Timing and genesis of base-metal mineralisation in black shales of the Upper Permian Ravnefjeld Formation,Wegener Halvø, East Greenland

Bituminous mud shales of the Upper Permian Ravnefjeld Formation (Zechstein 1 equivalent) are mineralised with zinc, lead and copper within a ca. 50 km² area on Wegener Halvø in central East Greenland. The occurrence of base-metal sulphides in shale nodules cemented prior to compaction indicates an early commencement of base-metal mineralisation. In other cases, post-compactional sulphide textures are observed. Homogeneous lead isotope signatures of galena and sphalerite from the shales (²⁰⁶Pb/²⁰⁴Pb: 18.440–18.466; ²⁰⁷Pb/²⁰⁴Pb: 16.554–16.586; ²⁰⁸Pb/²⁰⁴Pb: 38.240–38.326) suggest that all base metals were introduced during a single hydrothermal event. Therefore, post-compactional textures are believed to result from recrystallisation of early diagenetic sulphides during deep burial in the Upper Cretaceous to Tertiary. Lead isotope signatures of galena hosted in Upper Permian carbonate build-ups are relatively heterogeneous compared to those of the shale-hosted sulphides. The observed relations indicate a shared lead source for the two types of mineralisation, but different degrees of homogenisation during mineralisation. This suggests that lead was introduced to the carbonate rocks and black shales during two separate events. δ³⁴S of base-metal sulphides in the Ravnefjeld Formation lie between –12 and –4‰, whereas synsedimentary and early diagenetic pyrite in unmineralised shales in general have δ³⁴S between –47 and –16.5‰. Early diagenetic pyrite in the Wegener Halvø area in general has δ³⁴S 15 to 20‰ higher than the same pyrite morphotype in Triaselv in the western part of the basin. This relatively high δ³⁴S can be explained by extensive microbial sulphate reduction within persistent euxinic (super-anoxic) bottom waters under which supply of isotopically light seawater sulphate (and disproportionation of intermediate sulphur compounds) was restricted. The sulphur in the base-metal sulphides is believed to represent sulphide-dominated pore water, enriched in ³⁴S due to preferential removal of ³²S by sulphate-reducing bacteria and precipitation of diagenetic pyrite in the near-seafloor environment. We suggest that the sulphide-dominated pore water was trapped in the shale formation prior to introduction of base-metal-bearing fluids through fractures in the underlying carbonates, and that sulphide precipitation took place when the two fluids met. δ³⁴S values of carbonate-hosted base-metal sulphides fall within the same range as the shale-hosted ones. The relationship between barite and sulphides and evidence for pre-mineralisation entrapment of liquid hydrocarbons in the carbonates suggest that the sulphide in this case is derived by in-situ thermochemical sulphate reduction (TSR). Measured fractionation between sulphide and sulphate ranges from 18.5 to 24.4‰, suggesting temperatures of TSR around 70 to 100 °C. Vitrinite reflectance measurements in mineralised shale samples are all between 1.7 and 2.0%, except for samples taken close to a Tertiary dyke giving ca. 3.0%. Vitrinite reflectance data are comparable to previously published data from unmineralised shale samples in the area and could not be proven to correlate with the degree of mineralisation. This indicates that any early hydrothermal effect has been overprinted later, probably during deep burial in the Late Cretaceous to Early Tertiary as previously proposed.     

‘Modelling the Arctic Boundary Layer: An Evaluation of Six Arcmip Regional-Scale Models using Data from the Sheba Project’

A primary climate change signal in the central Arctic is the melting of sea ice. This is dependent on the interplay between the atmosphere and the sea ice, which is critically dependent on the exchange of momentum, heat and moisture at the surface. In assessing the realism of climate change scenarios it is vital to know the quality by which these exchanges are modelled in climate simulations. Six state-of-the-art regional-climate models are run for one year in the western Arctic, on a common domain that encompasses the Surface Heat Budget of the Arctic Ocean (SHEBA) experiment ice-drift track. Surface variables, surface fluxes and the vertical structure of the lower troposphere are evaluated using data from the SHEBA experiment. All the models are driven by the same lateral boundary conditions, sea-ice fraction and sea and sea-ice surface temperatures. Surface pressure, near-surface air temperature, specific humidity and wind speed agree well with observations, with a falling degree of accuracy in that order. Wind speeds have systematic biases in some models, by as much as a few metres per second. The surface radiation fluxes are also surprisingly accurate, given the complexity of the problem. The turbulent momentum flux is acceptable, on average, in most models, but the turbulent heat fluxes are, however, mostly unreliable. Their correlation with observed fluxes is, in principle, insignificant, and they accumulate over a year to values an order of magnitude larger than observed. Typical instantaneous errors are easily of the same order of magnitude as the observed net atmospheric heat flux. In the light of the sensitivity of the atmosphere–ice interaction to errors in these fluxes, the ice-melt in climate change scenarios must be viewed with considerable caution.     

The Greenland Ice Core Chronology 2005, 15–42 ka. Part 2: comparison to other records

A new Greenland Ice Core Chronology (GICC05) based on multi-parameter counting of annual layers has been obtained for the last 42 ka. Here we compare the glacial part of the new time scale, which is based entirely on records from the NorthGRIP ice core, to existing time scales and reference horizons covering the same period. These include the GRIP and NorthGRIP modelled time scales, the Meese-Sowers GISP2 counted time scale, the Shackleton–Fairbanks GRIP time scale (SFCP04) based on ¹⁴C calibration of a marine core, the Hulu Cave record, three volcanic reference horizons, and the Laschamp geomagnetic excursion event occurring around Greenland Interstadial 10. GICC05 is generally in good long-term agreement with the existing Greenland ice core chronologies and with the Hulu Cave record, but on shorter time scales there are significant discrepancies. Around the Last Glacial Maximum there is a more than 1 ka age difference between GICC05 and SFCP04 and a more than 0.5 ka discrepancy in the same direction between GICC05 and the age of a recently identified tephra layer in the NorthGRIP ice core. Both SFCP04 and the tephra age are based on ¹⁴C-dated marine cores and fixed marine reservoir ages. For the Laschamp event, GICC05 agrees with a recent independent dating within the uncertainties.     

Human-driven topographic effects on the distribution of forest in a flat,lowland agricul-tural region简

Complex topography buffers forests against deforestation in mountainous regions. However, it is unknown if terrain also shapes forest distribution in lowlands where human impacts are likely to be less constrained by terrain. In such regions, if important at all, to- pographic effects will depend on cultural-historical factors and thus be human-driven （an- thropogenic） rather than natural, except in regions where the general climate or extreme soils limit the occurrence of forests. We used spatial regression modeling to assess the extent to which topographic factors explain forest distribution （presence-absence at a 48x48 m resolu- tion） in a lowland agricultural region （Denmark, 43,075 km2） at regional and landscape scales （whole study area and 10x10 km grid cells, respectively）, how landscape-scale for- est-topography relationships vary geographically, and which potential drivers （topographic heterogeneity, forest cover, clay content, coastal/inland location） determine this geographic heterogeneity. Given a moist temperate climate and non-extreme soils all landscapes in Denmark would naturally be largely forest covered, and any topographic relationships will be totally or primarily human-driven. At regional scale, topographic predictors explained only 5% of the distribution of forest. In contrast, the explanatory power of topography varied from 0%-61% at landscape scale, with clear geographic patterning. Explanatory power of topog- raphy at landscape scale was moderately dependent on the potential drivers, with topog- raphic control being strongest in areas with high topographic heterogeneity and little forest cover. However, these conditioning effects were themselves geographically variable. Our findings show that topography by shaping human land-use can affect forest distribution even in flat, lowland regions, but especially via localized, geographically variable effects.     

New multifunctional hunting landscapes in Denmark

Between 1992 and 2008 subsidization of mandatory set aside land under the EU Common Agricultural Policy (CAP) gave rise to the establishment of a characteristic type of multifunctional hunting landscapes in Denmark, primarily located on fallow land in tilled valley bottoms. A national survey of these landscapes in 2006 has been carried out and 1061 hunting areas have been identified nationwide. Subsidies relating to set aside land acted as a supplementary type of income, which supported the development of multifunctional land use on marginal soils where the income from hunting and subsidies in combination was a viable alternative to monofunctional rotational agriculture. Hunting landscapes developed as the consequence of landscape management strategies designed to comply with the requirements of the CAP while improving habitat conditions for wildlife and increasing income from hunting rental activities. Forty-seven percent of the hunting landscapes in 2006 were in rotational production in 2010 while 19% were used for other agricultural purposes and 34% were taken out of the subsidy regime and removed from the general agricultural register. In 2012, a total of 431 such areas ? 41% of the areas identified in 2006 ? were still used for hunting. The number and geographical distribution of the hunting landscapes seems closely related to the potential average hunting rent, the level of urbanisation and the occurrence of manorial estates with traditions for multifunctional land use as part of their economic strategy. Implications for the ongoing discussion on land use policy concerning land sharing vs. land sparing is discussed.