SORPTION AND DESORPTION CHARACTERISTICS OF CADMIUM BY FOUR DIFFERENT SOILS IN NORTHEAST CHINA

1IN TR O D U C TIO NA s a persistentand toxic pollutant, cadm ium (C d) canresultin m any adverse health effects in a variety oftis-suesand organssuch asthe lung,kidney,urinary,blad-der,pancreas,breast and prostate (SA TA R U G etal.,2003).C adm ium in so…     

Tidal effects on temperature front in the Yellow Sea

Temperature front (TF) is one of the important features in the Yellow Sea, which forms in spring, thrives in summer, and fades in autumn as thermocline declines. TF intensity ⋎S _T ⋎ is defined to describe the distribution of TF. Based on the MASNUM wave-tide-circulation coupled model, temperature distribution in the Yellow Sea was simulated with and without tidal effects. Along 36°N, distribution of TF from the simulated results are compared with the observations, and a quantitative analysis is introduced to evaluate the tidal effects on the forming and maintaining processes of the TF. Tidal mixing and the circulation structure adapting to it are the main causes of the TF. Supported by the National Basic Research Program of China (No. G1999043809) and the National Science Foundation of China (No. 49736190).     

CATASTROPHIC ECO-ENVIRONMENTAL CHANGE IN THE SONGNEN PLAIN, NORTHEASTERN CHINA SINCE 1900S

Although the Songnen Plain in the northeastern China was developed relatively late in the temperate zone of the world, its eco-environment has changed greatly. This paper analyzes the changes of land cover and the rates and trends ofdesertification during the past 100 years in the Songnen Plain. According to the macroscopic analysis, we find that the eco-environment in the plain has reached to the threshold of catastrophic change since the 1950s. The Thorn Needle Catastrophic Model was used to determine and validate this conclusion. Human activities, including large-scale construction projects, such as huge dams and dikes, and excessive grazing were the primary factors contributing to regional eco-environmental catastrophe. And irrational reclamation of the wilderness also affected the eco-environmental change. The results reveal the complex human-land interactions.     

A reinterpretation of the crustal N‐isotope record: evidence for a 15N‐enriched Archean atmosphere?

A new compilation of N‐isotope and abundance data for metasedimentary rocks, and hyrdothermal micas that proxy for bulk crust, show systematic patterns. (1) δ¹⁵N values of kerogen in Precambrian cherts are more negative relative to siliciclastic counterparts, probably due to a mantle hydrothermal component. (2) There is a secular trend from average δ¹⁵N 15.3 ± 1.8‰ in Archean shales, through intermediate values in the Proterozoic, to Phanerozoic counterparts where δ¹⁵N averages +3.5‰. (3) Hydrothermal micas in metamorphic hydrothermal systems of Palaeozoic and Mesozoic age that proxy for crust have δ¹⁵N within the range of contemporaneous sedimentary rocks. (4) Hydrothermal micas track the secular trend of δ¹⁵N for kerogen from 2.7 Ga to the Phanerozoic. (5) Within Precambrian datasets δ¹⁵N does not increase with decreasing N content; accordingly, high δ¹⁵N values cannot stem either from metamorphism or form Rayleigh fractionation. (6) Previous studies show isotopic shifts during metamorphism are only +1 to +3‰ up to amphibolite facies. Values of 10–24‰ are attributed to a high δ¹⁵N Archean atmosphere, a residual signature of CI carbonaceous chondrites where δ¹⁵N is +30‰ to + 42‰.     

Automatic Determination of Stellar Atmospheric Parameters Using Neural Networks and Instance-Based Machine Learning

In this article we show how machine learning methods can beeffectively applied to the problem of automatically predictingstellar atmospheric parameters from spectral information, a veryimportant problem in stellar astronomy. We apply feedforwardneural networks, Kohonen's self-organizing maps andlocally-weighted regression to predict the stellar atmosphericparameters effective temperature, surface gravity and metallicityfrom spectral indices. Our experimental results show that thethree methods are capable of predicting the parameters with verygood accuracy. Locally weighted regression gives slightly betterresults than the other methods using the original dataset asinput, while self-organizing maps outperform the other methods when significant amounts of noise are added. We also implemented a heterogeneous ensemble of predictors, combining the results given by the three algorithms. This ensemble yields better results than any of the three algorithms alone, using both the original and the noisy data.     

Accretion disk spectra of super-luminal jet sources and ultra-luminous compact X-ray sources in nearby spiral galaxies

The Ultra-luminous Compact X-ray Sources (ULXs)in nearby spiral galaxies and the Galactic super-luminaljet sources sharethe common spectral characteristic that they haveextremely high disk temperatures which cannot be explainedin the framework of the standard accretion disk modelin the Schwarzschild metric. We have calculated an extreme Kerr disk model to examine if the Kerr disk model can instead explain the observed `too hot' accretion disk spectra.We found that the Kerr disk spectrum becomes significantly hardercompared to the Schwarzschild disk only when the disk is highlyinclined.For super-luminal jet sources, which are known to beinclined systems, the Kerr disk model may thuswork if we choose proper values for the black hole angular momentum. For the ULXs, however, the Kerr disk interpretation will be problematic,as is is highly unlikely that their accretion disks are preferentiallyinclined.     

Low‐energy helium ion irradiation‐induced amorphization and chemical changes in olivine: Insights for silicate dust evolution in the interstellar medium

Abstract— We present the results of irradiation experiments aimed at understanding the structural and chemical evolution of silicate grains in the interstellar medium. A series of He+ irradiation experiments have been performed on ultra‐thin olivine, (Mg,Fe)₂SiO₄, samples having a high surface/volume (S/V) ratio, comparable to the expected S/V ratio of interstellar dust. The energies and fluences of the helium ions used in this study have been chosen to simulate the irradiation of interstellar dust grains in supernovae shock waves. The samples were mainly studied using analytical transmission electron microscopy. Our results show that olivine is amorphized by low‐energy ion irradiation. Changes in composition are also observed. In particular, irradiation leads to a decrease of the atomic ratios O/Si and Mg/Si as determined by x‐ray photoelectron spectroscopy and by x‐ray energy dispersive spectroscopy. This chemical evolution is due to the differential sputtering of atoms near the surfaces. We also observe a reduction process resulting in the formation of metallic iron. The use of very thin samples emphasizes the role of surface/volume ratio and thus the importance of the particle size in the irradiation‐induced effects. These results allow us to account qualitatively for the observed properties of interstellar grains in different environments, that is, at different stages of their evolution: chemical and structural evolution in the interstellar medium, from olivine to pyroxene‐type and from crystalline to amorphous silicates, porosity of cometary grains as well as the formation of metallic inclusions in silicates.     

Evidence of climatic warming in the southern Urals region derived from borehole temperatures and meteorological data

Thirty borehole temperature–depth profiles in the central and southern Urals, Russia were scrutinized for evidence of ground surface temperature histories. We explored two inversion schemes: a simple ramp inversion in which solutions are parameterized in terms of an onset time and magnitude of change and a more sophisticated functional space inverse algorithm in which the functional form of the solution is left unspecified. To enhance and potentially identify latitudinal differences in the ground surface temperature signal, we subdivided the data into three groups based on geographic proximity and simultaneously inverted the borehole temperature–depth logs. The simultaneous inversions highlighted 13 temperature–depth logs that could not both fit a common ground surface temperature history and a priori models within reasonable bounds. Our results confirm that this is an effective way to reduce site-specific noise from an ensemble of boreholes. Each inversion scheme gives comparable results indicating locally variable warming on the order of 1°C starting between 1800 and 1900 AD. Similarly surface air temperature records from 12 nearby meteorological stations exhibit locally variable warming also on the order of 1°C of warming during the 20th century. To explore the degree to which borehole temperatures and surface air temperature (SAT) time series are responding to the same signal, we average the SAT data into the same three groups and used these averages as a forcing function at the Earth's surface to generate synthetic transient temperature profiles. Root mean square (RMS) misfits between these synthetic temperature profiles and averaged temperature–depth profiles are low, suggesting that first-order curvature in borehole temperatures and variations in SAT records are correlated.     

Radar observations of Itokawa in 2004 and improved shape estimation

Abstract— We present June 2004 radar images of asteroid 25143 Itokawa (1998 SF36) that improve upon the longitude‐latitude coverage of images obtained in 2001 by Ostro et al. (2004) and use the 2001–2004 data to refine that paper's constraints on Itokawa's shape. The 2004 images, the first of the asteroid's southern side, look distinctly different from the 2001 images, revealing leading edges that are much more curved and rugged than the nearly convex leading edges seen at northern latitudes in 2001. Itokawa is shaped like a slightly asymmetrical, bent, lumpy ellipsoid with dimensions along the principal axes within 10% of 594 times 320 times 288 m. To illustrate the uncertainty space associated with shape reconstruction from images with suboptimal orientational coverage, we present two alternative three‐dimensional models of the object.