Proximity to ice fields and lake depth as modulators of paleoclimate records: a regional study from southwest Yukon,Canada

Pronounced climate warming during the past century has been well documented in high-latitude regions. Nonetheless, considerable heterogeneity exists in northern climate trends. We examined the roles of cryospheric landscape and lake depth in modulating the rate and magnitude of local climate responses through a paleolimnological study of lakes from southwest Yukon, Canada. By sampling lakes at varying distances from the Wrangell-St. Elias ice fields, we hypothesized that, for lakes of similar maximum depth, sites closest to the ice fields would be relatively complacent in terms of their chironomid and diatom assemblage changes over the past ~200 years. This hypothesis is based on the moderating effect of the glaciers on local climate, which would be most pronounced in the lakes nearest to the ice fields. However, given the known ecological differences between deep and shallow lakes, we further predicted that, for a given distance from the ice fields, a sediment record from a shallower lake would show the greatest change in stratigraphic subfossil assemblages. Because of the complicated shape of the ice fields, we applied the longitude for each site (which decreases from west to east) to approximate the proximity of our study lakes to the ice fields. Consistent with our predictions, we observed a space-transgressive pattern in the chironomid assemblage turnover that was associated with their proximity to the ice fields (r = ?0.75, P = 0.034, n = 8) across lakes of similar depth (mean maximum depth ± 1, SE = 18.1 ± 2.6 m). Considering a broader network of lakes that represented a greater range in maximum depth (4.9–29 m), we found that differences in subfossil chironomid assemblages between the modern and ca. AD 1800 sediment layers were strongly related to lake depth (r = ?0.77, P < 0.001, n = 15), but failed to detect a significant relationship with latitude or longitude (i.e. our proxy for proximity to the ice fields). Similarly, our comparative high-resolution analyses of two lakes with distinct lake morphometries, but similar proximities to the ice fields, demonstrated the predicted contrasting pattern: we observed pronounced post-1880 changes in the biotic assemblages in the shallow lake and a muted and delayed response (i.e. ~1970s) in the deeper lake. Our findings confirm that cryospheric landscape features can strongly modulate regional climate. Furthermore, our work shows that investigators need to be conscious of how climate change affects the structure and functioning of lakes of different typologies, which influences the way in which paleoclimate signals are recorded and interpreted.     

Time series analysis of CO concentrations from an Eastern Kentucky coal fire

Coal fires in natural outcrops, in abandoned and active coal mines, and in coal and coal-refuse piles are responsible for the uncontrolled emissions of gases, including CO, CO₂, H₂S, hydrocarbons, and volatile aromatics. Typically, measurements of gases at a mine vent are made over a short time interval, perhaps no more than 10 min, including the time for replicate measurements. Such timing provides little information on longer-term variations in emissions, although comparisons of seasonal measurements suggest such changes do occur. To address this problem, we placed temperature and CO data loggers in coal fire vents to collect time series measurements for a period of up to three weeks. For one experiment, 11 days of data at one-minute intervals indicated that the CO emissions were generally in the 400–550 ppmv range. However near daily depressions in CO concentrations occurred and in some cases fell below 50 ppmv; followed by an increase to ~ 700–800 ppmv; in turn followed by a return to the ambient conditions. Data for a separate 21-day collection period in a different vent of the same fire exhibited similar trends, albeit at a higher CO concentration. The drop in CO concentration may be associated with a meteorologically-driven inhalation cycle of the fire, whereby air diluted the combustion generated CO. We propose this was followed by an increase in the intensity of the fire due to increased O₂ from the inhaled air, producing increased CO concentrations, before settling back to the ambient conditions.     

The role of hydrothermal fluids in sedimentation in saline alkaline lakes: Evidence from Nasikie Engida,Kenya Rift Valley

Saline alkaline lakes that precipitate sodium carbonate evaporites are most common in volcanic terrains in semi‐arid environments. Processes that lead to trona precipitation are poorly understood compared to those in sulphate‐dominated and chloride‐dominated lake brines. Nasikie Engida (Little Magadi) in the southern Kenya Rift shows the initial stages of soda evaporite formation. This small shallow (<2 m deep; 7 km long) lake is recharged by alkaline hot springs and seasonal runoff but unlike neighbouring Lake Magadi is perennial. This study aims to understand modern sedimentary and geochemical processes in Nasikie Engida and to assess the importance of geothermal fluids in evaporite formation. Perennial hot‐spring inflow waters along the northern shoreline evaporate and become saturated with respect to nahcolite and trona, which precipitate in the southern part of the lake, up to 6 km from the hot springs. Nahcolite (NaHCO₃) forms bladed crystals that nucleate on the lake floor. Trona (Na₂CO₃·NaHCO₃·2H₂O) precipitates from more concentrated brines as rafts and as bottom‐nucleated shrubs of acicular crystals that coalesce laterally to form bedded trona. Many processes modify the fluid composition as it evolves. Silica is removed as gels and by early diagenetic reactions and diatoms. Sulphate is depleted by bacterial reduction. Potassium and chloride, of moderate concentration, remain conservative in the brine. Clastic sedimentation is relatively minor because of the predominant hydrothermal inflow. Nahcolite precipitates when and where pCO₂ is high, notably near sublacustrine spring discharge. Results from Nasikie Engida show that hot spring discharge has maintained the lake for at least 2 kyr, and that the evaporite formation is strongly influenced by local discharge of carbon dioxide. Brine evolution and evaporite deposition at Nasikie Engida help to explain conditions under which ancient sodium carbonate evaporites formed, including those in other East African rift basins, the Eocene Green River Formation (western USA), and elsewhere.     

Mineralogy of suspended sediment in three karst springs

Springs in karstic carbonate rocks frequently carry a sediment load as well as a dissolved load. Analysis of morphology and mineralogy of suspended sediment from three contrasting karst springs reveals a suite of clastic particles that reflect both source areas and processes that take place within the aquifer. Nolte Spring in Lancaster County, Pennsylvania, USA, discharges sediment of apparently precipitated calcite, indicating that at some point in the aquifer or vadose zone, water exceeds saturation with respect to calcite. Sediment morphologies and chemical conditions in the aquifer point to two different scenarios for this precipitation. The other two springs, Arch Spring in Blair County, Pennsylvania and Bushkill Spring in Northampton County, Pennsylvania, show no evidence of calcite precipitation. Arch Spring discharges mainly layer silicates, while Bushkill Spring discharges mainly silica.

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Resumen Los manantiales en rocas carbonatadas karstficadas tienen frecuentemente una carga de sedimentos y de sólidos disueltos. Los análisis de la morfología y mineralogía de los sedimentos suspendidos de tres manantiales kársticos contrastados revela un conjunto de partículas clásticas que reflejan ambas áreas fuente y los procesos que tienen lugar dentro del acuífero. Nolte Spring en el Condado de Lancaster, Pennsylvania, USA, descarga sedimento de calcita aparentemente precipitada indicando que en cierto punto del acuífero o en la zona vadosa, el agua supera la saturación con respecto a la calcita. La morfología de los sedimentos y las condiciones químicas en el acuífero apuntan a dos escenarios diferentes para esta precipitación. Los otras dos manantiales, Arch Spring en el Condado de Blair, Pennsylvania y Bushkill Spring en el Condado de Norhtampton, Pennsylvania, no muestran evidencia de precitación de calcita. Arch Spring descarga principalmente filosilicatos mientras que Bushkill Spring descarga fundamentalmente Sílice.

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Résumé Les sources situées en contexte carbonaté karstique charrient fréquemment, outre les matières dissoutes, une charge solide. La morphologie et la minéralogie des sédiments en suspension issus de trois sources karstiques de caractéristiques distinctes ont été analysées : une série de particules clastiques, reflétant à la fois les secteurs des sources et les processus internes de l’aquifère, en ressort. Les sédiments issus de Nolte Spring (Comté de Lancaster, Pennsylvanie, Etats-Unis) sont constitués de calcite apparemment précipitée: ceci indique que l’eau atteint la sursaturation vis-à-vis de la calcite à un certain point de l’aquifère ou de la zone non-saturée. La morphologie des sédiments et les conditions chimiques au sein de l’aquifère mènent à deux scénarii différents pour expliquer cette précipitation. Les deux autres sources, Arch Spring (Comté de Blair, Pennsylvanie) et Bushkill Spring (Comté de Northampton, Pennsylvanie), ne présentent aucun indice de précipitation de calcite. Arch Spring exporte essentiellement des phyllosilicates, alors que la silice est majoritaire à Bushkill Spring.

     

Chemical Dynamics and Evaluation of Biogeochemical Processes in Alpine River Kamniška Bistrica, North Slovenia

Biogeochemical processes were investigated in alpine river—Kamni?ka Bistrica River (North Slovenia), which represents an ideal natural laboratory for studying anthropogenic impacts in catchments with high weathering capacity. The Kamni?ka Bistrica River water chemistry is dominated by HCO₃ ^?, Ca²⁺ and Mg²⁺, and Ca²⁺/Mg²⁺ molar ratios indicate that calcite weathering is the major source of solutes to the river system. The Kamni?ka Bistrica River and its tributaries are oversaturated with respect to calcite and dolomite. pCO₂ concentrations were on average up to 25 times over atmospheric values. δ¹³C_DIC values ranged from ?12.7 to ?2.7 ‰, controlled by biogeochemical processes in the catchment and within the stream; carbonate dissolution is the most important biogeochemical process affecting carbon isotopes in the upstream portions of the catchment, while carbonate dissolution and organic matter degradation control carbon isotope signatures downstream. Contributions of DIC from various biogeochemical processes were determined using steady state equations for different sampling seasons at the mouth of the Kamni?ka Bistrica River; results indicate that: (1) 1.9–2.2 % of DIC came from exchange with atmospheric CO₂, (2) 0–27.5 % of DIC came from degradation of organic matter, (3) 25.4–41.5 % of DIC came from dissolution of carbonates and (4) 33–85 % of DIC came from tributaries. δ¹⁵N values of nitrate ranged from ?5.2 ‰ at the headwater spring to 9.8 ‰ in the lower reaches. Higher δ¹⁵N values in the lower reaches of the river suggest anthropogenic pollution from agricultural activity. Based on seasonal and longitudinal changes of chemical and isotopic indicators of carbon and nitrogen in Kamni?ka Bistrica River, it can be concluded that seasonal changes are observed (higher concentrations are detected at low discharge conditions) and it turns from pristine alpine river to anthropogenic influenced river in central flow.     

The relation of Holocene fluvial terraces to changes in climate and sediment supply,South Fork Payette River,Idaho

Well-preserved Holocene terraces along the South Fork Payette River in central Idaho provide a record of fluvial system behavior in a steep mountain watershed characterized by weathered and erodible Idaho Batholith granitic rocks. Terrace deposit ages were provided by ¹⁴C dating of charcoal fragments and optically stimulated luminescence (OSL) dating of sandy sediments. Along with pairing of many terrace tread heights, these data indicate episodic downcutting during the Holocene, with a mean incision rate of ～0.9 m/ka from ～7 ka to present. Prior to 7 ka, the river incised to within～3 m of current bankfull, but then aggraded by ～5 m over at least a ～10 km-long reach in an episode centered ～7–6 ka. Aggradation may relate to (1) increased hillslope sediment input from landslides and debris flows in steep tributary basins with abundant grussified granitic bedrock, (2) possible local landslide-damming of the channel, (3) decreased peak discharge, or (4) a combination of these factors. Middle Holocene channel aggradation ca. 7–6 ka corresponds with a period of prolonged and widespread aridity in the northern Rocky Mountains. Between ～5 and 1.3 ka, the river aggraded slightly and then remained stable, forming a prominent terrace tread at ～3 m above current bankfull. Modest aggradation to vertical stability of the South Fork Payette River at the 1.5 m terrace level ～1.0–0.7 ka corresponds with large fire-related debris flows in tributaries during Medieval droughts. Three intervals of incision (～5.5–5 ka, 1.3–1.0 ka and 0.5 ka) correspond with frequent but small fire-related sedimentation events and generally cooler, wetter conditions suggesting increased snowmelt runoff discharges. Other possible drivers of channel incision include an increase in stochastic or climate-modulated large storms and floods and a reduction in delivery of hillslope sediment to the channel. Aggradation is more confidently tied to climate through increases in hillslope sediment delivery and (or) decreased stream power, both likely related to warmer, drier conditions (including high-severity fires) that reduce snowmelt and decrease vegetation cover on steep slopes. Thus, the Holocene terraces of the South Fork Payette River do not reflect simple stepwise incision with periods of vertical stability and lateral migration, but record substantial episodes of aggradation as well. We infer that increases in hillslope erosion and mass movements combined with reduced discharges during prolonged droughts episodically reverse the post-glacial trend of downcutting, in particular during the middle Holocene. The present bedrock-dominated channel implies a strong tendency toward incision in the late Holocene.     

Examining the effects of climate change, acidic deposition, and copper sulphate poisoning on long-term changes in cladoceran assemblages

We analyzed cladoceran remains in dated sediment cores from four lakes in Nova Scotia, Canada, to assess the potential effects of climate warming, acidic deposition, and a major fish kill caused by copper sulphate poisoning on assemblage composition and Bosmina size structure. In three of the four lakes, we observed a decline in Daphnia in the early 20th century that might be indicative of limnological changes in response to acidic deposition or increased fish predation. The appearance of the softwater zooplankter Holopedium glacialis in Hirtle Lake ~1995 might be linked to declining aqueous [Ca], a consequence of acidic deposition. No shifts in subfossil Cladocera were identified in this study that could be linked to climate warming. The application of copper sulphate as a fish poison to Trefry Lake (the lake was later re-stocked with trout fry) in 1938 resulted in dramatic and persistent changes in the cladoceran assemblage, where littoral Cladocera declined in relative abundance and small, pelagic Bosmina increased. In addition, we observed a reduction in the mean body size of Bosmina in post-1938 sediments, suggesting that planktivorous fish abundance increased and/or predatory copepods and other invertebrate predators decreased. No recovery of Cladocera to pre-disturbance conditions was observed. Overall, our data suggest that acidic deposition and calcium decline may have had a modest impact on the cladoceran communities in these lakes, but the effects of copper sulphate poisoning on the food web in Trefry Lake were widespread, and still persist over 70?years following this intervention.     

Eddy covariance imaging of diffuse volcanic CO<Subscript>2</Subscript> emissions at Mammoth Mountain,CA, USA

Use of eddy covariance (EC) techniques to map the spatial distribution of diffuse volcanic CO₂ fluxes and quantify CO₂ emission rate was tested at the Horseshoe Lake tree-kill area on Mammoth Mountain, California, USA. EC measurements of CO₂ flux were made during September–October 2010 and ranged from 85 to 1,766 g m⁻² day⁻¹. Comparative maps of soil CO₂ flux were simulated and CO₂ emission rates estimated from three accumulation chamber (AC) CO₂ flux surveys. Least-squares inversion of measured eddy covariance CO₂ fluxes and corresponding modeled source weight functions recovered 58–77% of the CO₂ emission rates estimated based on simulated AC soil CO₂ fluxes. Spatial distributions of modeled surface CO₂ fluxes based on EC and AC observations showed moderate to good correspondence (R ² = 0.36 to 0.70). Results provide a framework for automated monitoring of volcanic CO₂ emissions over relatively large areas.     

Indicators of sediment and biotic mercury contamination in a southern New England estuary

Total mercury (Hg) and methylmercury (MeHg) were analyzed in near surface sediments (0-2 cm) and biota (zooplankton, macro-invertebrates, finfish) collected from Narragansett Bay (Rhode Island/Massachusetts, USA) and adjacent embayments and tidal rivers. Spatial patterns in sediment contamination were governed by the high affinity of Hg for total organic carbon (TOC). Sediment MeHg and percent MeHg were also inversely related to summer bottom water dissolved oxygen (DO) concentrations, presumably due to the increased activity of methylating bacteria. For biota, Hg accumulation was influenced by inter-specific habitat preferences and trophic structure, and sediments with high TOC and percent silt-clay composition limited mercury bioavailability. Moreover, hypoxic bottom water limited Hg bioaccumulation, which is possibly mediated by a reduction in biotic foraging, and thus, dietary uptake of mercury. Finally, most biota demonstrated a significant positive relationship between tissue and TOC-normalized sediment Hg, but relationships were much weaker or absent for sediment MeHg. These results have important implications for the utility of estuarine biota as subjects for mercury monitoring programs.     

Stream nitrate uptake and transient storage over a gradient of geomorphic complexity,north‐central Colorado,USA

The understanding of nutrient uptake in streams is impeded by a limited understanding of how geomorphic setting and flow regime interact with biogeochemical processing. This study investigated these interactions as they relate to transient storage and nitrate uptake in small agricultural and urban streams. Sites were selected across a gradient of channel conditions and management modifications and included three 180‐m long geomorphically distinct reaches on each of two streams in north‐central Colorado. The agricultural stream has been subject to historically variable cattle‐grazing practices, and the urban stream exhibits various levels of stabilisation and planform alteration. Reach‐scale geomorphic complexity was characterised using highly detailed surveys of channel morphology, substrate, hydraulics and habitat units. Breakthrough‐curve modelling of conservative bromide (Br^?) and nonconservative nitrate (NO₃^?) tracer injections characterised transient storage and nitrate uptake along each reach. Longitudinal roughness and flow depth were positively associated with transient storage, which was related to nitrate uptake, thus underscoring the importance of geomorphic influences on stream biogeochemical processes. In addition, changes in geomorphic characteristics due to temporal discharge variation led to complex responses in nitrate uptake. Copyright © 2011 John Wiley & Sons, Ltd.