ASSESSMENT OF A SIMPLE METHOD FOR THE DETERMINATION OF NB AND TA AT THE SUB-μG/G LEVEL IN SILICATE ROCKS BY ICP-MS

We report Nb and Ta data for 15 international silicate rock standards, obtained by inductively coupled plasma-mass spectrometry (ICP-MS) measurement following decomposition with HF-HNOs-HCI.⁹⁵ Moand¹⁸⁵Re were used as internal standards, and calibration lines were constructed with artificial solutions. Typical relative standard deviations are better than 10% above 0.2 μg/g, and detection limits for Nb and Ta are 40 and 0.8 ng/g, respectively. The results are generally in good agreement with published data. Moreover, this study points out the Nb-Ta heterogeneity of some standard reference materials on the 100 mg scale.     

New carbonatite complexes in the Archaean In'Ouzzal nucleus (Ahaggar,Algeria): mineralogical and geochemical data

Several massifs of very old carbonatites have been discovered in the Archaean granulitic block of In'Ouzzal (Western Ahaggar, Algeria). These carbonatites are original since they are associated with Silica — saturated syenitic magmatism and present, in the late stages of evolution, a very uncommon mineralogy, with silicate minerals, especially wollastonite, allanite, and quartz. The mineralogy, C and O isotopes and R.E.E. distributions indicate that the late stages of crystallization occurred under high SiO₂ activities, and produced the uncommon mineralogy and extremely high R.E.E. concentrations in phosphate minerals apatite and britholite. Interaction with continental crust is a possible mechanism to explain the original features of these carbonatite complexes.     

Pyrite oxidation during sample storage determines phosphorus fractionation in carbonate-poor anoxic sediments

We investigated the phosphorus (P) and iron (Fe) fractionation in four cores with anoxic sediments, deposited during the mid-Cretaceous oceanic anoxic event 2 (∼94 Ma) and the Paleocene-Eocene thermal maximum (∼55 Ma), that were exposed to oxygen after core recovery. Surprisingly, P associated with iron oxyhydroxides (Fe-bound P) was a major P phase in these laminated sediments deposited under euxinic conditions. A significant fraction of total Fe was present as (poorly) crystalline ferric Fe. This fraction increased with increasing storage time of the investigated cores. In carbonate-poor samples, Fe-bound P accounted for up to 99% of total P and its abundance correlated with pyrite contents. In samples with higher CaCO₃ contents (>5 wt% in the investigated samples), P was mostly present in authigenic Ca-P minerals, irrespective of pyrite contents. We conclude that the P fractionation in anoxic, carbonate-poor, sediments is strongly affected by pyrite oxidation that occurs when these sediments are exposed to oxygen. Pyrite oxidation produces sulfuric acid and iron oxyhydroxides. The abundance of poorly crystalline Fe oxyhydroxides provides further evidence that these were indeed formed through recent (post-recovery) oxidation rather than in situ tens of millions of years ago. The acid dissolves apatite and the released phosphate is subsequently bound in the freshly formed iron oxyhydroxides. Pyrite oxidation thus leads to a conversion of authigenic Ca-P to Fe-bound P. In more calcareous samples, CaCO₃ can act as an effective buffer against acidic dissolution of Ca-P minerals. The results indicate that shielding of sediments from atmospheric oxygen is vital to preserve the in situ P fractionation and to enable a valid reconstruction of marine phosphorus cycling based on sediment records.     

Ion exchange and trace element surface complexation reactions associated with applied recharge of low-TDS water in the San Joaquin Valley,California

Stable isotope data, a dissolved gas tracer study, groundwater age dating, and geochemical modeling were used to identify and characterize the effects of introducing low-TDS recharge water in a shallow aerobic aquifer affected by a managed aquifer recharge project in California’s San Joaquin Valley. The data all consistently point to a substantial degree of mixing of recharge water from surface ponds with ambient groundwater in a number of nearby wells screened at depths above 60 m below ground surface. Groundwater age data indicate that the wells near the recharge ponds sample recently recharged water, as delineated by stable O and C isotope data as well as total dissolved solids, in addition to much older groundwater in various mixing proportions. Where the recharge water signature is present, the specific geochemical interactions between the recharge water and the aquifer material appear to include ion exchange reactions (comparative enrichment of affected groundwater with Na and K at the expense of Ca and Mg) and the desorption of oxyanion-forming trace elements (As, V, and Mo), possibly in response to the elevated pH of the recharge water.     

Hydrological processes of a rainforest headwater swamp from natural chemical tracing in Nsimi watershed,Cameroon

The hydrological role of a headwater swamp in a tropical rainforest is studied using chloride mass balance (CMB) and end‐member mixing analysis. There are three main contributions to streamflow: (1) the hillside bedrock aquifer, (2) overland flow from the swamp during storm events and (3) groundwater flow from the swamp aquifer. Before rainfall events of the wet season, the pre‐event water comprises a mix of 80% of bedrock aquifer and 20% of swamp aquifer. During storms, the relative contribution of overland flow increases according to the rainfall intensity and the initial saturation rate of the pre‐event water reservoirs. The yearly contribution of overland flow from the swamp to the stream is about 31%. The relationship between the swamp and the stream fluctuates with space and time. Generally, the swamp is drained by the stream; however, at the end of long dry seasons, after the first rains, indirect recharge occurs from the stream to the swamp with a hydraulic gradient inversion in the swamp aquifer. The net contribution of the swamp aquifer to the stream is only 4%, which is much lower than the hillside aquifer contribution of about 65%. Recharge on the swamp being very low, these results suggest that, except for a few storms at the end of the dry season, the Nsimi swamp does not contribute to flood attenuation. Evapotranspiration is higher on the hillside than in the swamp. Nevertheless, depletion of water stored within the swamp is dominated by evaporation rather than by its contribution to streamflow. The export of solutes through swamp groundwater flow below the weir is low (<7%). Nevertheless, the swamp is the most active area of weathering in the watershed. Copyright © 2011 John Wiley & Sons, Ltd.     

Estimation of PM20 emissions by wind erosion: main sources of uncertainties

The physics of the two processes (saltation and sandblasting) leading to fine mineral dust emissions by wind erosion in arid or semi-arid areas has been detailed and modeled. The combination of these two models has led to a physically explicit Dust Production Model (DPM). In this work, sensitivity tests are performed with the DPM to determine the nature of the main soil parameters that control dust emissions by sandblasting. It is found that the soil roughness length and the dry size distribution of the soil aggregates constituting the loose wind erodible fraction of the topsoil have the greatest influence on the soil potential for mineral dust production. Contrary to what is often assumed, soil texture is not a relevant parameter.In the light of these new findings, results of vertical flux measurements performed over a wide variety of sources in Niger and the US south west (14 soils) have been reanalyzed. Results show (1) that for the tested soils the DPM, and hence sandblasting, explain all dust emissions, and (2) that 13 of the 14 soils that had been selected a priori for their high potential for dust emissions contained a fine soil-aggregate component. This is consistent with the sensitivity tests indicating that the presence of such a component could enhance dust emissions by one order of magnitude. Finally, it can be concluded that most of the apparent scatter in the experimental results was in large part due to an inappropriate choice of soil parameters to interpret them.     

Bifurcation and generalized mixed loading conditions in geomaterials

The concept of bifurcation has been widely discussed, based, for example, on homogeneous tests in soil mechanics. Essentially two‐dimensional (axisymmetric) conditions have been considered. This paper aims at deriving a bifurcation criterion in geomechanics, independently of the problem's dimension. This criterion is related to the vanishing of the determinant of the symmetric part of the material's (or the discrete system's) constitutive (or stiffness) matrix. The derivation is essentially based on the notion of loading parameters (controlling the loading). Basically, a bifurcation occurs when the existence of a unique solution to the quasistatic problem, involving a given set of loading parameters, is lost. Interestingly, the criterion is shown to be independent of the choice of loading parameters. As a possible extension, the context of structure mechanics is considered, and the close connection between both soil and structure analysis is discussed. Copyright © 2010 John Wiley & Sons, Ltd.     

An opportunity to connect the morphodynamics of alternate bars with their sedimentary products

Field investigations that help clarify local sedimentary processes involved in the migration of alternate bars as a consequence of flood events are lacking. A simple approach combining scour chains, stratigraphy and frequent bathymetric surveys is proposed to connect the dynamics of free migrating alternate bars present in disconnected channels of large sandy‐gravelly rivers with their sedimentary products and vice versa. The results show that the spatial distribution of bars before a flood partly governs the scour and fill processes and that the sediment transport rates vary significantly on a single cross‐section. This can be due to preferential axes of the migration of the bars determined by their location on the cross‐section, the bank direction and the discharge. The approach allows the reconstruction of local sedimentary processes involved in alternate bar migration by combining maximum scour depths reached during a flood with frequent channel bed topography surveys and post‐flood stratigraphy. It is also possible to distinguish deposited and preserved sediments compared with sediments by‐passed during the flood. Copyright © 2011 John Wiley & Sons, Ltd.