Siderophile and chalcophile element abundances in shergottites: Implications for Martian core formation

Elemental abundances for volatile siderophile and chalcophile elements for Mars inform us about processes of accretion and core formation. Such data are few for Martian meteorites, and are often lacking in the growing number of desert finds. In this study, we employed laser ablation inductively coupled plasma–mass spectrometry (LA‐ICP‐MS) to analyze polished slabs of 15 Martian meteorites for the abundances of about 70 elements. This technique has high sensitivity, excellent precision, and is generally accurate as determined by comparisons of elements for which literature abundances are known. However, in some meteorites, the analyzed surface is not representative of the bulk composition due to the over‐ or underrepresentation of a key host mineral, e.g., phosphate for rare earth elements (REE). For other meteorites, the range of variation in bulk rastered analyses of REE is within the range of variation reported among bulk REE analyses in the literature. An unexpected benefit has been the determination of the abundances of Ir and Os with a precision and accuracy comparable to the isotope dilution technique. Overall, the speed and small sample consumption afforded by this technique makes it an important tool widely applicable to small or rare meteorites for which a polished sample was prepared. The new volatile siderophile and chalcophile element abundances have been employed to determine Ge and Sb abundances, and revise Zn, As, and Bi abundances for the Martian mantle. The new estimates of Martian mantle composition support core formation at intermediate pressures (14 ± 3 GPa) in a magma ocean on Mars.     

Use of the conditional spectrum to incorporate record‐to‐record variability in simplified seismic assessment of RC wall buildings

A procedure for incorporating record‐to‐record variability into the simplified seismic assessment of RC wall buildings is presented. The procedure relies on the use of the conditional spectrum to randomly sample spectral ordinates at relevant periods of vibration. For inelastic response, displacement reduction factors are then used to relate inelastic displacement demand to the spectral displacement at the effective period for single‐degree‐of‐freedom systems. Simple equations are used to convert back and forth between multi‐degree‐of‐freedom RC wall buildings and equivalent single‐degree‐of‐systems so that relevant engineering demand parameters can be obtained. Consideration is also given to higher‐mode effects by adapting existing modal combination rules. The proposed method is applied to several case study buildings, showing promising results in the examination of inter‐storey drift ratio and shear forces. The proposed method captures the variation in the distribution of structural response parameters that occurs with variations in structural configuration, intensity, engineering demand parameter of interest and site characteristics. Discussion is provided on possible ways to improve the accuracy of the procedure and suggestions for additional future work. Copyright © 2015 John Wiley & Sons, Ltd.     

Active tectonics of an apparently aseismic region: distributed active strike-slip faulting in the Hangay Mountains of central Mongolia

We identify and describe a series of east–west left-lateral strike-slip faults (named the Songino-Margats, the Hag Nuur, the Uliastay and the South Hangay fault systems) in the Hangay mountains of central Mongolia: an area that has little in the way of recorded seismicity and which is often considered as a rigid block within the India–Eurasia collision zone. The strike-slip faults of central Mongolia constitute a previously unrecognized hazard in this part of Mongolia. Each of the strike-slip faults show indications of late Quaternary activity in the form of aligned sequences of sag-ponds and pressure-ridges developed in alluvial deposits. Total bed-rock displacements of ∼3 km are measured on both the Songino-Margats and South Hangay fault systems. Bed-rock displacements of 11 km are observed across the Hag Nuur fault. Cumulative offset across the Uliastay fault systems are unknown but are unlikely to be large. We have no quantitative constraint on the age of faulting in the Hangay. The ≤20 km of cumulative slip on the Hangay faults might, at least in part, be inherited from earlier tectonic movements. Our observations show that, despite the almost complete absence of instrumentally recorded seismicity in the Hangay, this part of Mongolia is cut through by numerous distributed strike-slip faults that accommodate regional left-lateral shear between Siberia and China. Central Mongolia is thus an important component of the India–Eurasia collision that would be overlooked in models of the active tectonics based on the distribution of seismicity. We suggest that active faults such as those identified in the Hangay of Mongolia might exist in other, apparently aseismic, regions within continental collision zones.     

Crustal Thermal Structure of the Brazilian Equatorial Margin Using Fourier and Continuous Wavelet Transforms: A Comparative Analysis Based on Different Magnetic Datasets

Surveys in Geophysics - In this work, we calculated the Curie Point Depth (CPD) for the Brazilian Equatorial Margin using the Fourier and continuous wavelet (CWT) transforms considering a linear...     

Numerical integration of the equations of motion of celestial mechanics

Recently a number of new techniques have been developed for the numerical solution of the differential equations governing the motion of bodies in the Solar System, moving under their mutual gravitational forces. Some of these new methods are tested against each other and against more traditional methods and conclusions are made as to under what circumstances any of these methods should be used to produce optimum results.     

Vegetation Cover and Elevation in Long-Term Experimental Nutrient-Enrichment Plots in Great Sippewissett Salt Marsh,Cape Cod,Massachusetts: Implications for Eutrophication and Sea Level rise

Nitrogen inputs restructure ecosystems and can interact with other agents of ecological change and potentially intensify them. To examine the effects of nitrogen combined with those of elevation and competition, in 2005 we mapped vegetation and elevation within experimental plots that have been fertilized since 1970 in Great Sippewissett salt marsh, Cape Cod, MA, USA and compared the resulting effects on marsh vegetation. Decadal-scale chronic nutrient enrichment forced changes in cover and spatial distribution of different species. With increasing enrichment, there was a shift in species cover primarily involving loss of Spartina alterniflora and an increase in Distichlis spicata. Percent cover of near monocultures increased with nitrogen fertilization, owing mainly to the proliferation of D. spicata. The experimental fertilization prompted a shift from the short form of S. alterniflora to taller forms, hence increasing above-ground biomass, where this species managed to remain. Chronic enrichment increased upper and lower limits of the elevation range within which certain species occurred. The shift to increased cover of D. spicata was also associated with faster accretion of the marsh surface where this species was dominant, but not where S. alterniflora was dominant. Interactions among nutrient supply, elevation, and competition altered the direction of competitive success among different species of marsh plants, and forced changes in the spatial distribution and composition of the salt marsh plant communities. The results imply that there will be parallel changes in New England salt marshes owing to the widespread eutrophication of coastal waters and the increasing sea level rise. Knowing the mechanisms structuring marsh vegetative cover, and their role in modification of salt marsh accretion, may provide background with which to manage maintenance of affected coastal wetlands.     

Soil properties controlling seepage erosion contributions to streambank failure

The majority of sediment leaving catchments may be from streambank failure. Seepage erosion of unconsolidated sand above a restrictive layer is an important erosion process in incised streams that leads to streambank failure by undercutting banks. The objective of this study was to determine the impact of soil properties on seepage erosion and the resulting streambank failure. Seepage flow and sediment concentrations were measured in situ at eight locations along the banks of a deeply incised stream in northern Mississippi. Using field observations as a guide, the soil profile conditions of a shallow (45 cm) streambank, consisting of 30 cm of topsoil, a 10 cm conductive layer, and a 5 cm restrictive layer, were mimicked in laboratory lysimeter experiments to quantify the hydrologic properties controlling seepage erosion and bank failure under a 40 cm head. The time to flow initiation and the flow rate were linearly related to the slope of the restrictive layer. Seepage erosion began within minutes of flow initiation and resulted in substantial (3 to 34 cm) undercutting of the bank. Sediment concentrations of seeps were as high as 660 g l^?1 in situ and 4500 g l^?1 in the lysimeters. Sediment concentrations were related to the layer slope, thereby indicating the importance of detailed site characterization. The USDA‐ARS Streambank Stability model demonstrated the increase in instability of banks due to undercutting by seepage erosion, but failed to account for the sediment loss due to sapping for stable banks and overestimated the sediment loads for failed banks. Published in 2006 by John Wiley & Sons, Ltd.     

High-Resolution Integrated Transport Model for Studying Surface Water–Groundwater Interaction

Transport processes that lead to exchange of mass between surface water and groundwater play a significant role for the ecological functioning of aquatic systems, for hydrological processes and for biogeochemical transformations. In this study, we present a novel integral modeling approach for flow and transport at the sediment–water interface. The model allows us to simultaneously simulate turbulent surface and subsurface flow and transport with the same conceptual approach. For this purpose, a conservative transport equation was implemented to an existing approach that uses an extended version of the Navier–Stokes equations. Based on previous flume studies which investigated the spreading of a dye tracer under neutral, losing and gaining flow conditions the new solver is validated. Tracer distributions of the experiments are in close agreement with the simulations. The simulated flow paths are significantly affected by in- and outflowing groundwater flow. The highest velocities within the sediment are found for losing condition, which leads to shorter residence times compared to neutral and gaining conditions. The largest extent of the hyporheic exchange flow is observed under neutral condition. The new solver can be used for further examinations of cases that are not suitable for the conventional coupled models, for example, if Reynolds numbers are larger than 10. Moreover, results gained with the integral solver provide high-resolution information on pressure and velocity distributions at the rippled streambed, which can be used to improve flow predictions. This includes the extent of hyporheic exchange under varying ambient groundwater flow conditions.