Heterogeneous characteristics of streambed saturated hydraulic conductivity of the Touchet River,south eastern Washington,USA

Traditionally a streambed is treated as a layer of uniform thickness and low saturated hydraulic conductivity (K) in surface‐ and ground‐water studies. Recent findings have shown a high level of spatial heterogeneity within a streambed and such heterogeneity directly affects surface‐ and ground‐water exchange and can have ecological implications for biogeochemical transformations, nutrient cycling, organic matter decomposition, and reproduction of gravel spawning fish. In this study a detailed field investigation of K was conducted in two selected sites in Touchet River, a typical salmon spawning stream in arid south eastern Washington, USA. In‐stream slug tests were conducted to determine K following the Bouwer and Rice method. For the upper and lower sites, each 50 m long and 9 m wide and roughly 20 m apart, a sampling grid of 5 m longitudinally and 3 m transversely was used. The slug tests were performed for each horizontal coordinate at 0·3–0·45, 0·6–0·75, 0·9–1·05 and 1·2–1·35 m depth intervals unless a shallower impenetrable obstruction was encountered. Additionally, water levels were measured to obtain vertical hydraulic gradient (VHG) between each two adjacent depth intervals. Results indicated that K ranged over three orders of magnitude at both the upper and lower sites and differed between the two sites. At the upper site, K did not differ significantly among different depth intervals based on nonparametric statistical tests for mean, median, and empirical cumulative distribution, but the spatial pattern of K varied among different depth intervals. At the lower site, K for the 0·3–0·45 m depth interval differed statistically from those at other depth intervals, and no similar spatial pattern was found among different depth intervals. Zones of upward and downward water flow based on VHG also varied among different depth intervals, reflecting the complexities of the water flow regime. Detailed characterization of the streambed as attempted in this study should be helpful in providing information on spatial variations of streambed hydraulic properties as well as surface‐ and ground‐water interaction. Copyright © 2009 John Wiley & Sons, Ltd.     

Assessment of the hydraulic slope flow approach using a mesoscale model

The simplified hydraulic two-layer model for a katabatic flow is analysed using the outputs from a high-resolution mesoscale simulation. A stably stratified night is simulated for the Duero basin, a complex terrain area located in the northern Spanish plateau, with large vertical and horizontal spatial resolution. Well-defined katabatic flows on the basin slopes are generated by the simulation, that are relatively stationary and quasi-bidimensional for some areas in the central part of the night. The bulk quantities used in the two-layer approach as well as the different terms in the equations are computed from the three-dimensional information provided by the mesoscale simulation. This method allows to inspect how well the simplified approach represents the katabatic flow generated by the mesoscale model. The study shows that the hydraulic model allows for a comprehensive analysis of the basic mechanisms of the slope flows but is not able to close the budget equations, since the residuals are large.     

Constraining Holocene sea levels using U‐Th ages of phreatic overgrowths on speleothems from coastal caves in Mallorca (Western Mediterranean)

Phreatic overgrowths on speleothems (POS) are carbonate formations deposited at the water table of caves in unique karstic coastal settings having morphologies that can be directly related to sea level at the time of formation. The U‐Th ages of calcite and aragonite overgrowths collected from the modern water table in coastal caves on Mallorca (Cova de Cala Varques A and Cova des Pas de Vallgornera) were determined using high‐precision MC‐ICPMS techniques. U‐Th ages indicate that phreatic carbonate deposition occurred between ca 2·8 and at least 0·6 ka BP and are in accord with an archeologically estimated age of 3·7–3·0 ka BP for a drowned prehistoric construction at a depth of 1 m below current sea level in a cave from the same area. Speleothem δ¹³C and δ¹⁸O and chemical composition of cave pools provide supportive evidence that POS reflect mixing between seawater and brackish water table. Copyright © 2010 John Wiley & Sons, Ltd.     

A crystal-chemical classification of borate structures with emphasis on hydrated borates

The rules governing formation of hydrated borate polyanions that were proposed by C.L. Christ in 1960 are critically reviewed and new rules added on the basis of recent crystal structure determinations. Principles and classifications previously published by others are also critically reviewed briefly. The fundamental building blocks from which borate polyanions can be constructed are defined on the basis of the number n of boron atoms, and the fully hydrated polyanions are illustrated. Known structures are grouped accordingly, and a shorthand notation using n and symbols Δ = triangle, T = tetrahedron is introduced so that the polyanions can be easily characterized. For example, 3:Δ+2T describes [B₃O₃(OH)₅]^2?. Correct structural formulas are assigned borates with known structures whereas borates of unknown structure are grouped separately.     

Heavy metals in particulate matter and sediments in the southern Barcelona sedimentation system (North-western Mediterranean)

Concentrations of selected heavy metals (Cr, Cu, Ni, Pb and Zn) from surface sediments, suspended particulate matter and settling particles in the southern Barcelona continental margin were studied in order to evaluate the environmental impact of the anthropogenic metals discharged by the Llobregat River in this Mediterranean area. The temporal variation of heavy metals discharged by this river onto the continental shelf is clearly related to the river water flow. Part of the fine sediment and associated heavy metals transported by the Llobregat River during periods of low river flow accumulate on the river bed, and they are totally removed and discharged onto the Barcelona continental shelf during sporadic river water flow increases. Metals produce significant anomalies of chromium (×2.5), copper (×3.4) and zinc (×3.7) in the surface sediments of the Llobregat prodelta and tend to be transported along the continental shelf following the mean flow. Metals associated with the finest suspended flocs transferred to the slope are controlled by the shelf-slope density front and are transported along slope by the general geostrophic current, instead of accumulating and becoming concentrated in the slope bottom sediments. Settling particulate matter collected in sediment traps on the Barcelona continental slope offshore of the shelf-slope front shows low heavy metal concentrations except in a few sediment trap samples that are significantly metal-enriched in chromium (×4.5) and zinc (×6.8). This enrichment is associated with very short and sporadic river flow increases and is only recorded inside the Foix submarine canyon, which acts as a preferential conduit for the shelf-slope sediment transfer.     

A comparison of sediment microbial communities associated with<Emphasis Type="Italic">Phragmites australis</Emphasis> and<Emphasis Type="Italic">Spartina alterniflora</Emphasis> in two brackish wetlands of New Jersey

The extensive spread ofPhragmites australis throughout brackish marshes on the East Coast of the United States is a major factor governing management and restoration decisions because it is assumed that biogeochemical functions are altered by the invasion. Microbial activity is important in providing wetland biogeochemical functions such as carbon and nitrogen cycling, but there is little known about sediment microbial communities inPhragmites marshes. Microbial populations associated with invasivePhragmites vegetation and with native salt marsh cordgrass,Spartina alterniflora, may differ in the relative abundance of microbial taxa (community structure) and in the ability of this biota to decompose organic substrates (community biogeochemical function). This study compares sediment microbial communities associated withPhragmites andSpartina vegetation in an undisturbed brackish marsh near Tuckerton, New Jersey (MUL), and in a brackish marsh in the anthropogenically affected Hackensack meadowlands (SMC). We use phospholipid fatty acid (PLFA) analysis and enzymataic activity to profile sediment microbial communities associated with both plants in each site. Sediment analyses include bulk density, total organic matter, and root biomass. PLFA profiles indicate that the microbial communities differ between sites with the undisturbed site exhibiting greater fatty acid richness (62 PLFA recovered from MUL versus 38 from SMC). Activity of the 5 enzymes analyzed (β-glucosidase, acid phosphatase, chitobiase, and 2 oxidases) was higher in the undisturbed site. Differences between vegetation species as measured by Principal Components Analysis were significantly greater at the undisturbed MUL site than at SMC, and patterns of enzyme activity and PLFAs did not correspond to patterns of root biomass. We suggest that in natural wetland sediments, macrophyte rhizosphere effects influence the community composition of sediment microbial populations. Physical and chemical site disturbances may impose limits on these rhizosphere effects, decreasing sediment microbial diversity and potentially, microbial biogeochemical functions.     

An Intercomparison of Large-Eddy Simulations of the Stable Boundary Layer

Results are presented from the first intercomparison of large-eddy simulation (LES) models for the stable boundary layer (SBL), as part of the Global Energy and Water Cycle Experiment Atmospheric Boundary Layer Study initiative. A moderately stable case is used, based on Arctic observations. All models produce successful simulations, in as much as they generate resolved turbulence and reflect many of the results from local scaling theory and observations. Simulations performed at 1-m and 2-m resolution show only small changes in the mean profiles compared to coarser resolutions. Also, sensitivity to subgrid models for individual models highlights their importance in SBL simulation at moderate resolution (6.25 m). Stability functions are derived from the LES using typical mixing lengths used in numerical weather prediction (NWP) and climate models. The functions have smaller values than those used in NWP. There is also support for the use of K-profile similarity in parametrizations. Thus, the results provide improved understanding and motivate future developments of the parametrization of the SBL.     

Lipid biogeochemistry of Phormidium and Microcoleus mats

A study on the predominant sources of organic matter and the main diagenetic processes in two different cyanobacterial mats from evaporite-controlled environments was performed. Fatty acids, hydrocarbons, alcohols, ketones and aldehydes were anlyzed in selected millimetre and submillimetre core sections. The changes in lipid composition were evaluated by comparison with the vertical distributions of the populations observed by optic microscopy and with the lipid patterns of enrichment cultures of species such as cyanobacteria, diatoms, purple bacteria, sulphate-reducers and methanogens obtained from the mats.The cyanobacteria Phormidium valderianum and Microcoleus chthonoplastes are the predominant primary producers, and occur almost as monocultures in the respective top layers. However, these mat-forming organisms only leave minor features in the solvent-extractable lipid sedimentary record. The predominant fatty acid distributions parallel the composition observed in the enrichment cultures of purple bacteria and appear mixed with acids characteristic of heterotrophic eubacteria such as sulphate-reducers. The concentrations of these lipids are, however, 5–10 times lower than the cyanobacterial acids from the top layer. De novo heterotrophic eubacterial synthesis is also observed in cases such as the highly branched isoprenoid eicosenes, the major hydrocarbon in the deep layers (>2 mm) of the Phormidium mat. Other major diagenetic changes involve dehydration and hydrogenation. These two processes take place concurrently under anoxic conditions and have been observed among the sterols and the isoprenoid alcohols. Significant amounts of 5ß(H)-stanols were observed in the more reducing sections where molecular indicators of methanogenic bacteria were also found.