不同海域沉积物对尿素吸附的实验模拟研究

本文对采自渤海、黄海和东海3个典型海域的沉积物进行了尿素吸附/解吸的实验室模拟研究,用Freundlich吸附模型和Henry吸附模型分析了不同沉积物对尿素吸附的热力学特性,并研究了温度、沉积物粒径、有机质含量等因素对尿素在沉积物表面吸附的影响。结果表明,沉积物对尿素的吸附/解吸过程总体呈现3个阶段:快速吸附阶段（0~5 h）—慢速吸附阶段（5~12 h）—平衡阶段（12 h之后）。当水体中的尿素浓度较低时,沉积物解吸释放尿素,随着上覆水中尿素浓度逐渐增加,沉积物对上覆水中的尿素产生吸附行为,各海区沉积物对尿素的吸附能力由强至弱依次为渤海、东海、黄海,这可能与沉积物的类型有关。Freundlich方程和Henry方程均可模拟沉积物对尿素的吸附,温度、粒径以及沉积物中有机质含量等因素均对尿素在沉积物上的吸附产生影响,随着温度升高,尿素在沉积物上的吸附量变小,沉积物粒径越小,有机质含量越高,吸附尿素的能力越强,因此,揭示尿素在沉积物表面的环境行为时,必须考虑以上因素的影响。     

Experimental Study on Sloshing Characteristics in the Elastic Tank Based on Morlet Wavelet Transform

Hydroelastic effect of sloshing is studied through an experimental investigation. Different excitation frequencies are considered with low-fill-depth and large amplitude. Morlet wavelet transform is introduced to analyze the free surface elevations and sloshing pressures. It focuses on variations and distributions of the wavelet energy in elastic tanks. The evolutions of theoretical and experimental wavelet spectra are discussed and the corresponding Fourier spectrums are compared. Afterwards, average values of the wavelet spectra are extracted to do a quantitative study at various points. From the wavelet analysis, sloshing energies are mainly distributed around the external excitation frequency and expanded to high frequencies under violent condition. In resonance, experimental wavelet energy of the elevation in elastic tanks is obviously less than that in the rigid one; for sloshing pressures, the elastic wavelet energy close to the rigid one and conspicuous impulse is observed. It recommends engineers to concern the primary natural frequency and impulsive peak pressures.     

Structural, curvature and electronic properties of Rh adsorption on armchair single-walled carbon nanotube

This paper systematically studies the rolling effects of the (n, n) single-wall carbon nanotubes (SWCNT) with different curvatures on Rh adsorption behaviours by using density functional theory. The outside charge densities of SWCNTs are found to be higher than those inside, and the differences decrease with the increase of the tube radius. This electronic property led to the discovery that the outside adsorption energies are higher than the inside ones, and that the differences are reduced with the increase of the tube radius. Partial density of states and charge density difference indicate that these strong interactions induce electron transfer between Rh atoms and SWCNTs.     

Exact solution of entanglement of the double Jaynes—Cummings model without rotating wave approximation

This paper investigates the influences of atom--field coupling and dipole--dipole coupling for atoms on the entanglement between two atoms by means of concurrence. The results show that the sudden death occurs when the atom--field coupling is strong enough, and the collapse and the revival appear when the dipole--dipole interaction is strong enough.     

基于物理特征的平面流场拓扑简化算法

基于网格合并思想实现的平面流场拓扑简化,存在物理特征被忽略和并行实现困难的问题,难以满足远程可视化的要求。文中提出1种基于物理特征的平面流场拓扑简化算法。算法通过计算生成平面流场的物理特征参数图像,利用图像分割提取平面流场的特征区域达到流场简化的目的。实验结果表明,算法能从物理特征和宏观的角度出发快速、准确描述平面流场的拓扑结构,为平面流场可视化提供了1种新方法。     

云南热区≥10℃和≥18℃年积温及日数的分布规律研究

云南热区以其独特的自然地理条件,在我国热区的研究与开发中占有极其重要的地位。利用云南实测地面气温资料等,采用线性回归及残差分析等分析方法,分析了云南热区森林生态系统≥10℃积温及其日数、≥18℃积温等热量指标在不同地区的空间分布规律及原因。结果表明,云南热区不同区域≥10℃积温及其日数、≥18℃积温等热量指标都有明显的空间差异。根据这些划分热量带的基本指标,以及热区分布县市的最低海拔和增温或降温的效应,对其热区分布的海拔上限进行了估测,为准确确定云南热区分布的空间格局及各县市热带和南亚热带的热区范围及热区的主要特性提供了依据。     

Simultaneous quantification of greenhouse gas and nitric oxide emissions from subtropical conventional vegetable systems: a 2-site field case study in Sichuan Basin

Quantification of greenhouse gases[nitrous oxide(N₂O)and methane(CH₄)]and nitric oxide(NO)emissions from subtropical conventional vegetable systems through multi-site field measurements are needed to obtain accurate regional and global estimates.N2 O,NO and CH4 emissions from subtropical conventional vegetable systems were simultaneously measured at two different sites with hilly topography in the Sichuan basin,southwest China by using the static chamber gas chromatography technique.Results showed that annual soil N₂O and NO fluxes for the treatment receiving N fertilizer ranged from 6.34-7.71 kg N ha^-1 yr^-1 and 0.69-0.85 kg N ha^-1 yr^-1,respectively,while decreased soil CH4 uptakes by 26.4%as compared with no N fertilizer addition across our two sites of experiment.Overall,the average direct N2 O and NO emission factor(EFd)were 0.71%and 0.12%,respectively,which were both lower than the available EFd for subtropical conventional vegetable systems.This finding indicates that current regional and global estimates of N₂O and NO emissions from vegetable fields are likely overestimated.Background N₂O emissions(3.42-3.62 kg N ha^-1 yr^-1)from the subtropical conventional vegetable systems were relatively high as compared with available field measurements worldwide,suggesting that background N₂O emissions cannot be ignored for regional estimate of N₂O emissions in subtropical region.Nevertheless,the significantly intra-and inter-annual variations in N₂O,CH₄ and NO emissions were also observed in the present study,which could be explained by temporal variations of environmental variables(i.e.soil temperature and moisture).The differences in N₂O and NO EFd and CH₄emissions between various vegetable systems in particular under subtropical conditions should be taken into account when compiling regional or global inventories and proposing mitigation practices.     

京郊门城镇地面塌陷危险性研究

采空地面塌陷是门城镇地区危害性最严重的地质灾害类型。根椐实地勘察资料 ,论述了地面塌陷的分布特征和形成条件 ;选取与塌陷密切相关的 1 1个因素 ,采用二级模糊综合评判法对地面塌陷的危险度进行了分区预测。     

山东中新世山旺组生物群的古生态

山东临朐产出的中新世山旺组化石群,保存精美、属种分异度高。50多年来,经发掘和研究,目前已从约30余米的硅藻页岩沉积中报导了真菌、硅藻、介形虫、孢粉、昆虫、鱼类、两栖动物、爬行类、鸟类、哺乳动物及遗迹化石等十几个门类的化石,共计400余属700多种。本文总结了化石与周围无机界的关系、化石的埋藏特征、形成原因以及相关古生态学问题――古气候、古温度、古纬度、古地形、山旺湖的水文性质、湖水的季节性变化与硅藻页岩的纹层、动植物群的营养结构以及山旺盆地的沉积历史。     

东南极伊利莎白公主地LGB65点的雪层密度与剖面特征

对东南极冰盖伊利莎白公主地LGB65点的50m雪芯及雪坑进行了雪层密度与剖面分析。结果表明，该处雪的密实化过程属冷型落实化类型，第一和第二临界密度深度分别为10．4m和60．4m深霜不育，雪层中为数不多的雏形深霜层厚度仅几厘米，多分布在冰壳层的上、下两侧，16．0m以上，发芯透光性的变化不明显，之下，透光性逐渐表现出韵律变化，雪层中辐射壳和风壳频繁出现，其中辐射壳可作为划分年层的重要依据，综合雪层内的各种层位特征，初步划分出LGB65雪芯的年层约为243a，总的年平均积累率为131．9mm，20世纪60年代年积累率低于平均水平，70年代中期以后，;积累率出现大幅度增加，进250a来该处的年积累率呈增大趋势。