Boron isotope ratios of surface waters in Guadeloupe,Lesser Antilles

Large variations are reported in the B concentrations and isotopic ratios of river and thermal spring waters in Guadeloupe, Lesser Antilles. Rivers have δ¹¹B values around 40‰ and B concentrations lower than 30 μg/L, while thermal springs have δ¹¹B of 8–15‰ and B concentrations of 250–1000 μg/L. River samples strongly impacted by hydrothermal inputs have intermediate δ¹¹B and B contents. None of these surface water samples have δ¹¹B comparable to the local unweathered volcanic rocks (around 0‰), implying that a huge isotopic fractionation of 40‰ takes place during rock weathering, which could be explained by preferential incorporation of ¹⁰B during secondary mineral formation and adsorption on clays, during rock weathering or in the soils. The soil-vegetation B cycle could also be a cause for such a fractionation. Atmospheric B with δ¹¹B of 45‰ represents 25–95% of the river B content. The variety of the thermal spring chemical composition renders the understanding of B behavior in Guadeloupe hydrothermal system quite difficult. Complementary geochemical tracers would be helpful.     

Dual-frequency ADCPs measuring turbidity

A pair of self-contained acoustic Doppler current profilers (SC-ADCPs) operating with different frequencies were moored on a muddy sea bottom at about 20 m depth in the Bay of Vilaine off the French Atlantic coast. With their acoustic beams oriented upwards, the SC-ADCPs ensonified most of the water column. The results of several months of in situ recorded echo intensity data spanning 2 years (2003 to 2004) from the dual-frequency ADCPs are presented in this paper. The aim was to estimate suspended particle mass concentration and mean size. A concentration index CI is proposed for the estimation of particle concentration. Based on theory the CI—unlike the volume backscatter strength—does not depend on particle size. Compared with in situ optical data, the CI shows reasonable precision but not increased with respect to that of the highest-frequency backscatter strength. Concerning the mean particle size, despite a lack of quantitative validation with optical particle-size measurements, the method yielded a qualitative discrimination of mineral (small) and organic (large) particles. This supports the potential of dual-frequency ADCPs to quantitatively determine particle size. A cross-calibration of the transducers of each ADCP shows that a specific component of the precision of the backscatter strength measured by ADCP depends on the acoustic frequency, the cell thickness and the ensemble integration time. Based on these results, the use of two ADCPs operating with distinctly different frequencies (two octaves apart) or a single dual-frequency ADCP is recommended.     

Spatio-temporal analysis of territorial changes from a multi-scale perspective

The full integration of time dimensions in GIS still represents a research challenge. A number of systems provide ways to visualise harmonised timestamped geographical data onto maps, with interpolated curves representing how these data have changed over time. However, these systems frequently mask the concerns linked to changes in territorial organisations and the harmonisation of data. In fact, the development of a territory should be considered in connection with its neighbourhood, governance and genealogy relationships. This article focuses on the difficulties linked with the ‘change of support problem’, which can arise when conducting spatio-temporal analysis of data. First, we present a data model handling the changing relationships between territories. Then, we illustrate how this model can be instantiated using examples that have taken place in Europe. We show how the model can address questions such as that of change blindness. Finally, we explain how hierarchical and genealogical relationships can be used inside an interactive cartographic tool for spatio-temporal analysis. It provides various views of the same phenomena at multiple scales, through an approach that takes into account the changes in territorial organisation.     

Numerical modelling of morphodynamics—Vilaine Estuary

The main objective of this paper is to develop a method to simulate long-term morphodynamics of estuaries dominated by fine sediments, which are subject to both tidal flow and meteorologically induced variations in freshwater run-off and wave conditions. The method is tested on the Vilaine Estuary located in South Brittany, France. The estuary is subject to a meso–macrotidal regime. The semi-diurnal tidal range varies from around 2.5 to 5 m at neap and spring, respectively. The freshwater input is controlled by a dam located approximately 8 km from the mouth of the estuary. Sediments are characterised as mostly fines, but more sandy areas are also found. The morphology of the estuary is highly influenced by the dam. It is very dynamic and changes in a complicated manner with the run-off from the dam, the tide and the wave forcing at the mouth of the estuary. Extensive hydrodynamic and sediment field data have been collected in the past and provide a solid scientific basis for studying the estuary. Based on a conceptual understanding of the morphodynamics, a numerical morphological model with coupled hydrodynamic, surface wave and sediment transport models is formulated. The numerical models are calibrated to reproduce sediment concentrations, tidal flat altimetry and overall sediment fluxes. Scaling factors are applied to a reference year to form quasi-realistic hydrodynamic forcing and river run-off, which allow for the simulations to be extended to other years. The simulation results are compared with observed bathymetric changes in the estuary during the period 1998–2005. The models and scaling factors are applied to predict the morphological development over a time scale of up to 10 years. The influence of the initial conditions and the sequence of external hydrodynamic forcing, with respect to the morphodynamic response of the estuary, are discussed.     

Magnetic classification of stony meteorites: 2. Non‐ordinary chondrites

Abstract— A database of magnetic susceptibility (χ) measurements on different non‐ordinary chondrites (C, E, R, and ungrouped) populations is presented and compared to our previous similar work on ordinary chondrites. It provides an exhaustive study of the amount of iron‐nickel magnetic phases (essentially metal and magnetite) in these meteorites. In contrast with all the other classes, CM and CV show a wide range of magnetic mineral content, with a two orders of magnitude variation of χ. Whether this is due to primary parent body differences, metamorphism or alteration, remains unclear. C3–4 and C2 yield similar χ values to the ones shown by CK and CM, respectively. By order of increasing χ, the classes with well‐grouped χ are: R << CO < CK ≈ CI < Kak < CR < E ≈ CH < CB. Based on magnetism, EH and EL classes have indistinguishable metal content. Outliers that we suggest may need to have their classifications reconsidered are Acfer 202 (CO), Elephant Moraine (EET) 96026 (C4–5), Meteorite Hills (MET) 01149, and Northwest Africa (NWA) 521 (CK), Asuka (A)‐88198, LaPaz Icefield (LAP) 031156, and Sahara 98248 (R). χ values can also be used to define affinities of ungrouped chondrites, and propose pairing, particularly in the case of CM and CV meteorites.     

Rainfall chemistry: long range transport versus below cloud scavenging. A two-year study at an inland station (Opme, France)

The present study investigates the chemical composition of wet atmospheric precipitation samples on a daily and an intra-event timescales in Opme, an experimental meteorological station located near Clermont-Ferrand, France. The samples have been collected from November 2005 to October 2007. A total of 217 rainwater samples, integrated for 24 h, were collected and analyzed for pH, conductivity, Na⁺, K⁺, Mg²⁺, NH₄⁺, Ca²⁺, Cl⁻, NO₃⁻ , SO₄²⁻ , PO₄³⁻ and HCO₃⁻. The composition of the rainwater collected appeared to be controlled by the following potential sources: neutralisation process (association among calcium, ammonium with nitrate and sulphate), marine and terrestrial sources. In order to determine the role of long-range transport, the integrated events were classified according to four origins of air-masses: (1) West, (2) North and East, (3) South including Iberian and Italian Peninsulae and (4) local. This analysis allows identifying the source areas of the different association of elements defined. Although calcium is always dominant, total content of rainfall is variable and neutralisation process can be more or less efficient and specific. Rainout (long-range transport) and washout (below-cloud scavenging) were investigated through intra-event measurements of chemical species. Four rain-events have been selected according to the four classes of origins of air-masses. It appears that the first fractions are responsible for an important part of the chemical content of the whole event. Terrestrial species, locally emitted, induce the neutralisation process of acid species. Local meteorological conditions, such as wind’s speed and direction, play an important role as they could provoke recharges of the below cloud air column during the event.     

Variations of the age of tides in the global oceans

Abstract

Earlier studies on the age of tide dealt mostly with the age of the semi‐diurnal tide in the Atlantic and Pacific Oceans. In these studies, the variations of the age of tide were determined making use of recorded tidal data up to and including the 1960s. In the present study, all available tidal data till the mid 1980s are utilized and the computations were done for the four global oceans: Atlantic, Pacific, Indian, and Arctic. Also, in addition to the age of the semi‐diurnal tide, the age of the parallax and the age of the diurnal tide were determined. The distribution patterns for the positive and negative ages for the semi‐diurnal tide, parallax, and diurnal tide were related whenever possible with the tidal amphidromic point locations and the amplitude ratios S₂/M₂, N₂/M₂, and O₁/K₁.     

Probability maps of landslide reactivation derived from tree-ring records: Pra Bellon landslide, southern French Alps

Probability maps of landslide reactivation are presented for the Pra Bellon landslide located in the southern French Alps based on results obtained with dendrogeomorphic analysis. Spatiotemporal patterns of past landslide activity was derived from tree-ring series of 403 disturbed mountain pine trees growing in the landslide body. In total, 704 growth disturbances were identified in the samples indicating 22 reactivation phases of the landslide body between 1910 and 2011. The mean return period was 4.5 years. Given the spatiotemporal completeness of the reconstruction, probabilities of landslide reactivation were computed and illustrated using a Poisson distribution model and for 5, 20, 50, and 100 years. Probability of landslide reactivation is highest in the central part of the landslide body and increases from 0.13 for a 5-year period to 0.94 for a 100-year period. Conversely, probabilities of reactivation are lower at its margins. The proposed method differs from conventional approaches based on statistical analyses or physical modeling that have demonstrated to have limitations in the prediction of spatiotemporal reactivation of landslides. Our approach is, in contrast, based on extensive data on past landslides and therefore allowed determination of quantitative probability maps of reactivation derived directly from the frequency of past events. This approach is considered a valuable tool for land managers in charge of protecting and forecasting people and their assets from the negative effects of landslides as well as for those responsible for land use planning and management. It demonstrates the reliability of dendrogeomorphic mapping that should be used systematically in forested shallow landslides.     

Friction effect on stresses in ensiled granular media

We develop, in this paper, an analytical approach of continuous medium type which improves the theory of Janssen and other existing approaches of the same type. This approach allows to calculate the stresses in any point of the ensiled granular medium and to represent as well qualitatively as quantitatively the stress saturation effect. The influence of the friction angles is studied.