Methodological Considerations Regarding the Measurement of Turbulent Fluxes in the Urban Roughness Sublayer: The Role of Scintillometery

We address some of the methodological challenges associated with the measurement of turbulence and use of scintillometers in the urban roughness sublayer (RSL). Two small-aperture scintillometers were located near the roof interface in a densely urbanized part of Basel, Switzerland, as part of the Basel Urban Boundary-Layer Experiment (BUBBLE) in the summer of 2002. Eddy correlation instruments were co-located near the mid-point of each scintillometer path for data verification purposes. The study presents the first values of the inner length scale of turbulence (l ₀) and the refractive index structure parameter of air for a city and demonstrates the influence of mechanical driven turbulence on dissipation. Comparison of dissipation values determined from the two approaches show large scatter that is possibly due to the spatial inhomogeneity of the turbulence statistics within the RSL. Velocity and temperature spectra display a −2/3 slope in the inertial subrange, although the spectral ratio is less than the theoretical prediction of 4/3 expected for isotropy. Conventional Monin–Obukhov equations used to calculate fluxes from the scintillometer were replaced with urban forms of the equations. The results suggest that the scintillometer may be an appropriate tool for the measurement of sensible heat flux (Q _H ) above the rooftops given a suitable determination of the effective measurement height.     

Dating prehistoric bog-fires in northern England to calendar years by long-distance cross-matching of pine chronologies

The ages of prehistoric fires can be approximated by radiocarbon dating of charcoal or associated material, but such dating is often inaccurate and at best imprecise. Pine trunks preserved in British and Irish peats occasionally show firescars, which might be dated through dendrochronology to yield calendar-year dates. However, unlike oak, there is no master pine chronology to provide absolute dates, so dating is dependent on interspecies cross-matching; for sites in the British Isles with no dated oaks, calendar-year dating of prehistoric pines has hitherto proved impossible. We present a first success in dating, accurately and precisely, prehistoric fire events recorded in subfossil bog-pine trunks, using long-distance cross-matching of pine chronologies between White Moss, Cheshire, and the Humberhead Levels, England. Results demonstrate a bog-fire in Cheshire in spring 2800 BC, and again in 2710 BC, between spring and summer. Further successful long-distance cross-matching of pine would permit international climatological comparisons. © 1997 John Wiley & Sons, Ltd.     

Quantification of Storm-Induced Bathymetric Change in a Back-Barrier Estuary

Geomorphology is a fundamental control on ecological and economic function of estuaries. However, relative to open coasts, there has been little quantification of storm-induced bathymetric change in back-barrier estuaries. Vessel-based and airborne bathymetric mapping can cover large areas quickly, but change detection is difficult because measurement errors can be larger than the actual changes over the storm timescale. We quantified storm-induced bathymetric changes at several locations in Chincoteague Bay, Maryland/Virginia, over the August 2014 to July 2015 period using fixed, downward-looking altimeters and numerical modeling. At sand-dominated shoal sites, measurements showed storm-induced changes on the order of 5 cm, with variability related to stress magnitude and wind direction. Numerical modeling indicates that the predominantly northeasterly wind direction in the fall and winter promotes southwest-directed sediment transport, causing erosion of the northern face of sandy shoals; southwesterly winds in the spring and summer lead to the opposite trend. Our results suggest that storm-induced estuarine bathymetric change magnitudes are often smaller than those detectable with methods such as LiDAR. More precise fixed-sensor methods have the ability to elucidate the geomorphic processes responsible for modulating estuarine bathymetry on the event and seasonal timescale, but are limited spatially. Numerical modeling enables interpretation of broad-scale geomorphic processes and can be used to infer the long-term trajectory of estuarine bathymetric change due to episodic events, when informed by fixed-sensor methods.     

NMR relaxation measurements of biofouling in model and geological porous media

Recently 2D nuclear magnetic resonance (NMR) relaxation techniques have been able to access changes in pore structures through surface and diffusion based relaxation measurements. This research investigates the applicability of these methods for measuring pore and surface changes due to biofilm growth in various model porous systems and natural geological media. Model bead packs of various construction containing 100 μm borosilicate and soda lime glass beads were used to demonstrate how changes in the measured relaxation rates can be used to non-invasively verify and quantify biofilm growth in porous media. However significant challenges are shown to arise when trying to implement the same techniques to verify biofilm growth in a natural geological media.     

An investigation of lead chromate (crocoite-PbCrO4) and other inorganic pigments in aged traffic paint samples from Hamilton,Ohio: implications for lead in the environment

Traffic paint samples collected from roads in the City of Hamilton, Butler County, OH, USA were investigated to determine whether or not pigments are hazardous and are of environmental concern. Powder X-ray diffraction (XRD) and scanning electron microscopy (SEM) indicate that white and gray paint samples are dominated by calcite, rutile, anatase and quartz and blue traffic paint samples are dominated by calcite and barite. XRD and SEM indicate that most yellow traffic paints have lead chromate (crocoite-PbCrO₄) with common particle sizes that are typically 125–350 nm in length and 75–200 nm in width. Larger aggregates of several micrometers in diameter are also observed. The solubility of PbCrO₄ (1.34 × 10^?7 mol/L at 25 °C) combined with an increase in solubility with exposure to 0.05–0.25 M NaCl and CaCl₂ road treatments solutions as demonstrated by basic batch experiments likely makes PbCrO₄ from traffic paint a potential source for lead pollution in surface water and groundwater that is not fully recognized.     

“Progressive port Elizabeth”: Liberal politics,local economic development and the territorial basis of racial domination, 1923–1935

The growth of state capacity with respect to African people in South Africa's cities, while an ambition of many local and central state managers, was secured only in the face of conflicts within the state and between the state and the people. This paper examines some of the specific social processes which shaped the segregated form of African settlement and administration in Port Elizabeth between 1923–35. The aim is to interpret how the unique configuration of social and economic conditions in Port Elizabeth both fed into and depended upon an as yet imperfectly implemented strategy for the government and control of the city's African populace. Issues of concern include the nature of the administration in the New Brighton Location, the influence of liberal politics on Location strategy and the impact of the local council's efforts at place entrepreneurialism on residential development and urban government.     

The importance of grain size and shape in controlling the dispersion of the Vedde cryptotephra

Volcanic ash is dispersed in the atmosphere according to meteorology and particle properties, including size and shape. However, the multiple definitions of size and shape for non-spherical particles affect our ability to use physical particle properties to understand tephra transport. Moreover, although particles are often excluded from operational ash dispersion model setups, ash in tephra deposits 1000 km from source can exceed . Here we measure the shape and size of samples of Vedde ash from Iceland, an exceptionally widespread tephra layer in Europe, collected in Iceland and Norway. Using X-ray computed tomography and optical microscopy, we show that distal ash is more anisotropic than proximate ash, suggesting that shape exerts an important control on tephra dispersion. Shape also impacts particle size measurements. Particle long axis, a parameter often reported by tephrochronologists, is on average greater than geometric size, used by dispersion modellers. By using geometric size and quantifying shape, we can explain the transport of Vedde ash particles more than 1200 km from source. We define a set of best practices for measuring the size and shape of cryptotephra shards and discuss the benefits and limitations of using physical particle properties to understand cryptotephra transport.     

Complex exposure histories of chert clasts in the late Pleistocene shorelines of Lake Lisan,southern Israel

Activities of ²⁶Al and ¹⁰Be in five chert clasts sampled from two beach ridges of late Pleistocene Lake Lisan, precursor of the Dead Sea in southern Israel, indicate low rates of chert bedrock erosion and complex exposure, burial, and by inference, transport histories. The chert clasts were derived from the Senonian Mishash Formation, a chert‐bearing chalk, which is widely exposed in the Nahal Zin drainage basin, the drainage system that supplied most of the material to the beach ridges. Simple exposure ages, assuming only exposure at the beach ridge sampling sites, range from 35 to 354 ky; using the ratio ²⁶Al/¹⁰Be, total clast histories range from 0·46 to 4·3 My, unrelated to the clasts' current position and exposure period on the late Pleistocene beach ridges, 160–177 m below sea level. Optically stimulated luminescence dating of fine sediments from the same and nearby beach ridges yielded ages of 20·0 ± 1·4 ka and 36·1 ± 3·3 ka. These ages are supported by the degree of soil development on the beach ridges and correspond well with previously determined ages of Lake Lisan, which suggest that the lake reached its highest stand around 27 000 cal. years BP . If the clasts were exposed only once and than buried beyond the range of significant cosmogenic nuclide production, then the minimum initial exposure and the total burial times before delivery to the beach ridge are in the ranges 50–1300 ky and 390–3130 ky respectively. Alternatively, the initial cosmogenic dosing could have occurred during steady erosion of the source bedrock. Back calculating such rates of rock erosion suggests values between 0·4 and 12 m My^?1. The relatively long burial periods indicate extended sediment storage as colluvium on slopes and/or as alluvial deposits in river terraces. Some clasts may have been stored for long periods in abandoned Pliocene and early Pleistocene routes of Nahal Zin to the Mediterranean before being transported again back into the Nahal Zin drainage system and washed on to the shores of Lake Lisan during the late Pleistocene. Copyright © 2003 John Wiley & Sons, Ltd.     

Toxicity of a secondary-treated sewage effluent to marine biota in Bass Strait, Australia: development of action trigger values for a toxicity monitoring program

Melbourne Water's Eastern Treatment Plant (ETP) produces a secondary-treated sewage effluent which is chlorinated and discharged into Bass Strait at Boags Rocks, Victoria, Australia. Disappearance of the sensitive brown seaweed Hormosira banksii from rock platforms immediately adjacent to the shore-line discharge was identified in the early 1990s. Subsequently, Melbourne Water and CSIRO undertook an environmental impact assessment and review of land and marine effluent disposal options, which included ambient water quality monitoring, biological monitoring, bioaccumulation studies and toxicity testing of existing effluent to assess the nature and magnitude of the environmental effects. This paper presents data from the toxicity monitoring programs since 2001. Chronic toxicity testing using macroalgal germination and cell division (H. banksii), microalgal growth rate (Nitzschia closterium) and scallop larval development (Chlamys asperrima), confirmed that ammonia was the major cause of effluent toxicity. Results from this toxicity monitoring program were used to develop action trigger values for toxicity for each species, which were then used in a refined monitoring program in 2005-2007. An upgrade of the ETP is in progress to improve nitrification/denitrification in order to reduce ammonia concentrations and the toxicity of the effluent. Toxicity testing with a simulated upgraded effluent confirmed that ammonia concentrations and toxicity were reduced. Estimated "safe" dilutions of effluent, calculated using species sensitivity distributions, decreased from 1:140-300 for existing ETP effluent to 1:20 for nitrified effluent, further confirming that treatment improvements should reduce the impact on marine biota in the vicinity of the discharge.