Mercury in Eastern Kentucky coals: Geologic aspects and possible reduction strategies

Mercury emissions from US coal-fired power plants will be regulated by the US Environmental Protection Agency (USEPA) before the end of the decade. Because of this, the control of Hg in coal is important. Control is fundamentally based on the knowledge of the amounts of Hg in mined, beneficiated, and as-fired coal. Eastern Kentucky coals, on a reserve district level, have Hg contents similar to the USA average for coal at mines. Individual coals show greater variation at the bench scale, with Hg enrichment common in the top bench, often associated with enhanced levels of pyritic sulfur. Some of the variation between parts of eastern Kentucky is also based on the position relative to major faults. The Pine Mountain thrust fault appears to be responsible for elemental enrichment, including Hg, in coals on the footwall side of the thrust.Eastern Kentucky coals shipped to power plants in 1999, the year the USEPA requested coal quality information on coal deliveries, indicate that coals shipped from the region have 0.09 ppm Hg, compared to 0.10 ppm for all delivered coals in the USA. On an equal energy basis, and given equal concentrations of Hg, the high volatile bituminous coals from eastern Kentucky would emit less Hg than lower rank coals from other USA regions.     

Determining the trophic guilds of fishes and macroinvertebrates in a seagrass food web

We established trophic guilds of macroinvertebrate and fish taxa using correspondence analysis and a hierarchical clustering strategy for a seagrass food web in winter in the northeastern Gulf of Mexico. To create the diet matrix, we characterized the trophic linkages of macroinvertebrate and fish taxa present inHalodule wrightii seagrass habitat areas within the St. Marks National Wildlife Refuge (Florida) using binary data, combining dietary links obtained from relevant literature for macroinvertebrates with stomach analysis of common fishes collected during January and February of 1994. Heirarchical average-linkage cluster analysis of the 73 taxa of fishes and macroinvertebrates in the diet matrix yielded 14 clusters with diet similarity ≥ 0.60. We then used correspondence analysis with three factors to jointly plot the coordinates of the consumers (identified by cluster membership) and of the 33 food sources. Correspondence analysis served as a visualization tool for assigning each taxon to one of eight trophic guilds: herbivores, detritivores, suspension feeders, omnivores, molluscivores, meiobenthos consumers, macrobenthos consumers and piscivores. These trophic groups, corss-classified with major taxonomic groups, were further used to develop consumer compartments in a network analysis model of carbon flow in this seagrass ecosystem. The method presented here should greatly improve the development of future network models of food webs by providing an objective procedure for aggregating trophic groups.     

Determination of the seismic performance factors for post‐tensioned rocking timber wall systems

Post‐tensioned technologies for concrete seismic resistant buildings were first developed in the 1990s during the PREcast Seismic Structural Systems program. Among different solutions, the hybrid system proved to be the most resilient solution providing a combination of re‐centering and energy dissipative contributions respectively by using post‐tensioned tendons and mild steel reinforcement. The system, while providing significant strength and energy dissipation, reduces structural element damage and limits post‐earthquake residual displacements. More recently, the technology was extended to laminated veneer lumber (LVL) structural members, and extensive experimental and numerical work was carried out and allowed the development of reliable analytical and numerical models as well as design guidelines. On the basis of the experimental and numerical outcomes, this paper presents the evaluation of the seismic performance factors for post‐tensioned rocking LVL walls using the FEMA P‐695 procedure. Several archetype buildings were designed considering different parameters such as the building and story height, the type of seismic resistant system, the magnitude of gravity loads and the seismic design category. Lumped plasticity models were developed for each index archetype to simulate the behavioral aspects and collapse mechanisms. Non‐linear quasi‐static analyses were carried out to evaluate the system over‐strength factor; moreover, non‐linear time history analyses were performed using the incremental dynamic analysis concept to assess the collapse of each building. From the results of quasi‐static and dynamic analyses the response modification factor, R, system over‐strength factor, Ω₀, and deflection amplification factor, C_d, values of, respectively, 7, 3.5 and 7.5 are recommended. Copyright © 2016 John Wiley & Sons, Ltd.     

Neutron star models based on an improved equation of state

Using an equation of state for cold degenerate matter which takes nuclear forces and nuclear clustering into account, neutron star models are constructed. Stable models were obtained in the mass range above 0.065M and density range 10^14.08 to 10^15.4 gm/cm³. All of these models were found to be bound. The outer crystalline layer of the star was found to have a thickness of 200 m or more depending on the mass of the model.     

Scientific problems addressed by the Spektr-UV space project (world space Observatory—Ultraviolet)

The article presents a review of scientific problems and methods of ultraviolet astronomy, focusing on perspective scientific problems (directions) whose solution requires UV space observatories. These include reionization and the history of star formation in the Universe, searches for dark baryonic matter, physical and chemical processes in the interstellar medium and protoplanetary disks, the physics of accretion and outflows in astrophysical objects, from Active Galactic Nuclei to close binary stars, stellar activity (for both low-mass and high-mass stars), and processes occurring in the atmospheres of both planets in the solar system and exoplanets. Technological progress in UV astronomy achieved in recent years is also considered. The well advanced, international, Russian-led Spektr-UV (World Space Observatory—Ultraviolet) project is described in more detail. This project is directed at creating a major space observatory operational in the ultraviolet (115–310 nm). This observatory will provide an effective, and possibly the only, powerful means of observing in this spectral range over the next ten years, and will be an powerful tool for resolving many topical scientific problems.     

Estimating economic losses of midrise reinforced concrete shear wall buildings in sedimentary basins by combining empirical and simulated seismic hazard characterizations

Studies of recorded ground motions and simulations have shown that deep sedimentary basins can greatly increase the intensity of earthquake ground motions within a period range of approximately 1–4 s, but the economic impacts of basin effects are uncertain. This paper estimates key economic indicators of seismic performance, expressed in terms of earthquake‐induced repair costs, using empirical and simulated seismic hazard characterizations that account for the effects of basins. The methodology used is general, but the estimates are made for a series of eight‐ to 24‐story residential reinforced concrete shear wall archetype buildings in Seattle, WA, whose design neglects basin effects. All buildings are designed to comply with code‐minimum requirements (i.e., reference archetypes), as well as a series of design enhancements, which include (a) increasing design forces, (b) decreasing drift limits, and (c) a combination of these strategies. As an additional reference point, a performance‐based design is also assessed. The performance of the archetype buildings is evaluated for the seismic hazard level in Seattle according to the 2018 National Seismic Hazard Model (2018 NSHM), which explicitly considers basin effects. Inclusion of basin effects results in an average threefold increase in annualized losses for all archetypes. Incorporating physics‐based ground motion simulations to represent the large‐magnitude Cascadia subduction interface earthquake contribution to the hazard results in a further increase of 22% relative to the 2018 NSHM. The most effective of the design strategies considered combines a 25% increase in strength with a reduction in drift limits to 1.5%.     

Argon and nitrogen isotopes of trapped air in the GISP2 ice core during the Holocene epoch (0-11,500 B.P.): Methodology and implications for gas loss processes

Argon and nitrogen isotopes of air in polar ice cores provide constraints on past temperature and firn thickness, with relevance to past climate. We developed a method to simultaneously measure nitrogen and argon isotopes in trapped air from the same sample of polar ice. This method reduces the time required for analysis, allowing large numbers of measurements. We applied this method to the entire Holocene sequence of the GISP2 ice core (82.37-1692.22 m) with a 10-20 year sampling interval (670 depths). δ⁴⁰Ar and δ¹⁵N show elevated values in the oldest part of the dataset, consistent with a thicker firn layer and increased temperature gradient in the firn due to the legacy of the abrupt warming at the end of the Younger Dryas interval and the gradual warming during the Preboreal interval (11.5-10.0 ka). The Preboreal Oscillation and the 8.2k event are clearly recorded. The data show remarkable stability after the 8.2k event.Available data suggests that post-coring gas loss involves two distinct types of fractionation. First, smaller molecules with less than a certain threshold size leak through the ice lattice with little isotopic fractionation. Second, gas composition changes via gas loss through microcracks, which induces isotopic fractionation. These two gas loss processes can explain most trends in our data and in other ice core records.     

Atmospheric mercury near Salmon Falls Creek Reservoir in southern Idaho

Gaseous elemental mercury (GEM) and reactive gaseous mercury (RGM) were measured over 2-week seasonal field campaigns near Salmon Falls Creek Reservoir in south-central Idaho from the summer of 2005 through the fall of 2006 and over the entire summer of 2006 using automated Tekran Hg analyzers. GEM, RGM, and particulate Hg (HgP) were also measured at a secondary site 90 km to the west in southwestern Idaho during the summer of 2006. The study was performed to characterize Hg air concentrations in the southern Idaho area for the first time, estimate Hg dry deposition rates, and investigate the source of observed elevated concentrations. High seasonal variability was observed with the highest GEM (1.91 ± 0.9 ng m⁻³) and RGM (8.1 ± 5.6 pg m⁻³) concentrations occurring in the summer and lower values in the winter (1.32 ± 0.3 ng m⁻³, 3.2 ± 2.9 pg m⁻³ for GEM, RGM, respectively). The summer-average HgP concentrations were generally below detection limit (0.6 ± 1 pg m⁻³). Seasonally averaged deposition velocities calculated using a resistance model were 0.034 ± 0.032, 0.043 ± 0.040, 0.00084 ± 0.0017 and 0.00036 ± 0.0011 cm s⁻¹ for GEM (spring, summer, fall and winter, respectively) and 0.50 ± 0.39, 0.40 ± 0.31, 0.51 ± 0.43 and 0.76 ± 0.57 cm s⁻¹ for RGM. The total annual RGM + GEM dry deposition estimate was calculated to be 11.9 ± 3.3 μg m⁻², or about 2/3 of the total (wet + dry) deposition estimate for the area. Periodic elevated short-term GEM (2.2–12 ng m⁻³) and RGM (50–150 pg m⁻³) events were observed primarily during the warm seasons. Back-trajectory modeling and PSCF analysis indicate predominant source directions to the SE (western Utah, northeastern Nevada) and SW (north-central Nevada) with fewer inputs from the NW (southeastern Oregon and southwestern Idaho).     

Recombination of electrons with H3+ and H5+ ions

The dissociative recombination coefficients α for capture of electrons by H₃⁺ and H₅⁺ ions have been determined as a function of electron temperature T_e using a microwave afterglow-mass spectrometer apparatus. At ion and neutral temperatures T_u+ = T_n = 240 K, the coefficient α (H₃⁺) is found to vary slowly with T_e at first, decreasing from 1.6 × 10^?7 cm³/s at T_e = 240 K to 1.2 × 10^?7 cm³/s at T_e = 500 K, thereafter falling as T_e^?1 over the range 500 K ? T_e, ? 3000 K. These results, which have a ± 20% uncertainty, agree satisfactorily over the common energy range (0.03–0.36 eV) with the recombination cross sections determined in merged beam measurements by Auerbach et al. At T₊ = T_n = 128 K, the coefficient α(H₅⁺) is found to be (1.8 ± 0.3) × 10^?6 [T_e(K)/300]^?0.69 cm³/s over the range 128 K ? T_e ? 3000 K, with a more rapid decrease, as T_e^?1, between 3000 K and 5500 K. The implications of these results for modelling planetary atmospheres and interstellar clouds are briefly touched on.