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421.
Recent developments from 2008 to 2009 in ICP-MS engineering, methods and applications are reviewed here. Of particular emphasis are advances in: (a) maximising sensitivity and reducing elemental/isotopic fractionation during laser ablation processing; (b) developing new analytical techniques to measure major, minor and trace element abundances without depending on matrix-matched calibrating materials, pre-determined internal standard concentrations and/or multiple analytical methods; (c) applying in situ and solution-based ICP-MS techniques to the analysis of forensic materials for criminal and/or nuclear investigations; and (d) improving precision and limits of detection of laser ablation multi-collector ICP-MS measurements of (ultra) trace elemental and isotopic abundances.  相似文献   
422.
The recent Heliophysics Virtual Observatory (VxO) effort involves the development of separate observatories with a low overlap in physical domain or area of scientific specialization and a high degree of overlap in metadata management needs. VxOware is a content and metadata management system. While it is intended for use by a VxO specifically, it can also be used by any entity that manages structured metadata. VxOware has many features of a content management system and extensively uses the W3C recommendations for XML (Extensible Markup Language), XQuery (XML Query), and XSLT (Extensible Style Sheet Language Transformations). VxOware has features such as system and user administration, search, user-editable content, version tracking, and a wiki. Besides virtual observatories, the intended user-base of VxOware includes a group or an instrument team that has developed a directory structure of data files and would like to make this data, and its associated metadata, available in the virtual observatory network. One of the most powerful features of VxOware is the ability to link any type of object in the observatory to other objects and the ability for every object to be tagged.  相似文献   
423.
We present a study of water vapour in the Venus troposphere obtained by modelling specific water vapour absorption bands within the 1.18 μm window. We compare the results with the normal technique of obtaining the abundance by matching the peak of the 1.18 μm window. Ground-based infrared imaging spectroscopy of the night side of Venus was obtained with the Anglo-Australian Telescope and IRIS2 instrument with a spectral resolving power of R  2400. The spectra have been fitted with modelled spectra simulated using the radiative transfer model VSTAR. We find a best fit abundance of 31 ppmv (?6 +9 ppmv), which is in agreement with recent results by Bézard et al. (Bézard, B., Fedorova, A., Bertaux, J.-L., Rodin, A., Korablev, O. [2011]. Icarus, 216, 173–183) using VEX/SPICAV (R  1700) and contrary to prior results by Bézard et al. (Bézard, B., de Bergh, C., Crisp, D., Maillard, J.P. [1990]. Nature, 345, 508–511) of 44 ppmv (±9 ppmv) using VEX/VIRTIS-M (R  200) data analyses. Comparison studies are made between water vapour abundances determined from the peak of the 1.18 μm window and abundances determined from different water vapour absorption features within the near infrared window. We find that water vapour abundances determined over the peak of the 1. 18 μm window results in plots with less scatter than those of the individual water vapour features and that analyses conducted over some individual water vapour features are more sensitive to variation in water vapour than those over the peak of the 1. 18 μm window. No evidence for horizontal spatial variations across the night side of the disk are found within the limits of our data with the exception of a possible small decrease in water vapour from the equator to the north pole. We present spectral ratios that show water vapour absorption from within the lowest 4 km of the Venus atmosphere only, and discuss the possible existence of a decreasing water vapour concentration towards the surface.  相似文献   
424.
A numerical surface-water/groundwater model was developed for the lower San Antonio River Basin to evaluate the responses of low base flows and groundwater levels within the basin under conditions of reduced recharge and increased groundwater withdrawals. Batch data assimilation through history matching used a simulation of historical conditions (2006-2013); this process included history-matching to groundwater levels and base-flow estimates at several gages, and was completed in a high-dimensional (highly parameterized) framework. The model was developed in an uncertainty framework such that parameters, observations, and scenarios of interest are envisioned stochastically as distributions of potential values. Results indicate that groundwater contributions to surface water during periods of low flow may be reduced from 6% to 25% with a corresponding 25% reduction in recharge and a 25% increase in groundwater pumping over an 8-year planning period. Furthermore, results indicate groundwater-level reductions in some hydrostratigraphic units are more likely than in other hydrostratigraphic units over an 8-year period under drought conditions with the higher groundwater withdrawal scenario.  相似文献   
425.
Southern rock lobster (Jasus edwardsii) support significant commercial and recreational fisheries in Tasmania, Australia. Since the mid 1990s the number of persons holding recreational lobster licences increased by over 80%, with c. 15 500 persons licensed in 2002/03. Assessment of the recreational fishery has been undertaken periodically since 1996 using a telephone‐diary survey method. The fishery was concentrated off the south‐east and east coasts of Tasmania and characterised by strong seasonality in catch and effort, which peaked markedly early in the fishing year (November‐January). Although pots were the most popular fishing method, daily catch rates by divers were more than double those for pots. Divers selectively harvested larger lobsters than those taken by pots and more frequently attained the daily bag limit of 5 lobsters. The estimated recreational harvest increased significantly since 1996/97 and in 2002/03 effectively reached a management trigger level of 10% of the total allowable commercial catch, flagging a review of recreational management arrangements.  相似文献   
426.
Jeremy Bailey 《Icarus》2009,201(2):444-453
The discovery of the near infrared windows into the Venus deep atmosphere has enabled the use of remote sensing techniques to study the composition of the Venus atmosphere below the clouds. In particular, water vapor absorption lines can be observed in a number of the near-infrared windows allowing measurement of the H2O abundance at several different levels in the lower atmosphere. Accurate determination of the abundance requires a good database of spectral line parameters for the H2O absorption lines at the high temperatures (up to ∼700 K) encountered in the Venus deep atmosphere. This paper presents a comparison of a number of H2O line lists that have been, or that could potentially be used, to analyze Venus deep atmosphere water abundances and shows that there are substantial discrepancies between them. For example, the early high-temperature list used by Meadows and Crisp [Meadows, V.S., Crisp, D., 1996. J. Geophys. Res. 101 (E2), 4595-4622] had large systematic errors in line intensities. When these are corrected for using the more recent high-temperature BT2 list of Barber et al. [Barber, R.J., Tennyson, J., Harris, G.J., Tolchenov, R.N., 2006. Mon. Not. R. Astron. Soc. 368, 1087-1094] their value of 45±10 ppm for the water vapor mixing ratio reduces to 27±6 ppm. The HITRAN and GEISA lists used for most other studies of Venus are deficient in “hot” lines that become important in the Venus deep atmosphere and also show evidence of systematic errors in line intensities, particularly for the 8000 to 9500 cm−1 region that includes the 1.18 μm window. Water vapor mixing ratios derived from these lists may also be somewhat overestimated. The BT2 line list is recommended as being the most complete and accurate current representation of the H2O spectrum at Venus temperatures.  相似文献   
427.
Summary. The ability to locate the hypocentres of earthquakes occurring along ridge crests and fracture zones accurately is a prerequisite to solving several problems associated with seafloor tectonics and oceanic crustal formation. Such resolution has rarely been achieved in the past, often because the seismic networks deployed were inadequate for the task. We demonstrate that sea surface receivers are not useful in such studies, and that the minimum acceptable size for a seafloor network is five receivers, of which at least one must be capable of detecting shear waves unambiguously.  相似文献   
428.
Magnetorotational instability in a rotating liquid metal annulus   总被引:1,自引:0,他引:1  
Although the magnetorotational instability (MRI) has been widely accepted as a powerful accretion mechanism in magnetized accretion discs, it has not been realized in the laboratory. The possibility of studying MRI in a rotating liquid metal annulus (Couette flow) is explored by local and global stability analysis. Stability diagrams are drawn in dimensionless parameters, and also in terms of the angular velocities at the inner and outer cylinders. It is shown that MRI can be triggered in a moderately rapidly rotating table-top apparatus, using easy-to-handle metals such as gallium. Practical issues of this proposed experiment are discussed.  相似文献   
429.
Universal kriging is an interpolation method for producing contour maps from irregularly spaced sample points, taking into account the trend (or polynomial drift), which is of known form. It assumes a known covariance model to express correlation of points a short distance apart. A sensitivity analysis examines how the fitted surface will change for given perturbations in the covariance model. We develop a simple approximate analysis in preference to exact analysis and show that it is adequate for small perturbations. For large data sets, a dramatic reduction in computer time is possible using approximate analysis. Possible extensions of this work are noted.  相似文献   
430.
Summary. We present a model of the magnetic field at the core–mantle boundary, for epoch 1959.5, based on a large set of observatory and survey measurements. Formal error estimates for the radial field at the core are 50 μT, compared with 30 and 40 μT for our previous MAGSAT (1980) and POGO (1970) models.
Current work on the determination of the velocity of the core fluid relies on the assumption that the core behaves as a perfect conductor, so that the field lines remain frozen to the fluid at the core surface. This frozen-flux condition requires that the integrated flux over patches of the core surface bounded by contours of zero radial field remain constant in time. A new method is presented for constructing core fields that satisfy these frozen-flux constraints. The constraints are non-linear when applied to main field data, unlike the case of secular variation which was considered in an earlier paper. The method is applied to datasets from epochs 1969.5 and 1959.5 to produce fields with the same flux integrals as the 1980 model.
The frozen-flux hypothesis is tested by comparing the changes in the flux integrals between 1980/1969.5, 1969.5/1959.5 and 1980/1959.5 with their errors. We find that the hypothesis can be rejected with 95 per cent confidence. The main evidence for flux diffusion is in the South Atlantic region, where a new null flux curve appears between 1960 and 1970, and continues to grow at a rapid rate from 1970 to 1980. However, the statistical result depends critically on our error estimates for the field at the core surface, which are difficult to assess with any certainty; indeed, doubling the error estimates negates the statistical argument. The conclusion is therefore, at this stage, tentative, and requires further evidence, either from older data, if good enough, or from future satellite measurements.  相似文献   
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