Petrochemical Investigation of the Antique Ophiolite (Philippines): Implications on Volcanogenic Massive Sulfide and Podiform Chromitite Deposits

Abstract: The Antique ophiolite, located in Panay island (west‐central Philippines), corresponds to several tectonic slices within the suture zone between the Philippine Mobile Belt (PMB) and the North Palawan Block (NPB). It includes dismembered fragments of a basaltic sequence, dominantly pillow‐lavas with minor sheet flows, rare exposures of sheeted dikes, isotropic gabbros, subordinate layered mafic and ultramafic rock sequences and serpentinites. Most of the ophiolite units commonly occur as clasts and blocks within the serpentinites, which intrude the whole ophiolitic body, as well as, the basal conglomerate of the overlying Middle Miocene sedimentary formation. The volcanic rock sequence is characterized by chemical compositions ranging from transitional (T)‐MORB, normal (N)‐MORB and to chemistry intermediate between those of MORB and island arc basalt (IAB). The residual upper mantle sequence is harzburgitic and generally more depleted than the upper mantle underlying modern mid‐oceanic ridges. Calculations using whole‐rock and mineral compositions show that they can represent the residue of a fertile mantle source, which have undergone degrees of partial melting ranging from 9‐22.5 %. Some of the mantle samples display chondrite‐nor‐malized REE and extended multi‐element patterns suggesting enrichments in LREE, Rb, Sr and Zr, which are comparable to those found in fore‐arc peridotites from the Izu‐Bonin‐Mariana (IBM) arc system. The Antique ultramafic rocks also record relatively oxidizing mantle conditions (Δlog f_O2 (FMQ)=0.9‐3.5). As a whole, the ophiolite probably represents an agglomeration of oceanic ridge and fore‐arc crust fragments, which were juxtaposed during the Miocene collision of the PMB and the NPB. The intrusion of the serpentinites might be either coeval or subsequent to the accretion of the oceanic crust onto the fore‐arc. Volcanogenic massive sulfide (VMS) deposits occur either in or near the contact between the pillow basalts and the overlying sediments or interbedded with the sediments. The morphology of the deposits, type of metals, ore texture and the nature of the host rocks suggest that the formation of the VMS bodies was similar to the accumulation of metals around and in the subsurface of hydrothermal vents observed in modern mid‐oceanic ridge and back‐arc basin rift settings. The podiform chromitites occur as pods and subordinate layers within totally serpentinized dunite in the residual upper mantle sequence. No large coherent chromitite deposit was found since the host dunitic rocks often occur as blocks within the serpentinites. It is difficult to evaluate the original geodynamic setting of the mineralized bodies since the chemistry of the host rocks were considerably modified by alteration during their tectonic emplacement. A preliminary conclusion for Antique is that the VMS is apparently associated with a primitive tholeiitic intermediate MORB‐IAB volcanic suite, the chemistry of which is close to the calculated composition of the liquid that coexisted with the podiform chromitites.     

Fluid composition and evolution in coesite-bearing rocks (Dora-Maira massif,Western Alps): implications for element recycling during subduction

Fluid inclusions and F, Cl concentration of hydrous minerals were analysed in the coesite-pyrope quartzite, the interlayered jadeite quartzite and their country-rock gneiss from the Dora-Maira massif using a combination of microthermometry, Raman spectrometry, synchrotron X-ray microfiuorescence and electron microprobe analysis. Three populations of fluid inclusions were recognized texturally and can be related to distinct metamorphic stages. A low-salinity aqueous fluid occurs in the retrogressed country gneiss and as late secondary inclusions in jadeite quartzite and chloritized pyrope. An earlier secondary population is found in matrix quartz of the jadeite- and pyro-pe-quartzites. This population can be related to the early decompression and so to incipient breakdown of garnet into phlogopite-bearing assemblages. The inclusion fluid is highly saline (up to 84 wt% equivalent NaCl) and contains Na, Ca, Fe, Cu and Zn as major cations. In pyrope quartzite, additional K was found in these brines, which locally coexist with CO₂-rich inclusions. The oldest fluid inclusions are preserved in kyanite grains included in fresh pyrope and in pyrope itself. In pyrope, all inclusions have decrepitated and contain magnesite, an Mg-phosphate, sheet-silicate(s), a chloride and an opaque phase, with no fluid preser ved. In contrast, the kyanite inclusions in pyrope preserve primary H₂O-CO₂ low-salinity fluid inclusions, probably owing to the low compressibility of the kyanite inclusions and host garnet. In spite of in-situ re-equilibration, these inclusions can be interpreted as relics of the dehydration fluid that attended pyrope growth. These correlations between textural and chemical fluid inclusion data and metamorphic stages are consistent with the fluid composition calculated from the halogen content of different generations of phlogopite and biotite. The preservation of different fluid compositions, both in time and space, is evidence for local control and possibly origin of the fluids, in agreement with isotopic data. These results, in particular the absence of CO₂ in the jadeite quartzite, are best interpreted in terms of a fluid-melt system evolution. With increasing metamorphism, partitioning of H₂O, Na, Ca, Fe and heavy metals into melt (jadeite quartzite) and Mg, Na/K, F, CO₂ and P(?) into a residual aqueous fluid can account for depletion in Na, Ca and Fe of the pyrope quartzite. During the retrograde path, a _{H 2 O} rose as melt crystallized, generating the two populations of hypersaline and water-rich fluids that were highly reactive to pyrope. The process of fluid-melt interaction envisioned here coupled with models of melt extraction in subduction zones provides an attractive opportunity for the instantaneous ( < 1 Ma) and selective transport of elements between a downgoing slab and the overlying mantle wedge.     

Présentation d'un capteur classeur de particules à lame unique et d'un capteur absolu permettant de l'étalonner

Résumé Dans le capteur monolame à un seul jet proposé ici, l'air est projeté obliquement sur la lame de verre en amont du jet; ce capteur permet ainsi d'obtenir un prélèvement de particules classées suivant leurs dimensions sur une grande surface d'une seule lame. Par ailleurs ce capteur, en plexiglas, permet de surveiller la lame en cours de prélèvement. Les coefficients de captation pour des gouttelettes de différentes dimensions ont été déterminés en comparant les prélèvements obtenus avec le capteur monolame à ceux obtenus avec un capteur à deux jets identiques en série, réalisé afin de permettre un comptage de toutes les gouttelettes déposées sur les parois intérieures. On a de la même façon déterminé les coefficients de captation d'un cascade impactor. Les coefficients du capteur monolame et du cascade impactor sont trouvés assez peu différents, et leurs valeurs restent comprises entre 40 et 86% pour des gouttelettes de 1 à 30 de rayon. Enfin un paragraphe de cette communication indique comment peut être utilisé le capteur monolame lors de prélèvements dans un nuage.

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Summary In the monoslide and monojet impactor here proposed, the air is obliquely projected on the slide, up the jet; thus this impactor gives samples of particles classified according to their sizes on a large surface of only one slide. On another way, this impactor, made of plexiglas, allows the supervision of the slide during the sampling. The different size droplets sampling coefficients have been determined by comparison of samples obtained with an impactor having two identical jets in series, this impactor being realized in order to permit a counting of all the droplets settled in the interior walls. On the same way the sampling coefficients of a cascade impactor have been determined. The monoslide impactor coefficients and these of the cascade impactor have been found nearly identical and their values remain included between 40 and 86% for 1 to 30 radius droplets. Lastly a paragraph of this paper shows how the monoslide impactor can be used when sampling in a cloud.

     

Reflexion sur la tectonique de faille plio-quaternaire

Résumé Après avoir montré l'importance tectonique du réseau de faille plio-quaternaire, il est insisté sur son indépendance par rapport aux tectoniques antérieures, d'après les deux exemples de chaÎnes alpines et leurs bordures méditerranénnes et de la Cordillère des Andes et sa bordure pacifique.Cette tectonique, «postgéosynclinale» dans le premier cas, «postliminaire» dans le second, témoigne de mouvement en extension et non des compressions qu'on admet généralement en compensation des extensions océaniques: l'état actuel des ceintures orogéniques paraÎt donc Être l'extension, du moins dans ces deux secteurs.Le Plio-Quaternaire semble ainsi une période d'extension généralisée, au contraire de périodes antérieures où des compressions se sont manifestées dans les ceintures orogéniques.

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The Plio-Quaternary fault net, beyond its tectonic and morphologic importance, seems independent of the previous structures, as illustrated by the examples of the Alpines chaines and their Mediterranean edges and of the Andes Cordillera and its Pacific edge.Theses structures — of postgeosynclinal origin in the first case, postliminar in the second — display tensional motion, not the compressions expected as sea floor spreading compensation. Thus the present status of orogenetics belts seems to be tension at least in theses two areas.Thus the Plio-Quaternary may appear as a period of general tension, in contrast to the previous periods, some of which show compressional motion in the orogenetic belts.

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Zusammenfassung Die tektonische Bedeutung des plio-quartÄren Verwerfungsnetzes wird gezeigt. Wie aus den beiden Beispielen der Alpenketten und ihrer mediterranen Küstenlinien sowie der Andenkordillere und ihrer pazifischen Küstenlinie hervorgeht, scheint dieses Verwerfungsnetz unabhÄngig von früheren Strukturen zu sein.Diese im ersten Fall postgeosynklinale und im zweiten Fall postliminare Tektonik zeugt von Extensions- und nicht von Kompressionsbewegungen, die man im allgemeinen als Folge ozeanischer Extensionen (sea floor spreading) annimmt: der gegenwÄrtige Zustand der orogenen Gürtel scheint also Extension zu sein, zumindest in diesen beiden Abschnitten.Das Plio-QuartÄr scheint demnach eine Periode allgemeiner Extension zu sein, im Gegensatz zu vorhergehenden Perioden, wo sich in den orogenen Gürteln Kompressionen zeigten.

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- . , , . , — , , , — sea floor spreading -; , , , - , .- , , , , .

     

Un nouveau gisement de granite orbiculaire dans le Massif Central français: le granite du Signal de Randon (Lozère)

This orbicular granite contains ovoïds of an exceptional composition, comprising a core of biotite, surrounded by an envelope of plagioclase, enclosed in turn by an envelope of potassium feldspar. The latter also occurs as isolated idiomorphic megacristals between the ovoïds.Because of the spectacularly clear mineralogical relationships of the rock, it is possible to work out the order of crystallization of the minerals, the magmatic differentiation of syenitic orbicules and that of the leucogranitic groundmass with an aplito-pegmatitic texture.A magmatic process is proposed to explain the origin of the rock.

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Les déterminations de l'indice de triclinicité des feldspaths potassiques ont été effectuées par Yves Blanc, Clermont-Ferrand (diffractométrie X, d'après G. Sabatier, 1963).     

Atmospheric absorption in the O2 Schumann-Runge band spectral range and photodissociation rates in the stratosphere and mesophere

A general analysis of the absorption of the Schumann-Runge bands of molecular oxygen has been made in order to compare the various experimental and theoretical results which have been obtained for an application to the O₂ atmospheric absorption and its photodissociation in the mesosphere and stratosphere. The different values of the oscillator strengths deduced from the laboratory absorption spectra and of the predissociation linewidths used for the calculation of the absorption have been compared.Calculations based on a Voight profile of the O₂ rotational lines have led to simple formulas for atmospheric applications taking into account that the total photodissociation rate in the stratosphere depends strongly on the absorption of solar radiation in the spectral range of the O₂ Herzberg continuum. Specific examples are given.