Flares associated with EFR's (Emerging Flux Regions)

I examined a moderately active sunspot group, McMath 9735, and found that 15 of 16 flares observed in 1968, October 20–21 occurred near, and were preceded by, at least one of several EFR's (Emerging Flux Regions) in the area. Flares were larger and more numerous when: (1) the EFR appeared close to already existing spots, (2) a large amount of filament reorientation was occurring, and when (3) the EFR was most active, i.e., it was increasing in area and brightness and was accompanied by violent surging and great brightness fluctuations at the feet of the dark fibrils. Only two flares occurred at an inverted EFR, i.e., a leading spot with f polarity, however the largest event (2B) of the 15 quickly spread to this region after starting in a different EFR. A sunspot appeared in the inverted emerging flux region less than three hours after the flares. However this is thought to be merely an indication of the growing EFR and, therefore, a secondary effect.     

Kα line emission during solar X-ray bursts

K X-ray line emission from S, Ar, Ca and Fe is calculated for conditions likely to exist in solar flares. We consider both the non-thermal and thermal phases of flares as indicated by X-ray observations. Impulsive non-thermal events seen at the onset of a flare at photon energies > 20 keV generally give rise to small K line fluxes (<250 photons cm^-2 s^-1) on the basis of data presented by Kane and Anderson. The amount of S K radiation in particular depends sensitively on the lower-energy bound of the non-thermal electron distribution giving rise to the impulsive burst, offering a possible means of determining this. Thermal K emission is significant for only Fe ions. For S, Ar and Ca, the temperatures required for a sizeable number of electrons with energies greater than the K-ionization potential will also strip these elements to ionization stages too high for K transitions to be possible. Comparison of thermal K emission from iron during an intense solar flare leads to a very high emission measure on the basis of these calculations, but such a value seems to be compatible with an analysis of the 1–3 Å continuum during the same event.NAS/NRC Resident Research Associate.Visiting Scientist, High Altitude Observatory, NCAR, Boulder, Colo. 80302.     

Biodegradation of petroleum hydrocarbons at low temperature in the presence of the dispersant Corexit 9500

Our study examined the effects of Corexit 9500 and sediment on microbial mineralization of specific aliphatic and aromatic hydrocarbons found in crude oil. We also measured gross mineralization of crude oil, dispersed crude oil and dispersant by a marine microbial consortium in the absence of sediment. When provided as carbon sources, our consortium mineralized Corexit 9500 the most rapidly, followed by fresh oil, and finally weathered oil or dispersed oil. However, mineralization in short term assays favored particular components of crude oil (2-methyl-naphthalene > dodecane > phenanthrene > hexadecane > pyrene) and was not affected by addition of nutrients or sediment (high sand, low organic carbon). Adding dispersant inhibited hexadecane and phenanthrene mineralization but did not affect dodecane and 2-methyl-naphthalene mineralization. Thus, the effect of dispersant on biodegradation of a specific hydrocarbon was not predictable by class. The results were consistent for both high and low oiling experiments and for both fresh and weathered oil. Overall, our results indicate that environmental use of Corexit 9500 could result in either increases or decreases in the toxicity of residual oil through selective microbial mineralization of hydrocarbons.     

Signatures of Divergence and Self-Organization in Soils and Weathering Profiles

Complex system behaviors such as self-organization are difficult to address in geology. System evolution often cannot be directly observed and, in geology models and theory, must be reconciled with field evidence. However, self-organization can be addressed within the historical-interpretive paradigm by applying a measure of the degree of self-organization of geologic features, using standard interpretive methods to determine the nature of changes, and determining whether those changes result in an increase or decrease in organization. In this way, stable non-self-organizing convergent development can be distinguished from unstable chaotic self-organizing divergent development. Kolmogorov entropy (K-entropy) was used as a measure of the self-organization of soil profiles in eastern North Carolina. In general, the profiles are low in K-entropy, indicating a generally high level of predictability and information in the vertical arrangement of pedogenetic horizons. As a broad generality, the study profiles appear to be decreasing in entropy if or when surface erosion is minimal and increasing in entropy otherwise. However, results show that whether the profiles demonstrate evidence of convergent or divergent behavior is determined by the relative rates or magnitudes of three main processes: (1) horizon differentiation in surficial horizons by the formation of transitional AE or A&E horizons due to secondary podzolization, (2) thickening of the solum at the weathering front, and (3) surface erosion. There is no direct relationship between the degree of pedogenic development and self-organization. The results suggest that complex system behaviors are controlled by, and can be linked to, specific pedologic and geomorphic processes and that soils and regoliths may be characterized by both convergent and divergent developmental pathways.     

Temporal Variability of Iron Speciation in Coastal Rainwater

Iron occurs in rain as particulateand dissolved Fe and includes both Fe(II) and Fe(III)species. Model calculations and correlation analysisindicate Fe(II)(aq) occurs almost exclusively as thefree ion whereas Fe(III)(aq) occurs as both ironoxalate and Fe(OH)₂ ⁺(aq) with largevariations over the pH range from 4.0 to 5.0. Complexation with humic-like compounds may also beimportant for Fe(III)(aq); however, the concentrationand structural characteristics of these compounds haveyet to be determined. 112 rain samples were collectedfor iron analysis in Wilmington, North Carolina,between 1 July 1997, and 30 June 1999. Total iron,particulate iron and Fe(III)(aq) were higher inconcentration in summer and spring rain relative towinter and autumn rain. Fe(II)(aq) concentrations, incontrast, did not vary seasonally. Particulate iron,which was approximately half the total rainwater iron,was highest between noon and 6 p.m. (EST), probably dueto more intense regional convection including land-seabreezes during that time. The ratio ofFe(II)(aq)/Fe(III)(aq) was also highest in rainreceived between noon and 6 p.m., which most likelyreflects photochemical reduction of Fe(III)(aq)complexes to form Fe(II)(aq). A conceptual modeldepicting the interplay between iron species, lightintensity and organic ligands in rainwater ispresented.     

A new quadruple gravitational lens system: CLASS B0128+437

High-resolution MERLIN observations of a newly discovered four-image gravitational lens system, B0128+437, are presented. The system was found after a careful re-analysis of the entire CLASS data set. The MERLIN observations resolve four components in a characteristic quadruple-image configuration; the maximum image separation is 542 mas and the total flux density is 48 mJy at 5 GHz. A best-fitting lens model with a singular isothermal ellipsoid results in large errors in the image positions. A significantly improved fit is obtained after the addition of a shear component, suggesting that the lensing system is more complex and may consist of multiple deflectors. The integrated radio spectrum of the background source indicates that it is a gigahertz peaked spectrum source. It may therefore be possible to resolve structure within the radio images with deep VLBI observations and thus to constrain the lensing mass distribution better.     

Water isotopic variability in Mallorca: a path to understanding past changes in hydroclimate

This paper reports the first results on δ¹⁸O and δ²H analysis of precipitations, cave drip waters, and groundwaters from sites in Mallorca (Balearic Islands, western Mediterranean), a key region for paleoclimate studies. Understanding the isotopic variability and the sources of moisture in modern climate systems is required to develop speleothem isotope‐based climate reconstructions. The stable isotopic composition of precipitation was analysed in samples collected between March 2012 and March 2013. The values are in the range reported by GNIP Palma station. Based on these results, the local meteoric water line (LMWL) δ²H = 7.9 (±0.3) δ¹⁸O + 10.8 (±2.5) was derived, with slightly lower slope than Global Meteoric Water Line. The results help tracking two main sources of air masses affecting the study sites: rain events with the highest δ¹⁸O values (> ?5‰) originate over the Mediterranean Sea, whereas the more depleted samples (< ?8‰) are sourced in the North Atlantic region. The back trajectory analysis and deuterium excess values, ranging from 0.4 to 18.4‰, further support our findings. To assess the isotopic variation across the island, water samples from eight caves were collected. The δ¹⁸O values range between ?6.9 and ?1.6‰. With one exception (Artà), the isotopic composition of waters in caves located along the coast (Drac, Vallgornera, Cala Varques, Tancada, and Son Sant Martí) indicates Mediterranean‐sourced moisture masses. By contrast, the drip water δ¹⁸O values for inland caves (Campanet, ses Rates Pinyades) or developed under a thick (>50 m) limestone cap (Artà) exhibit more negative values. A well‐homogenized aquifer supplied by rainwaters of both origins is clearly indicated by groundwater δ¹⁸O values, which show to be within 2.4‰ of the unweighted arithmetic mean of ?7.4‰. Although limited, the isotopic data presented here constitute the baseline for future studies using speleothem δ¹⁸O records for western Mediterranean paleoclimate reconstructions. Copyright © 2016 John Wiley & Sons, Ltd.     

Delineating coastal groundwater discharge processes in a wetland area by means of electrical resistivity imaging, 224Ra and 222Rn

Coastal groundwater discharge (CGD) plays an important role in coastal hydrogeological systems as they are a water resource that needs to be managed, particularly in wetland areas. Despite its importance, identifying and monitoring CGD often presents physical and logistical constraints, restraining the application of more traditional submarine groundwater discharge surveying techniques. Here we investigate the capability of electrical resistivity imaging (ERI) in the Peníscola wetland (Mediterranean coast, Spain). ERI surveying made it possible to identify and delineate an ascending regional groundwater flow of thermal and Ra‐enriched groundwater converging with local flows and seawater intrusion. The continuous inputs of Ra‐rich groundwater have induced high activities of Ra isotopes and ²²²Rn into the marsh area, becoming among the highest previously reported in wetlands and coastal lagoons. Geoelectrical imaging enabled inferring focused upward discharging areas, leaking from the aquifer roof through a confining unit and culminating as spring pools nourishing the wetland system. Forward modelling over idealized subsurface configurations, borehole datasets, potentiometric records from standpipe piezometers, petrophysical analysis, and four natural and independent tracers (²²⁴Ra, ²²²Rn, temperature and salinity) permitted assessing the geoelectrical model and a derived hydrogeological pattern. The research highlights the potential of ERI to improve hydrogeological characterization of subsurface processes in complex contexts, with different converging flows. Additionally, a hydrogeological conceptual model for a groundwater‐fed coastal wetland was proposed, based on the integration of surveying datasets. Copyright © 2013 John Wiley & Sons, Ltd.     

Evolution of Ataúro Island: Temporal constraints on subduction processes beneath the Wetar zone, Banda Arc

Ataúro is a key to understanding the late stage volcanic and subduction history of the Banda Arc to the north of Timor. A volcanic history of bi-modal subaqueous volcanism has been established and new whole rock and trace element geochemical data show two compositional groups, basaltic andesite and dacite–rhyolite. ⁴⁰Ar/³⁹Ar geochronology of hornblende from rhyo-dacitic lavas confirms that volcanism continued until 3.3 Ma. Following the cessation of volcanism, coral reef marine terraces have been uplifted to elevations of 700 m above sea level. Continuity of the terraces at constant elevations around the island reflects regional-scale uplift most likely linked to sublithospheric processes such as slab detachment. Local scale landscape features of the eastern parts of Ataúro are strongly controlled by normal faults. The continuation of arc-related volcanism on Ataúro until at least 3.3 Ma suggests that subduction of Australian lithosphere continued until near this time. This data is consistent with findings from the earthquake record where the extent of the Wetar seismic gap to a depth of 350 km suggests slab breakoff, as a result of collision, commenced at ∼4 Ma, leading to subsequent regional uplift recorded in elevated terraces on Ataúro and neighbouring islands.