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Heterogeneous distribution of H2O in the Martian interior: Implications for the abundance of H2O in depleted and enriched mantle sources 下载免费PDF全文
Francis M. McCubbin Jeremy W. Boyce Poorna Srinivasan Alison R. Santos Stephen M. Elardo Justin Filiberto Andrew Steele Charles K. Shearer 《Meteoritics & planetary science》2016,51(11):2036-2060
We conducted a petrologic study of apatite within 12 Martian meteorites, including 11 shergottites and one basaltic regolith breccia. These data were combined with previously published data to gain a better understanding of the abundance and distribution of volatiles in the Martian interior. Apatites in individual Martian meteorites span a wide range of compositions, indicating they did not form by equilibrium crystallization. In fact, the intrasample variation in apatite is best described by either fractional crystallization or crustal contamination with a Cl‐rich crustal component. We determined that most Martian meteorites investigated here have been affected by crustal contamination and hence cannot be used to estimate volatile abundances of the Martian mantle. Using the subset of samples that did not exhibit crustal contamination, we determined that the enriched shergottite source has 36–73 ppm H2O and the depleted source has 14–23 ppm H2O. This result is consistent with other observed geochemical differences between enriched and depleted shergottites and supports the idea that there are at least two geochemically distinct reservoirs in the Martian mantle. We also estimated the H2O, Cl, and F content of the Martian crust using known crust‐mantle distributions for incompatible lithophile elements. We determined that the bulk Martian crust has ~1410 ppm H2O, 450 ppm Cl, and 106 ppm F, and Cl and H2O are preferentially distributed toward the Martian surface. The estimate of crustal H2O results in a global equivalent surface layer (GEL) of ~229 m, which can account for at least some of the surface features on Mars attributed to flowing water and may be sufficient to support the past presence of a shallow sea on Mars' surface. 相似文献
413.
Characterizing aquifer properties and their associated uncertainty remains a fundamental challenge in hydrogeology. Recent studies demonstrate the use of oscillatory flow interference testing to characterize effective aquifer flow properties. These characterization efforts relate the relative amplitude and phase of an observation signal with a single frequency component to aquifer diffusivity and transmissivity. Here, we present a generalized workflow that relates extracted Fourier coefficients for observation signals with single and multiple frequency components to aquifer flow properties and their associated uncertainty. Through synthetic analytical modeling we show that multi-frequency oscillatory flow interference testing adds information that improves inversion performance and decreases parameter uncertainty. We show increased observation signal length, sampling frequency, and pressure sensor accuracy all produce decreased parameter uncertainty. This work represents the first attempt we are aware of to quantify effective aquifer parameters and their associated uncertainty using multi-frequency oscillatory flow interference testing. 相似文献
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The Plain of Jars in north-eastern Laos is home to over 2000 stone jars varying in size from 100 kg to over 30 tonnes. The jars were probably made between 1500 and 2500 years ago; however, who by is not known, as the indigenous people have only lived in the area for 1000 years. Local legend speaks of these jars being used to store Lao-Lao or rice whisky; research indicates that these jars were part of loca funerary rites. There are currently 60 known jar sites, where anywhere between one and 350 individual jars are recorded. The jars are constructed from a variety of lithologies although a few basic rules to selecting suitable rocks have been observed. This study outlines which rock types have been used and how the characteristics of the rock mass controlled the jar makers' selection. 相似文献
418.
China is by far the largest host of projects implemented under the Kyoto Protocol's Clean Development Mechanism (CDM). However, earlier studies shed little light on the determinants of the distribution of CDM projects across Chinese provinces. Given China's large size and political-economic diversity, this dearth of research is troubling. We provide an empirical analysis of 2097 CDM projects in 30 Chinese provinces, 2004–2009. We find that high electricity consumption, low per capita income, and a lack of foreign direct investment are all associated with CDM project implementation. The findings are particularly strong for electricity and foreign direct investment. These findings are consistent with the economic theory of CDM project implementation. Project developers focus on minimizing the cost of carbon abatement. Moreover, they suggest that the CDM can, despite its limitations, contribute to reducing economic inequality and uneven development in China. 相似文献
419.
Alexandra Gross Jeremy Kiszka Olivier Van Canneyt Pierre Richard Vincent Ridoux 《Estuarine, Coastal and Shelf Science》2009,84(3):367
Mayotte in the southwest Indian Ocean is characterized by high dolphin diversity. They may coexist within a fairly small area around the island because they exploit neither the same preferential habitats nor the same resources. This preliminary study aimed to investigate ecological niche segregation among these delphinid communities: the Indo-Pacific bottlenose dolphin, Tursiops aduncus, the pantropical spotted dolphin, Stenella attenuata, the spinner dolphin, Stenella longirostris, and the melon-headed whale, Peponocephala electra. Two approaches were used. Habitat preferences were investigated by analysing dolphin sighting data and associated physiographical characteristics. Resource partitioning was explored by analysing C and N stable isotopes in skin and blubber biopsies. Only T. aduncus, which showed clear association with coastal habitats in the lagoon, differed from the others in terms of habitat preferences, characterised by shallow depth and slope, and proximity to the coast. All other species shared similar oceanic habitats immediately outside the lagoon, these being of higher depth and slope, greater distance from the coast and were not discernable by discriminant analysis. The two Stenella species and the melon-headed whale displayed very high overlap in habitat physiographic variables. The analysis of stable isotopes confirmed the ecological isolation of T. aduncus and revealed a clear segregation of P. electra compared to the two Stenella that was not apparent in the habitat analysis. This may reflect ecological differences that were not observable from diurnal surface observations. 相似文献
420.
Jeremy B. Fein 《Applied Geochemistry》1996,11(6):735-744
Aqueous metals and chlorophenols are common co-contaminants of groundwater systems. However, the importance of aqueous metal-chlorophenolate complexation cannot be accurately assessed because the stability constants for environmentally important aqueous metal-phenolate and metal-chlorophenolate complexes have not been measured. In order to determine the role these complexes play in contaminant transport, this study applies a correlation technique to the limited data that do exist to estimate the stabilities of metal-chlorophenolate complexes of environmental interest. Speciation calculations that are based on these estimated stability constants indicate that aqueous metal-chlorophenolate complexation may significantly affect both aqueous metal and dissolved chlorophenolate species distributions. Therefore, aqueous metal-chlorophenolate complexation may affect the extent of adsorption of both metals and chlorophenolates onto mineral surfaces. In addition, aqueous complexation may significantly enhance dissolution of aquifer aluminosilicate minerals. This study suggests that aqueous complexation between metals and chlorophenolates can significantly affect the mobility of metal and phenolic contaminants. 相似文献