Trace metal enrichments in Lake Tanganyika sediments: Controls on trace metal burial in lacustrine systems

We investigate the distributions of several key diagenetic reactants (C, S, Fe) and redox-sensitive trace metals (Mo, Cd, Re, U) in sediments from Lake Tanganyika, East Africa. This study includes modern sediments from a chemocline transect, which spans oxygenated shallow waters to sulfidic conditions at depth, as well as ancient sediments from a longer core (∼2 m) taken at ∼900 m water depth. Modern sediments from depths spanning ∼70-335 m are generally characterized by increasing enrichments of C, S, Mo, Cd, and U with increasing water depth but static Fe distributions. It appears that the sedimentary enrichments of these elements are, to varying degrees, influenced by a combination of organic carbon cycling and sulfur cycling. These modern lake characteristics contrast with a period of high total organic carbon (C_org), total sulfur (S_Tot), and trace metal concentrations observed in the 900 m core, a period which follows the most recent deglaciation (∼18-11 ky). This interval is followed abruptly by an interval (∼11-6 ky) that is characterized by lower C, S, U, and Mo. Consistent with other work we suspect that the low concentrations of S, Mo, and U may indicate a period of intense lake mixing, during which time the lake may have been less productive and less reducing as compared to the present. An alternative, but not mutually exclusive, hypothesis is that changes in the lake’s chemical inventory, driven by significant hydrological changes, could be influencing the distribution of sedimentary trace elements through time.     

Laser depth profiling studies of helium diffusion in Durango fluorapatite

Ultraviolet lasers coupled with sensitive mass spectrometers provide a useful way to measure laboratory-induced noble gas diffusion profiles in minerals, thus enabling the calculation of diffusion parameters. We illustrate this laser ablation depth profiling (LADP) technique for a previously well-studied mineral-isotopic system: ⁴He in Durango fluorapatite. LADP studies were conducted on oriented, polished slabs from a single crystal that were heated under vacuum to a variety of temperatures between 300 and 450 °C for variable times. The resolved ⁴He profiles exhibited error-function loss as predicted by previous bulk ⁴He diffusion studies. All of the slabs, regardless of crystallographic orientation, yielded modeled diffusivities that are statistically co-linear on an Arrhenius diagram, suggesting no diffusional anisotropy of ⁴He in this material. The data indicate an activation energy of 142.2 ± 5.0 (2σ) kJ/mol and diffusivity at infinite temperature - reported as ln(D₀) - of −4.71 ± 0.94 (2σ) m²/s. These values imply a bulk closure temperature for ⁴He in Durango fluorapatite of 74 °C for a 50 μm radius grain, infinite cylinder geometry, and a cooling rate of 10 °C/Myr.     

Pressure effects on the joint elastic‐electrical properties of reservoir sandstones

We conducted a laboratory study of the joint elastic‐electrical properties of sixty‐three brine‐saturated sandstone samples to assess the likely impact of differential pressure (confining minus pore fluid pressures) in the range 8–60 MPa on the joint interpretation of marine seismic and controlled‐source electromagnetic survey data. The samples showed a wide range of petrophysical properties representative of most sandstone reservoirs. We found that a regression equation comprising both a constant and an exponential part gave a good fit to the pressure dependence of all five measured geophysical parameters (ultrasonic P‐ and S‐wave velocity, attenuation and electrical resistivity). Electrical resistivity was more pressure‐sensitive in clay‐rich sandstones with higher concentrations of low aspect ratio pores and micropores than in clean sandstones. Attenuation was more pressure‐sensitive in clean sandstones with large open pores (macropores) than in clay‐rich sandstones. Pore shape did not show any influence on the pressure sensitivity of elastic velocity. As differential pressure increases, the effect of the low aspect ratio pores and micropores on electrical resistivity becomes stronger than the effect of the macropores on attenuation. Further analysis of correlations among the five parameters as a function of pressure revealed potentially diagnostic relationships for geopressure prediction in reservoir sandstones.     

Joint elastic‐electrical properties of reservoir sandstones and their relationships with petrophysical parameters

We measured in the laboratory ultrasonic compressional and shear‐wave velocity and attenuation (0.7–1.0 MHz) and low‐frequency (2 Hz) electrical resistivity on 63 sandstone samples with a wide range of petrophysical properties to study the influence of reservoir porosity, permeability and clay content on the joint elastic‐electrical properties of reservoir sandstones. P‐ and S‐wave velocities were found to be linearly correlated with apparent electrical formation factor on a semi‐logarithmic scale for both clean and clay‐rich sandstones; P‐ and S‐wave attenuations showed a bell‐shaped correlation (partial for S‐waves) with apparent electrical formation factor. The joint elastic‐electrical properties provide a way to discriminate between sandstones with similar porosities but with different clay contents. The laboratory results can be used to estimate sandstone reservoir permeability from seismic velocity and apparent formation factor obtained from co‐located seismic and controlled source electromagnetic surveys.     

Temperature Inverted Haloclines Provide Winter Warm-Water Refugia for Manatees in Southwest Florida

Florida manatees (Trichechus manatus latirostris) overwintering in the Ten Thousand Islands and western Everglades have no access to power plants or major artesian springs that provide warm-water refugia in other parts of Florida. Instead, hundreds of manatees aggregate at artificial canals, basins, and natural deep water sites that act as passive thermal refugia (PTR). Monitoring at two canal sites revealed temperature inverted haloclines, which provided warm salty bottom layers that generally remained above temperatures considered adverse for manatees. At the largest PTR, the warmer bottom layer disappeared unless significant salt stratification was maintained by upstream freshwater inflow over a persistent tidal wedge. A detailed three-dimensional hydrology model showed that salinity stratification inhibited vertical convection induced by atmospheric cooling. Management or creation of temperature inverted haloclines may be a feasible and desirable option for resource managers to provide passive thermal refugia for manatees and other temperature sensitive aquatic species.     

Towards climate adaptation and coastal governance in Ireland: Integrated architecture for effective management?

Coastal environments are susceptible to a range of impacts arising from medium and long-term climate change. However, as Ireland's population and industrial centres are concentrated in coastal locations, Ireland's coastal communities will be particularly vulnerable to the impacts of climate change. Therefore, making the best use of existing knowledge to inform the establishment of governance structures capable of facilitating the measures and actions which may soon be required is a national imperative. Coastal communities worldwide have turned to integrated coastal zone management (ICZM) as a process to deliver sustainable development. This paper explores how experience gained from ICZM implementation can be harnessed to inform the development and implementation of climate adaptation policies, with a particular focus on the coastal zone. Using the principles and conceptual basis of Earth System Governance – an emerging approach to analyse complexity of governance under global environmental change – the paper maps the architecture of ICZM and climate governance in Ireland. The research identifies the main barriers to, and opportunities for, integrated application of the two policy domains. Barriers include the fragmentation of governance structures and responsibilities of key stakeholders, a lack of coordinated support for ICZM implementation at the national level, and a relatively weak awareness of the specifics of adaptation at the local level. Opportunities include the availability of expertise gathered from phases of ICZM implementation in Ireland, which encompasses mechanisms for science-policy integration, and invaluable experience of stakeholder participation and interaction. Current political and scientific support at national and EU levels give an additional impetus to climate research and actions which may bring additional opportunities and resources to coastal governance in Ireland.     

The birthrate of magnetars

Magnetars, neutron stars with ultrastrong magnetic fields  ( B ∼ 10¹⁴−10¹⁵G)  , manifest their exotic nature in the form of soft gamma-ray repeaters and anomalous X-ray pulsars. This study estimates the birthrate of magnetars to be ∼0.22 per century with a Galactic population comprising ∼17 objects. A population synthesis was carried out based on the five anomalous X-ray pulsars detected in the ROSAT All Sky Survey by comparing their number to that of massive OB stars in a well-defined volume. Additionally, the group of seven X-ray dim isolated neutron stars detected in the same survey were found to have a birthrate of ∼2 per century with a Galactic population of ∼22 000 objects.