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991.
A simple one-dimensional analytical solution is presented to model oxygen diffusion through the pore space of mine spoils containing pyrite. The model incorporates volumetric oxygen consumption terms due to pyrite oxidation, oxidation of Fe 2+ to Fe 3+ and bacterial activity. Based on this analytical solution, a graphical user interface (GUI) tool is programmed and designed in MATLAB software. This tool can be used to model transport of oxygen through the mine spoils either with or without a cap. Results of several simulation scenarios of sensitivity analysis showed a significant change in oxygen concentration with varying effective diffusion coefficient of oxygen transport model and simulation time. Efficiency and flexibility of the tool developed here is verified by modelling oxygen transport through the pore space of a coal waste pile (case A) and a copper mine tailings (case B). Maximum depth of oxygen diffusion is obtained approximately equal to 2 and 1.5 m through the cases A and B, respectively. 相似文献
992.
El-Arabi Shendi Akram Aziz Khalid Mamoun Mohamed Gamal 《Environmental Earth Sciences》2017,76(22):783
Very low frequency electromagnetic (VLF-EM) measurements were carried out in Wadi Isbayia area, south Sinai Peninsula, to test the efficiency of the VLF-EM method in the exploration of sulphide mineralization in arid environments. The VLF-EM field measurements, including tilt angle, real and imaginary components of the received VLF field, were carried out along fifteen profiles covering a quartz monzonite bedrock. Interpretation of the VLF measurements, in the light of geological information, has showed that sulphide minerals in the Wadi Isbayia area extend from the ground surface to a depth of about 200 m. However, the structural lineaments, especially faults, have controlled the distribution of the sulphide mineralization. A few of polished sections for rock samples, collected from the sites of the VLF-EM anomalies in the study area, have been prepared and examined by ore microscopy which confirmed the presence of pyrite and chalcopyrite as well as iron oxides, disseminated in the quartz monzonite bedrock. These results showed that the VLF-EM method is an effective tool in the exploration of sulphide minerals in the arid environments. 相似文献
993.
A numerical simulation of residual circulation in Tampa Bay. Part I: Low-frequency temporal variations 总被引:1,自引:0,他引:1
Steven D. Meyers Mark E. Luther Monica Wilson Heather Havens Amanda Linville Kristin Sopkin 《Estuaries and Coasts》2007,30(4):679-697
The residual (time-average) salinity and circulation in a numerical ocean model of the Tampa Bay estuary are shown to experience
significant temporal variation under realistic forcing conditions. A version of the Estuarine Coastal Ocean Model developed
for Tampa Bay with 70 by 100 horizontal grid points and 11 sigma levels is examined for the years 2001–2003. Model output
variables are averaged over the entire time of the simulation to generate long-term residual fields. The residual axial current
is found to be dominated by the buoyancy-driven baroclinic circulation with an outflow (southwestward) at the surface and
to the sides of the shipping channel, and an inflow (northeastward) usually occurring subsurface within or above the shipping
channel. Averages over 30 d are used to examine variations in the residual fields. During the simulation the average surface
salinity near the head of Tampa Bay varies with the freshwater inflow, from 12‰ to 33%. At the bay mouth salinity varies from
30%. to 36%.. A localized measure of the baroclinic circulation in the shipping channel indicates the residual circulation
can vary strongly, attaining a magnitude triple the long-term mean value. The baroclinic circulation can be disrupted, going
to near zero or even reversing, when the buoyancy-driven flow is weak and the surface winds are to the northeast. Three time
periods, representing different environmental conditions, are chosen to examine these results in detail. A scaling argument
indicates the relative strength of buoyancy versus wind as ΔρgH2(LC
Dω2)−1, where δρ is head-to-mouth density difference across the bay,g is gravitational acceleration,H is depth,L is bay length,C
D is the surface wind drag coefficient, andw is wind speed. Tampa Bay is usually in the buoyancy dominated regime. The importance of winds in the weak-buoyancy case is
demonstrated in an additional simulation without wind stress. 相似文献
994.
N. N. Rabalais R. E. Turner B. K Sen Gupta D. F. Boesch P. Chapman M. C. Murrell 《Estuaries and Coasts》2007,30(5):753-772
We update and reevaluate the scientific information on the distribution, history, and causes of continental shelf hypoxia
that supports the 2001 Action Plan for Reducing, Mitigating, and Controlling Hypoxia in the Northern Gulf of Mexico (Mississippi
River/Gulf of Mexico Watershed Nutrient Task Force 2001), incorporating data, publications, and research results produced
since the 1999 integrated assessment. The metric of mid-summer hypoxic area on the LouisianaTexas shelf is an adequate and
suitable measure for continued efforts to reduce nutrients loads from the Mississippi River and hypoxia in the northern Gulf
of Mexico as outlined in the Action Plan. More frequent measurements of simple metrics (e.g., area and volume) from late spring
through late summer would ensure that the metric is representative of the system in any given year and useful in a public
discourse of conditions and causes. The long-term data on hypoxia, sources of nutrients, associated biological parameters,
and paleoindicators continue to verify and strengthen the relationship between the nitratenitrogen load of the Mississippi
River, the extent of hypoxia, and changes in the coastal ecosystem (eutrophication and worsening hypoxia). Multiple lines
of evidence, some of them representing independent data sources, are consistent with the big picture pattern of increased
eutrophication as a result of long-term nutrient increases that result in excess carbon production and accumulation and, ultimately,
bottom water hypoxia. The additional findings arising since 1999 strengthen the science supporting the Action Plan that focuses
on reducing nutrient loads, primarily nitrogen, through multiple actions to reduce the size of the hypoxic zone in the northern
Gulf of Mexico. 相似文献
995.
Beach-cast wrack of marine origin is considered a spatial subsidy to the marine-terrestrial transition zone. We found that
the wrack line on sand and gravel beaches of Vancouver Island was frequented by intertidal purple shore crabs,Hemigrapsus nudus (Dana 1851) and densely colonized by detritivorous talitrid amphipods. Amphipods spend the day buried in sand and forage
on beach wrack during the night.H. nudus were found in supratidal wrack putches immediately after nightly high tides in field censuses, but spent most of the day
and ebb tides either submerged subtidally or hidden underneath intertidal rocks and boulders. In feeding trials, intertidal
shore crabs were capable of preying on talitrid amphipods. We considerH. nudus an omnivore feeding on both fresh and decaying macroalgae as well as animal prey. Although living supratidally, amphipods
were significantly preferred over intertidal littorine snails by foraging shore crabs. Handling time of amphipods was significantly
shorter than for littorine snails. While amphipods had a reduced risk of predation byH. nudus when buried in the sand, foraging undern eath wrack patches did not reduce predation pressure on amphipods by shore crabs.
Rates of amphipod consumption by shore crabs were higher at darkness than daylight. In addition to an apparent day-night rhythm,
tidal height and time elapsed since previous high tide had a significant influence on shore crab density wrack. We conclude
that beach-cast wrack acts as a spatial subsidy by virtue of providing a valuable food source to talitrid amphipods, which
are in turn consumed by shore crabs that ride the nightly high tide into supratidal wrack patches to reduce the risk of passing
bare sand on theiry way to a feeding habitat rich in valuable prey. 相似文献
996.
Net ecosystem metabolism (NEM) is becoming a commonly used ecological indicator of estuarine ecosystem metabolic rates. Estuarine
ecosystem processes are spatially and temporally variable, but the corresponding variability in NEM has not been properly
assessed. Spatial and temporal variability in NEM was assessed in four western Gulf of Mexico shallow water estuaries. NEM
was calculated from high-frequency dissolved oxygen measurements. Interbay, intrabay, and water column spatial scales were
assessed for NEM, gross primary production (GPP), and respiration (R) rate variability. Seasonal, monthly, and daily temporal
scales in NEM, GPP, and R were also assessed. Environmental conditions were then compared to NEM to determine which factors
were correlated with each temporal and spatial scale. There was significant NEM spatial variability on interbay, intrabay,
and water column spatial scales. Significant spatial variability was ephemeral, so it was difficult to ascertain which environmental
conditions were most influential at each spatial scale. Significant temporal variability in NEM on seasonal, monthly, and
daily scales was found and it was correlated to temperature, salinity, and freshwater inflow, respectively. NEM correlated
strongly with dissolved oxygen, temperature, and salinity, but the relationships where different in each bay. The dynamics
of NEM on daily scales indicate that freshwater inflow events may be the main driver of NEM in the semiarid estuaries studied.
The variable nature of NEM found here is further evidence that it is not valid to use single station monitoring deployments
for assessment of whole estuarine ecosystem metabolic rates in large ecosystems. The relationship between NEM and temperature,
salinity, and freshwater inflow events could drive predictive models assessing the potential influence of projected climate
change and watershed development scenarios on estuarine metabolic rates. 相似文献
997.
Ben K. Greenfield Geoffrey S. Siemering Joy C. Andrews Michael Rajan Stephen P. Andrews David F. Spencer 《Estuaries and Coasts》2007,30(4):627-640
Management actions to control invasive aquatic species can have significant ecosystem-scale effects. We evaluated the water
chemistry and nutrient effects of mechanical shredding to control water hyacinth (Eichhornia crassipes) in an agricultural slough and a tidal wetland on the Sacramento-San Joaquin River Delta, California. Shredding was conducted
with two types of shredder boats in fall of 2003 and another boat in spring of 2004. Shredding measurably affected water quality,
but specific effects varied as a function of shredding site and season. Significant increases were observed for total Kjeldahl
nitrogen and total phosphorus for all experiments. Dissolved oxygen effects varied by site, decreasing after shredding at
the agricultural slough but increasing at the tidal wetland. The increase in dissolved oxygen likely resulted from tidal incursions
from the adjacent river. A year-long time series of dissolved oxygen data indicated a negative relationship between hyacinth
abundance and dissolved oxygen concentrations. Hyacinth contained similar tissue concentrations of mercury to underlying sediments,
suggesting that plant harvesting could aid mercury remediation efforts. Simple mass calculations indicated that Delta-wide
shredding operations could cause between 0.1% and 9.6% increases in the overall abundance of carbon, nitrogen, and phosphorus
in the Delta water column. Results suggest that local effects of management actions to control invasive aquatic plants will
vary widely as a function of site-specific hydrology, but that estuary-wide effects would be limited. 相似文献
998.
Weidong Li 《Mathematical Geosciences》2007,39(3):321-335
Multi-dimensional Markov chain conditional simulation (or interpolation) models have potential for predicting and simulating categorical variables more accurately from sample data because they can incorporate interclass relationships. This paper introduces a Markov chain random field (MCRF) theory for building one to multi-dimensional Markov chain models for conditional simulation (or interpolation). A MCRF is defined as a single spatial Markov chain that moves (or jumps) in a space, with its conditional probability distribution at each location entirely depending on its nearest known neighbors in different directions. A general solution for conditional probability distribution of a random variable in a MCRF is derived explicitly based on the Bayes’ theorem and conditional independence assumption. One to multi-dimensional Markov chain models for prediction and conditional simulation of categorical variables can be drawn from the general solution and MCRF-based multi-dimensional Markov chain models are nonlinear. 相似文献
999.
1000.
Effect of chemical fertilizers on the fractionation of Cu,Cr and Ni in contaminated soil 总被引:1,自引:0,他引:1
Jie Liu Chang-Qun Duan Yi-Nian Zhu Xue-Hong Zhang Cheng-Xian Wang 《Environmental Geology》2007,52(8):1601-1606
Effect of chemical fertilizers (urea, NH4Cl, Ca(NO3)2, KCl and KH2PO4) on the fractionation of Cu, Cr and Ni was studied by a 4-month incubation experiment. Using sequential extraction procedure,
it was found that the application of fertilizers could change the distribution of Cu, Cr and Ni in the fractions of soil.
Applying urea (CO(NH2)2) significantly decreased the concentrations of Cu, Cr and Ni in water soluble plus exchangeable (WE) fraction, but increased
those in Fe–Mn oxides bound (FM) fraction (p < 0.01). However, application of NH4Cl caused an increase in the WE fraction by 27.7% for Cu, 111.5% for Cr and 20.4% for Ni. The CO(NH2)2 raised the soil pH from 4.51 to 4.96, whereas NH4Cl lowered the pH of soil by 0.44 units. The WE fraction of the three heavy metals was significantly increased, while the
FM fraction was significantly decreased by adding KCl (p < 0.01). Moreover, the supply of KH2PO4 reduced the WE and carbonate bound (CB) fractions of Cu, Cr and Ni in the soil, however, it raised Cu and Ni in the residual
(RS) fraction and Cr in the FM fraction. In addition, the mobility index indicated that KCl and NH4Cl increased the mobility of Cu, Cr and Ni in the soil, whereas urea and KH2PO4 decreased the mobility of the three metals in the soil. These results suggest that applying chemical fertilizers does not
only provide plant nutrients, but may also change the speciation and mobility of heavy metals in the soil. 相似文献