Heterogeneous Nocturnal Cooling in a Large Basin Under Very Stable Conditions

Large basins with relatively wide floors experience heterogeneous nocturnal cooling due to the diversity of the topography and the land use within the basin. Near mountain ranges the drainage flows prevail, but in low areas, river valleys or embedded plateaux, the actual rates of cooling differ as does the behaviour of the local flows in the first few metres above the surface. In this study, the temporal and spatial heterogeneity of the surface cooling is inspected through the analysis of satellite radiative surface temperature, data from a meteorological network and a tall tower. The organisation of the flow within the basin is also studied by means of a high-resolution numerical mesoscale simulation. Although the basin cools almost as a unit, there exists a large diversity of local regimes. Vertical profiles from the mesoscale simulation are analysed and grouped according to their wind structure and stratification.     

Stable oxygen and hydrogen isotopic composition of bentonites from Cabo de Gata (Almería,Spain)

The aim of this study is to investigate the nature of the solutions and the temperature during the bentonite formation by using δ¹⁸O and δ²H values and the relationship between chemical and isotopic composition of smectites from Cabo de Gata region. Therefore, 36 bentonite samples had been selected. For analyses the <2 μm fraction were separated. Most of the samples contain smectite above 90 wt%. The stable oxygen and hydrogen isotopic composition of the analysed smectites is close to the “montmorillonite line”. However, from isotopic composition two types of bentonite can be distinguished. The Sierra de Gata (SG) and Serrata de Nijar (SN) types show δ¹⁸O and δ²H values above and below this line, respectively. Temperatures obtained from geothermometer equation are similar to the temperatures values obtained from the equation of Savin and Lee (1988). Estimated formation temperatures of SG type are 25 and 49 °C higher compared to those of the SN type (6 and 25 °C).Correlations between structural cations versus isotopic composition show no statistical significance concerning all samples. However, separating the samples of SG (Sierra de Gata) from SN (Serrata of Nijar) a statistical significance for the individual areas is obtained. In both cases the effect is similar for ¹⁸O and for ²H. This could be due to the different composition of the solutions forming these bentonites.     

The quest for the solar g modes

Solar gravity modes (or g modes)—oscillations of the solar interior on which buoyancy acts as the restoring force—have the potential to provide unprecedented inference on the structure and dynamics of the solar core, inference that is not possible with the well-observed acoustic modes (or p modes). The relative high amplitude of the g-mode eigenfunctions in the core and the evanesence of the modes in the convection zone make the modes particularly sensitive to the physical and dynamical conditions in the core. Owing to the existence of the convection zone, the g modes have very low amplitudes at photospheric levels, which makes the modes extremely hard to detect. In this article, we review the current state of play regarding attempts to detect g modes. We review the theory of g modes, including theoretical estimation of the g-mode frequencies, amplitudes and damping rates. Then we go on to discuss the techniques that have been used to try to detect g modes. We review results in the literature, and finish by looking to the future, and the potential advances that can be made—from both data and data-analysis perspectives—to give unambiguous detections of individual g modes. The review ends by concluding that, at the time of writing, there is indeed a consensus amongst the authors that there is currently no undisputed detection of solar g modes.     

From Tethys to Eastern Paratethys: Oligocene depositional environments, paleoecology and paleobiogeography of the Thrace Basin (NW Turkey)

The Oligocene depositional history of the Thrace Basin documents a unique paleogeographic position at a junction between the Western Tethys and the Eastern Paratethys. As part of the Tethys, shallow marine carbonate platforms prevailed during the Eocene. Subsequently, a three-staged process of isolation started with the Oligocene. During the Early Rupelian, the Thrace Basin was still part of the Western Tethys, indicated by typical Western Tethyan marine assemblages. The isolation from the Tethys during the Early Oligocene is reflected by oolite formation and endemic Eastern Paratethyan faunas of the Solenovian stage. The third phase reflects an increasing continentalisation of the Thrace Basin with widespread coastal swamps during the Late Solenovian. The mollusc assemblages are predominated by mangrove dwelling taxa and the mangrove plant Avicennia is recorded in the pollen spectra. The final continentalisation is indicated by the replacement of the coastal swamps by pure freshwater swamps and fluvial plains during the Late Oligocene (mammal zone MP 26). This paleogeographic affiliation of the Thrace Basin with the Eastern Paratethys after ~32 Ma contrasts all currently used reconstructions which treat the basin as embayment of the Eastern Mediterranean basin.     

Pedo-geochemical baseline content levels and soil quality reference values of trace elements in soils from the Mediterranean (Castilla La Mancha, Spain)

To evaluate trace element soil contamination, geochemical baseline contents and reference values need to be established. Pedo-geochemical baseline levels of trace elements in 72 soil samples of 24 soil profiles from the Mediterranean, Castilla La Mancha, are assessed and soil quality reference values are calculated. Reference value contents (in mg kg^?1) were: Sc 50.8; V 123.2; Cr 113.4; Co 20.8; Ni 42.6; Cu 27.0; Zn 86.5; Ga 26.7; Ge 1.3; As 16.7; Se 1.4; Br 20.1; Rb 234.7; Sr 1868.4; Y 38.3; Zr 413.1; Nb 18.7; Mo 2.0; Ag 7.8; Cd 4.4; Sn 8.7; Sb 5.7; I 25.4; Cs 14.2; Ba 1049.3; La 348.4; Ce 97.9; Nd 40.1; Sm 10.7; Yb 4.2; Hf 10.0; Ta 4.0; W 5.5; Tl 2.3; Pb 44.2; Bi 2.2; Th 21.6; U 10.3. The contents obtained for some elements are below or close to the detection limit: Co, Ge, Se, Mo, Ag, Cd, Sb, Yb, Hf, Ta, W, Tl and Bi. The element content ranges (the maximum value minus the minimum value) are: Sc 55.0, V 196.0, Cr 346.0, Co 64.4, Ni 188.7, Cu 49.5, Zn 102.3, Ga 28.7, Ge 1.5, As 26.4, Se 0.9, Br 33.0 Rb 432.7, Sr 3372.6, Y 39.8, Zr 523.2, Nb 59.7, Mo 3.9, Ag 10.1, Cd 1.8, Sn 75.2, Sb 9.9, I 68.0, Cs 17.6, Ba 1394.9, La 51.3, Ce 93.5, Nd 52.5, Sm 11.2, Yb 4.2, Hf 11.3, Ta 6.3, W 5.2, Tl 2.1, Pb 96.4, Bi 3.0, Th 24.4, U 16.4 (in mg kg^?1). The spatial distribution of the elements was affected mainly by the nature of the bedrock and by pedological processes. The upper limit of expected background variation for each trace element in the soil is documented, as is its range as a criterion for evaluating which sites may require decontamination.     

Intellectual property rights and low carbon technology transfer: Conflicting discourses of diffusion and development

Intellectual property rights (IPRs) and the transfer of low carbon technologies to developing countries have been the focus of sustained disagreement between many developed and developing country Parties to the United Nations Framework Convention on Climate Change (UNFCCC). We argue that this disagreement stems from two conflicting political discourses of economic development and low carbon technology diffusion which tend to underpin developing and developed countries’ respective motivations for becoming party to the Convention. We illustrate the policy implications of these discourses by examining empirical evidence on IPRs and low carbon technology transfer and highlight how the two discourses are based on an incomplete understanding of the role of technological capacity in either economic development or technology diffusion. This has important implication for the success of post-2012 international climate agreements.     

Applying multifractality and the self‐organized criticality theory to describe the temporal rainfall regimes in Andalusia (southern Spain)

A multifractal analysis of hourly and daily rainfall data recorded at four locations of Andalusia (southern Spain) was carried out in order to study the temporal structure of rainfall and to find differences between both time resolutions. The results show that an algebraic tail is required to fit the probability distribution of the extreme rain events for all the cases. The presence of a multifractal phase transition associated with a critical moment in the empirical moments scaling exponent function was also detected. Both facts indicate that the rainfall process is a case of self‐organized criticality (SOC) dynamics, although the results differ for each place according to the time resolution and the nature of the rainfall, either convective or frontal. This SOC behaviour is related to a statistically steady state that implies the presence of clusterization in the time‐occurrence sequence of rain events. Such fluctuations have been shown by performing the analysis of the Fano and Allan factors and the count‐based periodogram. The values for the “synoptic maximum”, the typical lifetime of planetary scale atmospheric structures, have been obtained for each place and some important periodicities have been detected when dealing with extremes. Copyright © 2007 John Wiley & Sons, Ltd.     

Impact of climate variability in the western Mediterranean during the last 20,000 years: oceanic and atmospheric responses

Eolian input fluctuations and paleoceanographic conditions in the western Mediterranean have been reconstructed by using a multi-proxy approach to infer climate variability for the last 20,000 yr. A sediment core from the East Alboran Sea basin provides high-resolution geochemical, mineralogical and grain size distribution records from the Last Glacial Maximum onward. The accurate chronology obtained, closely related with the North Greenland Ice core Project, has provided a detailed paleoclimate reconstruction at the centennial–millennial time scale. Mineral and chemical compositions as well as sediment grain size distribution have been used to establish both fluvial and eolian input variations, deep-water current intensity, and ventilation and productivity conditions at the time of deposition. During the cold period Greenland Stadial-2a, the analyzed proxies evidence significant climate oscillations. Redox proxies, showing marked Mn/Al and Fe/Al peaks, as well as granulometric parameters, support major changes in thermohaline circulation, with active circulation triggered by the Western Mediterranean Deep Water formation. Ba/Al ratios and the presence of authigenic barite point to high productivity during the Last Heinrich event. At this time, Zr/Al, Si/Al and Ti/Al ratios as well as quartz and palygorskite contents also corroborate dryer conditions in the Alboran borderlands, with a major reorganization of atmospheric circulation at the beginning of the deglaciation and during the Last Heinrich event. In contrast, a decreasing trend in the Zr/Al ratio and increasing Mg/Al, K/Al and illite + chlorite/kaolinite ratios would indicate enhanced river runoff and supporting lower eolian dust input and wetter periods during the Bölling–Alleröd. Short-term and abrupt climate oscillations such as the Intra-Alleröd Cold Period are likewise reflected by minor yet conspicuous changes in eolian proxies. During the Younger Dryas, we distinguish an initial cold and dry phase, with major westerlies intensity, thermohaline reactivation, and high productivity levels, and a second wetter phase characterized by sporadic rainfalls over poorly vegetated surrounding continental areas. Then, during the Holocene, alternating phases of major humidity and aridity were recorded by major fluctuations in detrital input. These are also correlated with recurrent forest cover declines reported from pollen records, with a noteworthy early decline in the African Humid Period. During the Holocene, an initial demise of the Last Organic-Rich Layer is also evidenced, tentatively associated with aspiration forces promoted by intense thermohaline circulation through the Gibraltar Strait.     

Planning in Jordan: Coping with uncertainty

Jordan is an Islamic state with planning based on Islamic principles. The execution of plans, though, has been constrained by geopolitical realities. In the last decade Jordan has moved from strictly sectoral planning to a strongly focused system of regional planning in order to achieve more growth in less developed regions. The prospects for these regions and the country as a whole will turn on the success of the peace process in the region.     

Thermal decomposition of NH<Subscript>4</Subscript><Superscript>+</Superscript>-vermiculite from Santa Olalla (Huelva,Spain) and its relation to the metal ion distribution in the octahedral sheet

The investigation of the NH₃ loss in the NH₄⁺-vermiculite (Santa Olalla) by thermogravimetry, evolved gas analysis, chemical analysis, X-ray diffraction and IR spectroscopy is reported here. The mass loss during heating takes place in two steps at about 650 and 825 °C. Additionally, the releases of H₂O and NH₃ occurs simultaneously. The experimental results indicate that the protons remaining in the interlayer space after NH₃ removal trigger the H₂O release. X-ray diffraction shows that during the decomposition of NH₄⁺-vermiculite there are two domains with different interlayer spaces at ~9 and ~10 Å. As the decomposition proceeds, the intensity of the 9 Å peak increases at the expense of the second one. The change in the IR-stretching modes of the structural OH groups during heating indicates that the OH groups surrounded by 3Mg²⁺ or 2Mg²⁺Fe²⁺ are released at lower temperatures than those with environments like 2Mg²⁺Fe³⁺, 2Mg²⁺Al³⁺ or more complex ones.