An approach to determination of phenolic compounds in seawater using SPME-GC-MS based on SWCNTs coating

Phenolic compounds have become one kind of the important pollutants of the marine environment. Single-walled Carbon nanotubes, as one-dimensional nano materials, have light weight and perfect hexagonal structure of connections, with many unusual mechanical, chemical and electrical properties. In recent years, with the research of carbon nanotubes and other nano materials, the application prospect is also constantly discussed. In this paper, homemade single-walled carbon nanotubes(SWCNTs) coating was used for establishing an analytical approach to the determination of five kinds of phenolic compounds in seawater using SPME-GC-MS. Optimal conditions: After saturation was conducted with Na Cl, and p H was adjusted to 2.0 with H_2SO_4, the extract was immersed in a water bath at 40 for GC℃-MS determination through 40-min agitating extraction at 500 rmin~(-1) and 3-min desorption at 280℃. The liniearities ranged between 0.01-100 μg L~(-1), and the determination limits ranged between 1.5-10 ngL~(-1). The relative standard deviation(RSD, n = 5) was less than 6.5%. For the phenolic compounds obtained from the spiked recovery test for actual seawater samples, the rates of recovery were 87.5%-101.7%, and the RSDs were less than 8.8%, which met the requirements of determination. Due to its simplicity, high efficiency and low consumption, this approach is suitable for the analysis of trace amounts of phenolic compounds in marine waters.     

The characteristics of rill development and their effects on runoff and sediment yield under different slope gradients

Rill formation is the predominant erosion process in slope land in the Loess Plateau, China. This study was conducted to investigate rill erosion characteristics and their effects on runoff and sediment yielding processes under different slope gradients at a rate of 10°, 15°, 20° and 25° with rainfall intensity of 1.5 mm min-1 in a laboratory setting. Results revealed that mean rill depth and rill density has a positive interrelation to the slope gradient. To the contrary, width-depth ratio and distance of the longest rill to the top of the slope negatively related to slope gradient. All these suggested that increasing slope steepness could enhance rill headward erosion, vertical erosion and the fragmentation of the slope surface. Furthermore,total erosion tended to approach a stable maximum value with increasing slope, which implied that there is probably a threshold slope gradient where soil erosion begins to weaken. At the same time, the correlation analysis showed that there was a close connection between slope gradient and the variousindices of soil erosion: the correlation coefficients of slope gradient with maximal rill depth, number of rills and the distance of the longest rill from the top of the slope were 0.98, 0.97 and-0.98, respectively,indicating that slope gradient is the major factor of affecting the development of rills. Furthermore,runoff was not sensitive to slope gradient and rill formation in this study. Sediment concentration,however, is positively related to slope gradient and rill formation, the sediment concentrations increased rapidly after rill initiation, especially. These results may be essential for soil loss prediction.     

Risk assessment of maize drought disaster in southwest China using the Environmental Policy Integrated Climate model

The East Asian monsoon has a tremendous impact on agricultural production in China. An assessment of the risk of drought disaster in maize-producing regions is therefore important in ensuring a reduction in such disasters and an increase in food security. A risk assessment model, EPIC(Environmental Policy Integrated Climate) model, for maize drought disasters based on the Erosion Productivity Impact Calculator crop model is proposed for areas with the topographic characteristics of the mountainous karst region in southwest China. This region has one of the highest levels of environmental degradation in China. The results showed that the hazard risk level for the maize zone of southwest China is generally high. Most hazard index values were between 0.4 and 0.5,accounting for 47.32% of total study area. However,the risk level for drought loss was low. Most of the loss rate was 0.1, accounting for 96.24% of the total study area. The three high-risk areas were mainlydistributed in the parallel ridge–valley areas in the east of Sichuan Province, the West Mountain area of Guizhou Province, and the south of Yunnan Province.These results provide a scientific basis and support for the reduction of agricultural drought disasters and an increase in food security in the southwest China maize zone.     

Temporal and spatial variations in extreme temperatures in the Qilian Mountains-Hexi Corridor over the period 1960-2013

Based on daily maximum and minimum temperatures at 18 meteorological stations in the Qilian Mountains and Hexi Corridor between 1960 and 2013, temporal and spatial variations in extreme temperatures were analysed using linear trends, ten-point moving averages and the Mann-Kendall test. The results are as follows: The trends in the majority of the extreme temperature indices were statistically significant, and the changes in the extreme temperatures were more obvious than the changes in the extreme values. The trends were different for each season, and the changes in rates and intensities in summer and autumn were larger than those in spring and winter. Unlike the cold indices, the magnitudes and trends of the changes in the warm indices were larger and more significant in the Hexi Corridor than in the Qilian Mountains. Abrupt changes were detected in the majority of the extreme temperature indices, and the extreme cold indices usually occurred earlier than the changes in the extreme warm indices. The abrupt changes in the extreme temperatures in winter were the earliest among the four seasons, indicating that these temperature changes were the most sensitive to global climate change. The timing of the abrupt changes in certain indices was consistent throughout the study area, but the changes in the cold indices in the Hexi Corridor occurred approximately four years before those in the Qilian Mountains. Similarly, the changes in the warm indices in the western Hexi Corridor preceded those of the other regions.     

关于城镇基准地价更新的思考

1基准地价更新技术途径基准地价更新是在土地定级或划分均质区域的基础上,用土地收益、市场交易的样点地价及地价指数等来重新确定各类用途土地在现状利用条件下于特定基准日的土地使用权平均价格。基准地价定期更新,既保持了基准地价的现势性,又能充分发挥基准地价在土地市场和土地资产管理中的重要作用。基准地价更新要严格按照国土资源部《城镇土地分等定级规程》、《城镇土地估价规程》、《中华人民共和国土地管理法》为主要技术依据,在借鉴国内已有的城市基准地价更新经验的基础上,从该地区实际情况出发,充分利用已有的土地定级估价、…     

����ˮ׼ϵͳ��������ѧ�о�

?????????????????????????????????е???????,???????????????????????????????????????????????????????????????HLS???????????????????     

关于垂准仪校准过程中铅垂度的研究

对垂准仪校准过程中同轴度和一测回垂准测量标准偏差进行了分析,并提出了铅垂 p 角的概念.     

固体矿产储量估算系统的研究与实现

通过对固体矿产储量估算过程的详细调研,对储量估算过程中的单工程圈定算法、矿体剖面连接以及传统的储量估算方法中的平行剖面法和地质块段法做了详细研究,并针对储量计算的可视化及交互技术进行了研究,实现了一种基于Windows操作系统、MapGIS地理信息系统平台的固体矿产储量估算原型系统,实现了对固体矿产勘查数据的有效存储、管理、可视化分析及评价。     

Relationship of Arctic sea ice and Northern Hemispheric 500 hPa Polar vortices

Using the NCEP/NCAR reanalysis monthly 500 hPa height data on a 2.5 latitude-longitude grid and 1°×1° sea ice data,the polar vortex area,intensity index and arctic sea ice area index are calculated respectively,and the meridional distribution,period variation and the abrupts in the long range trend are analyzed to study their relationship.The results show that the meridional distribution of sea ice and polar vortex h-ave distinctive difference,the relative positions of them are different in the eastern and western hemispheres,and exept they have periods of 4 months,quasi half year,quasi year,4-5 years and 10 years commonly,and each of them has its own respective variation as well.The sea ice area is decreasing apparently since 1980's,so is the polar vortex area,but their abrupt changge time are different totally.The area of sea ice and polar vortex has prominent positive correlation,but the relationship of sea ice intensity,polar vortex intensity,polar vortex area is complicated.     

Impact factors on distribution and characteristics of natural plant community in reclamation zones of Changjiang River estuary

To identify impact factors on the distribution and characters of natural plants community in reclamation area, with survey data from 67 plant quadrats in July 2009, soil properties data from 216 sampling points in April 2009, and TM (30 m) data in 2006, the composition and characteristics of natural plants community in different time of the Fengxian area in the Changjiang (Yangtze) River estuary were analyzed with two-way indicator species analysis (TWINSPAN), multivariate analysis of variance (MANOVA), detrended canonical correspondence analysis (DCCA) and canonical correspondence analysis (CCA). The results show that: 1) The plant communities in the reclaimed area are mainly mesophytes and helophytic-mesophytic transitional communities, showing a gradient distribution trend with the change in reclamation years. Species richness (MA), species diversity (H) and above-ground biomass also increase with the increase of reclamation years. Nevertheless, they appear to decline slightly in the middle and late reclamation period (> 30 years). 2) With the rise in land use levels, the changes in species richness and species diversity tend to increase at first and then decrease; species dominance (D), however, tends to decline; and above-ground biomass increases slightly. 3) The distribution of the plant community is mainly influenced by the following factors: land use levels (R = 0.55, p < 0.05), soil moisture (R = 0.53, p < 0.05), soil salinity (R = 0.43, p < 0.05) and reclamation time (R = 0.40, p < 0.05).