The extremely reduced silicate‐bearing iron meteorite Northwest Africa 6583: Implications on the variety of the impact melt rocks of the IAB‐complex parent body

Northwest Africa (NWA) 6583 is a silicate‐bearing iron meteorite with Ni = 18 wt%. The oxygen isotope composition of the silicates (?′¹⁷O = ?0.439 ‰) indicates a genetic link with the IAB‐complex. Other chemical, mineralogical, and textural features of NWA 6583 are consistent with classification as a new member of the IAB‐complex. However, some unique features, e.g., the low Au content (1.13 μg g^?1) and the extremely reducing conditions of formation (approximately ?3.5 ?IW), distinguish NWA 6583 from the known IAB‐complex irons and extend the properties of this group of meteorites. The chemical and textural features of NWA 6583 can be ascribed to a genesis by impact melting on a parent body of chondritic composition. This model is also consistent with one of the most recent models for the genesis of the IAB‐complex. Northwest Africa 6583 provides a further example of the wide lithological and mineralogical variety that impact melting could produce on the surface of a single asteroid, especially if characterized by an important compositional heterogeneity in space and time like a regolith.     

A new magnetostratigraphic framework for the Lower Miocene (Burdigalian/Ottnangian, Karpatian) in the North Alpine Foreland Basin

Oligocene–Miocene chronostratigraphic correlations within the Paratethys domain are still highly controversial. This study focuses on the late Early Miocene of the Swiss and S-German Molasse Basin (Late Burdigalian, Ottnangian–Karpatian). Previous studies have published different chronologies for this time interval that is represented by the biostratigraphically well constrained Upper Marine Molasse (OMM, lower and middle Ottnangian), Upper Brackish Molasse (OBM, Grimmelfingen and Kirchberg Formations, middle and upper Ottnangian to lower Karpatian, MN 4a–MN 4b) and Upper Freshwater Molasse (OSM, Karpatian–Badenian, MN 5). Here, we suggest a new chronostratigraphic framework, based on integrated magneto-litho-biostratigraphic studies on four sections and three boreholes. Our data indicate that the OBM comprises chrons 5D.1r and 5Dn (Grimmelfingen Fm), chron 5Cr (lower Kirchberg Fm) and the oldest part of chron 5Cn.3n (upper Kirchberg Fm). The OSM begins during chron 5Cn.3n, continues through 5Cn, and includes a long reversed segment that can be correlated to chron 5Br. The OMM-OSM transition was completed at 16.0 Ma in the Swiss Molasse Basin, while the OBM-OSM changeover ended at 16.6 Ma in the S-German Molasse Basin. As the lower Kirchberg Fm represents a facies of the Ottnangian, our data suggest that the Ottnangian–Karpatian boundary in the Molasse Basin is approximately at 16.8 Ma, close to the 5Cr–5Cn.3n magnetic reversal, and thus 0.4 Myr younger than the inferred age of 17.2 Ma used in recent Paratethys time scales. Notably, this would not be problematic for the Paratethys stratigraphy, because chron 5Cr is mainly represented by a sedimentation gap in the Central Paratethys. We also realise, however, that additional data is still required to definitely solve the age debate concerning this intriguing time interval in the North Alpine Foreland Basin. We dedicate this work to our dear friend and colleague Jean-Pierre Berger (8 July 1956–18 January 2012).     

Incrementally non‐linear plasticity applied to rock joint modelling

Rock joint constitutive modelling is discussed through two new rock joint constitutive relations and a discrete numerical model. Regarding the constitutive relations, we emphasise the number of ‘tensorial zones’, that is, domains of constitutive incremental linearity; they involve four zones for the first (called ‘quadrilinear’) and an infinite number for the second one (called ‘incrementally nonlinear’). Using these formulations, a large class of loading paths can be considered. Hardening through shearing and relations between the normal and tangential directions of the joint (e.g., dilatancy) can be described. Their predictive abilities are checked. Plastic features are included even if the relations are defined outside the elasto‐plastic formalism. These relations obey, hence, the physical evidence as the plastic limit criterion and flow rule. The flow rule is nonassociated, and the corresponding link with the nonsymmetry of the constitutive matrix is examined. Comparisons between the two relations and the discrete numerical model, that is, a direct numerical simulation, which is fundamentally different, also are discussed within the context of infilled rock joints. Copyright © 2011 John Wiley & Sons, Ltd.     

A 70 ka record of explosive eruptions from the TALDICE ice core (Talos Dome,East Antarctic plateau)

The new Antarctic TALDICE ice core (72° 49′ S, 159° 11′ E, 1620 m depth), containing abundant primary tephras, provides the opportunity to elucidate the late Quaternary volcanic history of the south polar region, as well as to broaden the East Antarctic tephrostratigraphic framework. Here grain size and glass compositional data for representative tephra layers from the last 70 ka core section are used for source identification. Results point to origin of layers from centres of the Melbourne Volcanic Province (McMurdo Volcanic Group), located ～250 km from the coring site. Occurrence of tephra layers within the ice core record suggests that explosive activity in the identified source was not constant over the considered period, with a minimum of activity between 20 and 35 ka, and increased activity back to 65 ka. In addition to palaeovolcanic implications, the TALDICE tephra layers offer prospects for firm correlations between diverse widely separated palaeoarchives and for accurate dating of the Antarctic climatic record. Copyright © 2010 John Wiley & Sons, Ltd.     

River network travel time is correlated with dissolved organic matter composition in rivers of the contiguous United States

Most terrestrial allochthonous organic matter enters river networks through headwater streams during high flow events. In headwaters, allochthonous inputs are substantial and variable, but become less important in streams and rivers with larger watersheds. As allochthonous dissolved organic matter (DOM) moves downstream, the proportion of less aromatic organic matter with autochthonous characteristics increases. How environmental factors converge to control this transformation of DOM at a continental scale is less certain. We hypothesized that the amount of time water has spent travelling through surface waters of inland systems (streams, rivers, lakes, and reservoirs) is correlated to DOM composition. To test this hypothesis, we used established river network scaling relationships to predict relative river network flow-weighted travel time (FWTT) of water for 60 stream and river sites across the contiguous United States (3090 discrete samples over 10 water years). We estimated lentic contribution to travel times with upstream in-network lake and reservoir volume. DOM composition was quantified using ultraviolet and visible absorption and fluorescence spectroscopy. A combination of FWTT and lake and reservoir volume was the best overall predictor of DOM composition among models that also incorporated discharge, specific discharge, watershed area, and upstream channel length. DOM spectral slope ratio (R² = 0.77) and Freshness Index (R² = 0.78) increased and specific ultraviolet absorbance at 254 nm (R² = 0.68) and Humification Index (R² = 0.44) decreased across sites as a function of FWTT and upstream lake volume. This indicates autochthonous-like DOM becomes continually more dominant in waters with greater FWTT. We assert that river FWTT can be used as a metric of the continuum of DOM composition from headwaters to rivers. The nature of the changes to DOM composition detected suggest this continuum is driven by a combination of photo-oxidation, biological processes, hydrologically varying terrestrial subsidies, and aged groundwater inputs.     

Cluster Observations of the Magnetospheric Low-Latitude Boundary Layer and Cusp during Extreme Solar Wind and Interplanetary Magnetic Field Conditions: I. 10 November 2004 ICME

We present a study of the magnetospheric cusp response to extreme external parameters during passage of the ICME over the Earth on 10 November 2004, based on Cluster observations of the plasma properties inside the low-latitude boundary layer (LLBL)/cusp regions. Two separate events are observed while Cluster is in the dawn sector, 07 – 08 h magnetic local time (MLT). First, a LLBL/cusp crossing occurs during a period of strong southward IMF. During this time, the LLBL/cusp is very small, ∼0.8 – 1° invariant latitude (ILAT) and moves equatorward, down to 67° ILAT. This can be explained by the occurrence of significant magnetopause erosion due to enhanced dayside sub-solar reconnection. The energy of the plasma inside this region is higher than normal, and the low-energy cut-off often observed in the ion data is also unusually high. This might be explained by the suggestion that the local magnetosheath Alfvén velocity and deHoffmann – Teller velocity are also both extremely high. However, the plasma convection and parallel velocity inside this region are not very high. The second event discussed in this paper is a LLBL/cusp crossing during strong equatorial IMF (mostly due to the dominant dawn – dusk component). Under these conditions, occurring at the same time as pulses of solar wind dynamic pressure, the observations are very complicated. However, we suggest that in the polar region of the southern hemisphere, Cluster cross two LLBLs/cusps, spatially separated by polar cap plasma. The first LLBL/cusp is formed by anti-parallel reconnection in the dusk sector of the southern hemisphere and the second is formed by anti-parallel reconnection in the dawn sector of the northern hemisphere. The second LLBL/cusp is located at extremely low latitude, less than ∼66.3° ILAT. During all LLBL/cusp crossings, strong ionospheric O⁺ ion outflow is detected in the form of a narrow beam with limited pitch-angle range.     

Evidence for millennial-scale climatic events in the sedimentary infilling of a macrotidal estuarine system,the Seine estuary (NW France)

High-resolution sedimentological and rock magnetic analyses from sediment cores collected in the Seine estuary record changes in coastal sedimentary dynamics linked to climatic variations during the late Holocene. Using AMS ¹⁴C and paleomagnetic data we present a first attempt in developing a reliable age model on macrotidal estuarine archives, with a decadal resolution. Correlations between sedimentary successions from the outer Seine estuary document the main sedimentary infilling phases of the system during the last 3000 years. Between 3000 and 1150 cal. BP sedimentary patterns reveal that sequence deposition and preservation are predominantly controlled by marine and tidal hydrodynamics while severe storm events are recorded at ca. 2700 and 1250 cal. BP in the outermost estuary. Conversely, the Medieval Warm Period (MWP; 900–1200 AD) is characterized by a drastic waning of the influence of marine hydrodynamics on sediment preservation. Pronounced episodes of Seine river floods indicate a much stronger impact of continental inputs on sedimentary patterns during this period. The onset of the Little Ice Age marks a diminishing influence of continental inputs while tidal and open marine hydrodynamics again exerted a primary control on the sedimentary evolution of the system during 1200–2003 AD. Coastal sedimentary dynamics as preserved within sedimentary successions appear to have been largely influenced by changes in storminess during the last 3000 years. We have matched the preservation of MWP Seine river floods, as revealed by sedimentological and rock magnetic proxy data, to a prolonged interval of weakened storminess in Normandy permitting the preservation of estuarine flood deposits within a context of reduced coastal erosion in northern Europe. The preservation of sedimentary successions in the Seine estuary is therefore maximal when climate conditions resembled those of the preferred low phase of the NAO on multidecadal timescales such as during 800–1200 AD (MWP). In contrast, increased removal and transport of estuarine sediments occur when winter storm activity greatly intensified over northwestern France. We report four prominent centennial-scale periods of stronger storminess, occurring with a pacing of ～1500 years, which are likely to be related to the last four Bond's Holocene cold events. Our results documenting a close link between coastal sedimentary dynamics, millennial-scale variations in Holocene climate and North Atlantic atmospheric circulation are fairly consistent with other records from Scandinavia, central Greenland and southern Europe.     

Optical positions of radiostars: The necessity of international cooperation

Positions of 175 radiostars have been obtained with the Bordeaux automatic meridian circle. Comparisons with VLBI and VLA results are given on the FK4 system. An international observation program of a unified list of radiostars is needed in order to obtain the best link of the FK5 with the extragalactic reference frame. The Astronomisches Rechen-Institut is proposed as compilation center.On leave from the Instituto Atronomico e Geofisico, Caixa Postal 30627, 0105 1 Sao Paulo, SP