The stable isotope signature of kilometre-scale fracturedominated metamorphic fluid pathways, Mary Kathleen, Australia

Abstract Large calcite veins and pods in the Proterozoic Corella Formation of the Mount Isa Inlier provide evidence for kilometre-scale fluid transport during amphibolite facies metamorphism. These 10- to 100-m-scale podiform veins and their surrounding alteration zones have similar oxygen and carbon isotopic ratios throughout the 200 × 10-km Mary Kathleen Fold Belt, despite the isotopic heterogeneity of the surrounding wallrocks. The fluids that formed the pods and veins were not in isotopic equilibrium with the immediately adjacent rocks. The pods have δ¹³C_calcite values of –2 to –7% and δ¹⁸O_calcite values of 10.5 to 12.5%. Away from the pods, metadolerite wallrocks have δ¹⁸O_whole-rock values of 3.5 to 7%. and unaltered banded calc-silicate and marble wallrocks have δ¹³C_calcite of –1.6 to –0.6%, and δ¹⁸O_calcite of 18 to 21%. In the alteration zones adjacent to the pods, the δ¹⁸O values of both metadolerite and calc-silicate rocks approach those of the pods. Large calcite pods hosted entirely in calc-silicates show little difference in isotopic composition from pods hosted entirely in metadolerite. Thus, 100- to 500-m-scale isotopic exchange with the surrounding metadolerites and calc-silicates does not explain the observation that the δ¹⁸O values of the pods are intermediate between these two rock types. Pods hosted in felsic metavolcanics and metasiltstones are also isotopically indistinguishable from those hosted in the dominant metadolerites and calc-silicates. These data suggest the veins are the product of infiltration of isotopically homogeneous fluids that were not derived from within the Corella Formation at the presently exposed crustal level, although some of the spread in the data may be due to a relatively small contribution from devolatilization reactions in the calc-silicates, or thermal fluctuations attending deformation and metamorphism. The overall L-shaped trend of the data on plots of δ¹³C vs. δ¹⁸O is most consistent with mixing of large volumes of externally derived fluids with small volumes of locally derived fluid produced by devolatilization of calc-silicate rocks. Localization of the vein systems in dilatant sites around metadolerite/calc-silicate boundaries indicates a strong structural control on fluid flow, and the stable isotope data suggest fluid migration must have occurred at scales greater than at least 1 km. The ultimate source for the external fluid is uncertain, but is probably fluid released from crystallizing melts derived from the lower crust or upper mantle. Intrusion of magmas below the exposed crustal level would also explain the high geothermal gradient calculated for the regional metamorphism.     

The middle pleistocene deposits of Waverley Wood Pit,Warwickshire, England

A complex of channels underlying the Baginton-Lillington Gravel (Baginton Formation) at Waverley Wood Quarry, Warwickshire is described. Fossil pollen and plant macrofossils, Coleoptera, Ostracoda, Mollusca and Mammalia are described from the channel-fill deposits. Consideration of all the evidence allows the identification of four separate stages of channel fill which largely occurred under a cool temperate climate. At the top of Channel 2 evidence for a cold, continental climatic episode can be recognised, suggesting that the whole complex was deposited under a fluctuating climate at the end of a temperate stage. At two levels in the channels human artefacts were recovered confirming the presence of Palaeolithic people in Warwickshire during the deposition of the sediments. Amino-acid geochronology suggests an age within the ‘Cromerian Complex’ Stage for the channels. The small vertebrate and molluscan faunas indicate that the deposits are no older than the latter part of the ‘Cromerian Complex’ Stage of East Anglia. The regional stratigraphic significance of the Waverley Wood succession is outlined.     

Late Quaternary vegetation changes around Lake Rutundu,Mount Kenya,East Africa: evidence from grass cuticles,pollen and stable carbon isotopes

Woody, subalpine shrubs and grasses currently surround Lake Rutundu, Mount Kenya. Multiple proxies, including carbon isotopes, pollen and grass cuticles, from a 755‐cm‐long core were used to reconstruct the vegetation over the past 38 300 calendar years. Stable carbon‐isotope ratios of total organic carbon and terrestrial biomarkers from the lake sediments imply that the proportion of terrestrial plants using the C₄ photosynthetic pathway was greater during the Late Pleistocene than in the Holocene. Pollen data show that grasses were a major constituent of the vegetation throughout the Late Pleistocene and Holocene. The proportion of grass pollen relative to the pollen from other plants was greatest at the last glacial maximum (LGM). Grass cuticles confirm evidence that C₄ grass taxa were present at the LGM and that the majority followed the cold‐tolerant NADP‐MEC₄ subpathway. Copyright © 2003 John Wiley & Sons, Ltd.     

Estimation of snow water equivalent using microwave radiometry over Arctic first‐year sea ice

The magnitude and spatial distribution of snow on sea ice are both integral components of the ocean–sea‐ice–atmosphere system. Although there exists a number of algorithms to estimate the snow water equivalent (SWE) on terrestrial surfaces, to date there is no precise method to estimate SWE on sea ice. Physical snow properties and in situ microwave radiometry at 19, 37 and 85 GHz, V and H polarization were collected for a 10‐day period over 20 first‐year sea ice sites. We present and compare the in situ physical, electrical and microwave emission properties of snow over smooth Arctic first‐year sea ice for 19 of the 20 sites sampled. Physical processes creating the observed vertical patterns in the physical and electrical properties are discussed. An algorithm is then developed from the relationship between the SWE and the brightness temperature measured at 37 GHz (55°) H polarization and the air temperature. The multiple regression between these variables is able to account for over 90% of the variability in the measured SWE. This algorithm is validated with a small in situ data set collected during the 1999 field experiment. We then compare our data against the NASA snow thickness algorithm, designed as part of the NASA Earth Enterprise Program. The results indicated a lack of agreement between the NASA algorithm and the algorithm developed here. This lack of agreement is attributed to differences in scale between the Special Sensor Microwave/Imager and surface radiometers and to differences in the Antarctic versus Arctic snow physical and electrical properties. Copyright © 2003 John Wiley & Sons, Ltd.     

Timing and tectonic setting of Grenvillian metamorphism—constraints from a transect along Georgian Bay,Ontario*

Systematic mapping of a transect along the well-exposed shores of Georgian Bay, Ontario, combined with the preliminary results of structural analysis, geochronology and metamorphic petrology, places some constraints on the geological setting of high-grade metamorphism in this part of the Central Gneiss Belt. Correlations within and between map units (gneiss associations) have allowed us to recognize five tectonic units that differ in various aspects of their lithology, metamorphic and plutonic history, and structural style. The lowest unit, which forms the footwall to a regional decollement, locally preserves relic pre-Grenvillian granulite facies assemblages reworked under amphibolite facies conditions during the Grenvillian orogeny. Tectonic units above the decollement apparently lack the early granulite facies metamorphism; out-of-sequence thrusting in the south produced a duplex-like structure. Two distinct stages of Grenvillian metamorphism are apparent. The earlier stage (c. 1160–1120 Ma) produced granulite facies assemblages in the Parry Sound domain and upper amphibolite facies assemblages in the Parry Island thrust sheet. The later stage (c. 1040–1020 Ma) involved widespread, dominantly upper amphibolite facies metamorphism within and beneath the duplex. Deformation and metamorphism recently reported from south and east of the Parry Sound domain at c. 1100–1040 Ma have not yet been documented along the Georgian Bay transect. The data suggest that early convergence was followed by a period of crustal thickening in the orogenic core south-east of the transect area, with further advance to the north-west during and after the waning stages of this deformation.     

The Early Pleistocene Praetiglian and Ludhamian pollen stages in the North Sea Basin and their relationship to the marine isotope record

In this paper, the currently accepted correlation of the Early Pleistocene Ludhamian stage of England with the Tiglian‐A sub‐stage of the Netherlands is challenged. Recent investigations of Early Pleistocene marine North Sea deposits from a borehole near Noordwijk (the Netherlands) yielded evidence from molluscs, dinoflagellate cysts and sporomorphs for an alternation of warm‐temperate and arctic intervals within the Praetiglian and Tiglian stages. Marine equivalents of the terrestrial‐based pollen sub‐stages Tiglian A and B have been recognised in the upper part of the sequence. A Praetiglian age can be assigned to the lower part of the sequence on the basis of mollusc analysis. Within the Praetiglian, an alternation of warm and cold phases has been recognised from both the dinoflagellate cyst and molluscan records. Three cold phases within the Praetiglian are tentatively correlated with marine isotope stages (MIS) 96–100. The molluscan assemblages provide evidence for climate forcing of the sea level: highest sea levels are reached in the warm‐temperate intervals. Within the Praetiglian, an interval with an acme zone of the dinoflagellate cyst Impagidinium multiplexum, is correlated with the Ludhamian and tentatively linked to MIS 97 and/or MIS 96. The cold molluscan assemblages from the Noordwijk borehole include an acme zone of Megayoldia thraciaeformis, the first and only occurrence of this North Pacific bivalve in the North Sea Basin. Copyright © 2006 John Wiley & Sons, Ltd.     

Application of an improved self-starter to geoacoustic inversion

The self-starter is improved using the operator of the split-step Pade solution. In addition to providing greater stability and being applicable closer to the source, the improved self-starter is an efficient forward model for geoacoustic inversion. It is necessary to solve only O(10) tridiagonal systems of equations to obtain the acoustic field on a vertical array located O(10) wavelengths from a source. This experimental configuration is effective for geoacoustic inverse problems involving unknown parameters deep in the ocean bottom. For problems involving depth-dependent acoustic parameters, the improved self-starter can be used to solve nonlinear inverse problems involving O(10) unknown sediment parameters in less than a minute on the current generation of workstations