大孔径闪烁仪观测数据在陆面模式验证中的应用初探

将大孔径闪烁仪(LAS)观测数据应用在陆面模式验证中对更好地认识和描述陆面过程在气候变化中的作用有着重要意义.以中国北方2个LAS观测站--密云和阿柔为例,分别设定一个公里尺度(1 km2)的研究区域,采用陆面模式SiB2,综合利用站点观测数据、实地调查数据及卫星遥感数据,对陆面过程进行了模拟,并利用LAS和涡动相关仪(EC)观测的显热通量对模拟结果进行了评估,结果表明:SiB2模式能够对阿柔和密云显热通量的总体情况、日变化情况及季节变化情况进行较好的模拟;利用LAS显热通量进行较大尺度模拟验证,能够在很大程度上避免EC能量不闭合及其观测尺度与模式模拟尺度不匹配在验证中所造成的偏差,验证效果更好.     

基于最优加权组合的甘肃金川矿14行风井变形预测

金川14行风井直接关系到矿山的安全生产。本文建立了3种单一预测模型,并根据最优加权组合原理得到了最优加权组合预测模型。最优加权组合预测模型包含了单一模型的有效信息,提高了变形的预测精度。最优加权组合预测模型的模型精度与权重分配与单一模型的选取有关。作为一种短期预测模型,得出金川14行风井在近两个半年会保持稳态变形,不会出现大的突变。     

金川二矿区14行风井返修支护效果分析

针对金川二矿区14行风井的返修支护方案,本文根据金川矿区高应力破碎岩体的条件,从锚杆、喷射混凝土、钢筋网三方面,分析了该方案中喷锚网支护的作用机理,并通过数值方法分析了该返修支护方案的效果。研究结果表明:14行风井的返修支护措施对竖井围岩移动、变形有一定的限制作用,但效果不是很好;随着开采深度和规模的扩大,井筒围岩还将产生较大的位移,并有可能重新发生破坏。     

强烈气洗作用导致原油成分变化的定量计算:以库车坳陷天然气藏为例

库车坳陷以产天然气为主,同时产出少量原油和凝析油,油气充注不同步,普遍具有"油早气晚"的特点,晚期大量天然气的侵入,必然对早期聚集的油藏发生改造作用。对气藏中原油成分变化的定量计算和讨论,可为天然气的注入强度定量评价提供直接证据。未遭受气洗的原油,正构烷烃摩尔浓度的对数与相应的碳数呈线性关系,而气洗作用可使轻组分的正构烷烃最先溶解于干气中,并随着天然气继续向前运移,原始油藏中的轻组分正构烷烃大大减少。以此为理论基础,建立了正构烷烃损失的定量计算模型。结果表明克拉2构造原油正构烷烃损失程度最高,平均可达70%左右,大北构造带原油正构烷烃损失程度差异较大,与该地区断块发育有关。气洗作用导致原油正构烷烃减少,而金刚烷、多环芳烃等在天然气中溶解度较低的化合物得以浓缩富集,相对含量大大增加。轻芳烃含量也会随之而增加,原油芳香度增加,石蜡度降低。在模拟实验基础上对气洗程度进行了定量评价,初步估算表明,克拉2构造原油遭受的气洗作用最强,是其他构造带的2～5倍。     

Glacial paleoceanography off the mouth of the Mekong River, southern South China Sea, during the last 500 ka

We have analyzed core MD01-2392, ∼ 360 km east of the Mekong River mouth in the South China Sea (SCS). Over the past 500 ka, planktonic foraminiferal oxygen-isotopic values are consistently lighter than northern SCS and open-ocean records by up to 0.5‰, indicating the influence of run-off from the Mekong River during both glacial and interglacial periods. Carbonate content is higher during interglacials; sedimentation rates were higher during glacials. Increased sedimentation rates since 30 ka imply increased run-off during the last glacial maximum and Holocene Period. Contrary to general experience, in which it is classed as a warm species for temperature estimates, the thermocline-dwelling species Pulleniatina obliquiloculata increased its numbers during glacial periods. This implies an estuarine circulation and even brackish-water caps during glacial periods, reinforcing the sense of strong run-off. In an overall decline of warm water, the thermocline shoaled stepwise, with rapid rises across the glacial terminations. We infer that the southern SCS was opened to an influx of Indian Ocean waters through southern passages at those times of rising sea levels.     

气相色谱-质谱法同时测定河流沉积物中多环芳烃和有机氯农药

建立了用加速溶剂萃取,气相色谱-质谱法同时测定河流沉积物中16种多环芳烃和19种有机氯农药的分析方法,优化了萃取溶剂、萃取温度和时间、凝胶渗透色谱收集时间、固相萃取洗脱溶剂和洗脱体积等条件。16种多环芳烃的方法检出限在0.15~0.59 ng/g,加标回收率为82%~102%,相对标准偏差(RSD,n=5)为1.1%~4.5%。19种有机氯农药的方法检出限在0.14~2.23 ng/g,加标回收率为71%~108%,相对标准偏差(RSD,n=5)为1.0%~4.5%。实际样品的测定结果表明,该方法分离效果较好,能够满足沉积物样品中多环芳烃和有机氯农药的分析要求。     

A geochemical survey of trace elements in agricultural and non-agricultural topsoil in Dexing area,China

In China, soil pollution is very serious, which has jeopardized the ecology, food safety, the people's health, and even the sustainable development of agriculture. In order to investigate the soil pollution situation, a total of 874 agricultural and non-agricultural topsoil samples were collected from Dexing area, northeast of Jiangxi Province, China. The total elemental concentrations of 17 elements (As, Hg, Mo, Cd, Cr, Zn, Cu, Mn, Ti, Pb, Fe, Ca, K, Si, Al, Mg, and Na) were determined. The geochemical background and threshold was predicted with the method of the median ± median absolute deviation (MAD). The agricultural soil median concentration of trace elements was similar to that of the non-agricultural soil. In contrast to Jiangxi soil background of trace elements, the geochemical background of the study area was obviously higher. The maps of the pollution indices for As, Cd, Cr, Cu, Hg, Mn, Mo, Pb, Ti and Zn of non-agricultural soil and agricultural soils in the study area, showed that the highest level of pollution is distributed near and along the Lean River, especially in the neighboring and surrounding Dexing and Leping mining area.     

郯庐断裂带南段构造演化与邻区成矿作用——从年代学资料得到的启示

郯庐断裂带为我国东部北北东—北东向岩石圈深大断裂带。在其南段的邻区,分布有胶东金矿区、鲁西铁金矿区以及长江中下游的铁铜(金)成矿带和苏北油气田等矿产。从已获得大量测年资料分析,可将构造—岩浆—成矿事件分为3个阶段:1)早期(800～550 Ma):自元古宙泛古陆裂解和随之而来的加里东期古地震和局部海西期喷流作用,证实地壳运动早已拉开了它的"构造活动序幕",此阶段继承和构建了华北克拉通岩石圈先存的构造薄弱带,从成矿作用而论,此阶段可称为"成矿预备场地";2)主期(1 80～110 Ma):在三叠纪期间,扬子板块和华北板块陆—陆碰撞和中生代西太平洋板块向欧亚板块俯冲等,造就了现今郯庐断裂与分支断裂的构造格架。其中主峰形成时间为140～120 Ma±,在这个阶段广泛有钙碱性系列、富钾高锶钙碱系列、碱性系列岩浆和后期成矿热液,沿着有利构造空间剧烈活动和成矿就位。本区壳幔混熔型和壳源同熔型花岗岩,是地壳减薄和下地壳拆沉、底侵的产物,而不是单一的构造运动的结果。此阶段可称为断裂构造—岩浆活动—成矿作用的鼎盛期;3)晚期(60Ma～现代):沿东西向与北北东向(或北东向)断裂交汇处,存在橄榄玄武岩喷侵,为石油和天然气的形成提供了热源和物源,此期可称其为构造—岩浆活动的衰变期。     

Estimation of aseismic crustal-strain using radon precursors of the 2003 <Emphasis Type="Italic">M</Emphasis> 6.8, 2006 <Emphasis Type="Italic">M</Emphasis> 6.1, and 2008 <Emphasis Type="Italic">M</Emphasis> 5.0 earthquakes in eastern Taiwan

Aseismic crustal-strain signals prior to the 2003 Mw 6.8 Chengkung, 2006 Mw 6.1 Taitung, and 2008 Mw 5.0 Antung earthquakes with epicenters located 20, 55 and 11 km, respectively, from the Antung radon-monitoring station have been calculated using the radon anomalies recorded. Specifically, radon decreased from background levels of 791 ± 46, 762 ± 57, and 735 ± 48 pCi/L to minima of 326 ± 9, 371 ± 9, and 480 ± 43 pCi/L prior to the 2003, 2006, and 2008 earthquakes, respectively. The estimated aseismic crustal-strain maxima at the Antung hot spring during the rock dilation stage were 3.6, 2.7, and 1.3 ppm, respectively. The v-shaped radon pattern recognized in all three anomalies is valuable for detecting the aseismic strain precursory to disastrous earthquakes in the Antung hot spring which is situated in a brittle fractured aquifer of limited recharge surrounded by ductile mudstone.     

腾冲马鞍山、打鹰山、黑空山火山岩浆来源与演化

本文对马鞍山、打鹰山、黑空山火山岩主微量和Sr、Nd、Pd同位素地球化学研究认为,腾冲火山岩浆源区具有MORB与富集地幔混合之特征,推测为新特提斯俯冲洋壳重新熔融,导致腾冲地区的高钾钙碱性岩浆的火山活动,解释了腾冲在新生代大陆板内构造环境背景下出现岛弧或活动大陆边缘火山岩地球化学特征的现象。马鞍山、打鹰山和黑空山火山高钾钙碱性岩浆经历了岩浆房阶段辉石、钛铁矿的结晶分离作用和岩浆上升过程中斜长石的结晶分离作用,导致岩浆成分从中基性向中酸性演化,火山岩从玄武质粗安岩→粗安岩→粗面质英安岩演化。