally, there is some seismic evidence of lithospheric penetration to depths deeper than 700 km. We discuss some salient features and assumption boundedness of arguments for convection confined to the upper mantle and for convection which acts throughout the mantle since the vertical length scale has a profound effect upon the relevance of geophysical observations. The horizontal form of mantle convection may be fully three-dimensional with complex planform and, therefore, searching for correlative gravity patterns in the ocean basins may not be useful without additional geophysical constraints. Many long-wavelength gravity anomalies may arise from beneath the lithosphere and must be supported dynamically, although thermal convection is not a unique explanation. Topography is an additional geophysical constraint, but for wavelengths greater than a few hundred kilometers, a general lack of correlation exists between oceanic residual gravity and topography, except at specific locations such as Hawaii. Theoretical calculations predict a complex relationship between these two observational types. Oceanic gravity data alone shows no regular planform and there is no correlation with any small-scale convective pattern predicted by laboratory experiments.All of the observational evidence argues against Martian plate tectonics occurring now or over much of the history of this planet, but lack of plate tectonics is not an argument against interior convection. The Tharsis uplift on Mars may have resulted from convective processes in the mantle, and the present-day gravity anomaly associated with Tharsis must be supported by the finite strength of the lithosphere or by mantle convection. Stresses imparted by the present topographic load would be greater than a kilobar, in excess of long-term finite strength. Observed fracture patterns are probably a direct result of this load, and the key question concerns the level of resultant strain relief. The global topographic and geomorphic dichotomy between the northern and southern hemisphere required a solid-state flow process to create the accompanying center-of-figure to center-of-mass offset.Lunar heat flow values, in analogy with oceanic heat flow on the Earth, strongly imply a convective mechanism of heat transport in the interior which, based on seismic Q values, is limited to the lower mantle. The presence of moonquakes in this region does not preclude solid-state convective processes. Lunar conductivity profiles provide no information on convection because of the difficulty in conductivity modeling, uniqueness of models, and the uncertainty in the conductivity-temperature relationship. The excess oblateness of the lunar figure over the hydrostatic value does not require convective support; in fact, such a mechanism is unlikely.The presence of a dipole magnetic field on Mercury does not provide a constraint on mantle convection unless its existence can be inextricably linked to a molten core. The non-hydrostatic shape of the equatorial figure, required for the observed $\text{3}\text{2}$ resonance between Mercury's rotational and orbital periods, is most likely related to surface processes, as opposed to convection. The $\text{3n}\text{2}$ resonance implies escape from a 2n resonance and, therefore, is related to the question of a molten core. Further dynamical data is needed to constrain interior models.Interpretation of limited radar imagery for the surface of Venus is enigmatic in terms of plate tectonics and therefore interior convection. Linear tensional and possibly compressional features are observed, but there are also crustal regions which appear to show large impact structures and are thus geologically old and may not have been recycled.     

Heavy metals in somerset marine organisms

Several independent studies of heavy metal pollution in the Severn Estuary and Bristol Channel are in progress. The County Health Department and Public Analyst have been examining the accumulation of metals in marine shore animals and the food chain, and report their results and conclusions.