Some comments on physical processes at and near the tropopause

The major physical processes at and near the tropopause are evaluated; these processes are radiation, convection and turbulence, advection and vertical convergence. Calculations of instantaneous long wave radiative temperature change for observed and postulated moisture distributions show that radiation usually acts to smooth the temperature profile. Observations and the principle of continuity show that convection is infrequent and unimportant in establishing the tropopause. General principles and numerical integration of the heat conduction equation for special cases show that turbulence will act to smooth the temperature profile unless flux has a certain relationship to hydrostatic stability. Observations, calculations and the principle of continuity show that advection and vertical convergence cannot be universal mechanisms of tropopause formation.

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Zusammenfassung Die grundlegenden physikalischen Prozesse an und in der Nähe der Tropopause werden bestimmt; diese Prozesse sind Strahlung, Konvektion und Turbulenz, Advektion und Vertikalakonvergenz. Berechnungen von momentanen Temperaturänderungen durch langwellige Strahlung für beobachtete und vorgegebene Feuchtigkeitsverteilungen lassen erkennen, daß die Strahlung gewöhnlich das Temperaturprofil auszugleichen sucht. Beobachtungen und das Kontinuitätsprinzip zeigen, daß Konvektion selten und für die Bildung der Tropopause unwichtig ist. Allgemeine Prinzipien und numerische Integration der Wärmeleitungsgleichung für spezielle Fälle zeigen, daß die Turbulenz das Temperaturprofil auszugleichen sucht, außer wenn der Wärmestrom in spezieller Beziehung zur hydrostatischen Stabilität steht. Beobachtungen, Berechnungen und das Kontinuitätsprinzip führen zu der Feststellung, daß Advektion und vertikale Konvergenz nicht als allgemeine Mechanismen für die Bildung der Tropopause angesehen werden können.

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Résumé L'auteur évalue les processus physiques fondamentaux de la tropopause et à sa proximité; ces processus sont le rayonnement, la convection et la turbulence, l'advection et la convergence verticale. Le calcul de variations instantanées de la température dûes au rayonnement de grande longueur d'onde, par une distribution observée et supposée de l'humidité, montre qu'en général le rayonnement semble atténuer et égaliser le profil de la température. Les observations et le principe de continuité font admettre que la convection est rare et de peu d'importance pour la formation de la tropopause. Des principes généraux et une intégration numérique de l'équation de transmission de chaleur pour des can spéciaux montrent que la turbulence tend à égaliser le profil de température à moins que le flux de chaleur ne soit en relation spécifique avec la stabilité hydrostatique. Des observations, des calculs et le principe de continuité prouvent que l'advection et la convergence verticale ne peuvent être considérées comme étant des mécanismes généraux pour la formation de la tropopause.

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With 4 Figures

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The research reported here was supported in part by the Geophysical Research Directorate, A. F. Cambridge Research Center.     

Recent Mountain Building at the Junction Zone of the Northwestern Caucasus and Intermediate Kerch–Taman Region,Russia

Geotectonics - The recent evolution of the marginal segment of the Northwestern Caucasus orogen at its junction with the Kerch–Taman periclinal trough has been studied. Geomorphological...     

Recent progress on combining geomorphological and geochronological data with ice sheet modelling,demonstrated using the last British–Irish Ice Sheet

Palaeo-ice sheets are important analogues for understanding contemporary ice sheets, offering a record of ice sheet behaviour that spans millennia. There are two main approaches to reconstructing palaeo-ice sheets. Empirical reconstructions use the available glacial geological and chronological evidence to estimate ice sheet extent and dynamics but lack direct consideration of ice physics. In contrast, numerically modelled simulations implement ice physics, but often lack direct quantitative comparison with empirical evidence. Despite being long identified as a fruitful scientific endeavour, few ice sheet reconstructions attempt to reconcile the empirical and model-based approaches. To achieve this goal, model-data comparison procedures are required. Here, we compare three numerically modelled simulations of the former British–Irish Ice Sheet with the following lines of evidence: (a) position and shape of former margin positions, recorded by moraines; (b) former ice-flow direction and flow-switching, recorded by flowsets of subglacial bedforms; and (c) the timing of ice-free conditions, recorded by geochronological data. These model–data comparisons provide a useful framework for quantifying the degree of fit between numerical model simulations and empirical constraints. Such tools are vital for reconciling numerical modelling and empirical evidence, the combination of which will lead to more robust palaeo-ice sheet reconstructions with greater explicative and ultimately predictive power.     

Development of a reactive zone technology for simultaneous in situ immobilisation of radium and uranium

Simultaneous in situ immobilisation of uranium (U) and radium (²²⁶Ra) by injectible amounts of grey cast iron (gcFe), nano-scale iron (naFe) and a gcFe/MnO₂ mixture (1:1) was studied in batch and column tests. Both 0.5 g/L naFe and gcFe are effective in ²²⁶Ra and U removal from mine water, whereas MnO₂ addition clearly increased the efficiency of gcFe for ²²⁶Ra and U immobilisation. In a column test with 0.6 wt% gcFe/MnO₂ mixture (1:1), neither ²²⁶Ra nor U was detected in the effluent after replacement of 45 pore volumes. A sequential extraction under flow condition revealed ²²⁶Ra to be mostly occluded in manganese oxides. Uranium was mostly sorbed onto poorly crystalline iron hydroxides, but a significant part was found to be occluded in manganese oxides also. The results of this study suggest that MnO₂ promotes iron hydroxide formation under slightly reducing environmental conditions resulting in an increased pollutant retention capacity.     

The Dynamics of Benthic Respiration at a Mid-Shelf Station Off Oregon

Mid-shelf sediments off the Oregon coast are characterized as fine sands that trap and remineralize phytodetritus leading to the consumption of significant quantities of dissolved oxygen. Sediment oxygen consumption (SOC) can be delayed from seasonal organic matter inputs because of a transient buildup of reduced constituents during periods of quiescent physical processes. Between 2009 and 2013, benthic oxygen exchange rates were measured using the noninvasive eddy covariance (EC) method five separate times at a single 80-m station. Ancillary measurements included in situ microprofiles of oxygen at the sediment–water interface, and concentration profiles of pore water nutrients and trace metals, and solid-phase organic C and sulfide minerals from cores. Sediment cores were also incubated to derive anaerobic respiration rates. The EC measurements were made during spring, summer, and fall conditions, and they produced average benthic oxygen flux estimates that varied between ?2 and ?15 mmol m^?2 d^?1. The EC oxygen fluxes were most highly correlated with bottom-sensed, significant wave heights (H _s). The relationship with H _s was used with an annual record of deepwater swell heights to predict an integrated oxygen consumption rate for the mid-shelf of 1.5 mol m^?2 for the upwelling season (May–September) and 6.8 mol m^?2 y^?1. The annual prediction requires that SOC rates are enhanced in the winter because of sand filtering and pore water advection under large waves, and it counters budgets that assume a dominance of organic matter export from the shelf. Refined budgets will require winter flux measurements and observations from cross-shelf transects over multiple years.     

The coupled δC-radiocarbon systematics of three Late Glacial/early Holocene speleothems; insights into soil and cave processes at climatic transitions

The coupled δ¹³C-radiocarbon systematics of three European stalagmites deposited during the Late Glacial and early Holocene were investigated to understand better how the carbon isotope systematics of speleothems respond to climate transitions. The emphasis is on understanding how speleothems may record climate-driven changes in the proportions of biogenic (soil carbon) and limestone bedrock derived carbon. At two of the three sites, the combined δ¹³C and ¹⁴C data argue against greater inputs of limestone carbon as the sole cause of the observed shift to higher δ¹³C during the cold Younger Dryas. In these stalagmites (GAR-01 from La Garma cave, N. Spain and So-1 from Sofular cave, Turkey), the combined changes in δ¹³C and initial ¹⁴C activities suggest enhanced decomposition of old stored, more recalcitrant, soil carbon at the onset of the warmer early Holocene. Alternative explanations involving gradual temporal changes between open- and closed-system behaviour during the Late Glacial are difficult to reconcile with observed changes in speleothem δ¹³C and the growth rates. In contrast, a stalagmite from Pindal cave (N. Spain) indicates an abrupt change in carbon inputs linked to local hydrological and disequilibrium isotope fractionation effects, rather than climate change. For the first time, it is shown that while the initial ¹⁴C activities of all three stalagmites broadly follow the contemporaneous atmospheric ¹⁴C trends (the Younger Dryas atmospheric ¹⁴C anomaly can be clearly discerned), subtle changes in speleothem initial ¹⁴C activities are linked to climate-driven changes in soil carbon turnover at a climate transition.