Experimental study of the effect of pH on the kinetics of montmorillonite dissolution at 25 °C

The effect of pH on the kinetics of smectite (K-montmorillonite) dissolution was investigated at 25 °C in batch and stirred flow-through reactors over the pH range of 1-13.5, in KNO₃ solutions. Dissolution rates were obtained based on the release of Si and Al at steady-state under far from equilibrium conditions. Dissolution was non-stoichiometric between pH 5 and 10, due to adsorption/precipitation of Al. Dissolution rates computed from batch and flow-through experiments were consistent, irrespective of the Si and Al concentrations. Sample pre-treatment and the interlayer cation do not affect the steady-state dissolution rate or stoichiometry of cation release. The rate dependence on pH can be described by:

     

Tectonic and oceanographic control of sedimentary patterns in a small oceanic basin: Dove Basin (Scotia Sea,Antarctica)

Dove Basin, a small oceanic domain located within the southern Scotia Sea, evidences a complex tectonic evolution linked to the development of the Scotia Arc. The basin also straddles the junction between the main Southern Ocean water masses: the Antarctic Circumpolar Current (ACC), the Southeast Pacific Deep Water (SPDW) and the Weddell Sea Deep Water (WSDW). Analysis of multichannel seismic reflection profiles, together with swath bathymetry data, reveals the main structure and sediment distribution of the basin, allowing a reconstruction of the tectonostratigraphic evolution of the basin and assessment of the main bottom water flows that influenced its depositional development. Sediment dispersed in the basin was largely influenced by gravity‐driven transport from adjacent continental margins, later modified by deep bottom currents. Sediments derived from melting icebergs and extensive ice sheets also contributed to a fraction of the basin deposits. We identify four stages in the basin evolution which – based on regional age assumptions – took place during the early Miocene, middle Miocene, late Miocene–early Pliocene and late Pliocene–Quaternary. The onsets of the ACC flow in Dove Basin during the early Miocene, the WSDW flow during the middle Miocene, and the SPDW during the late Miocene were influenced by tectonic events that facilitated the opening of new oceanic gateways in the region. The analysis of Dove Basin reveals that tectonics is a primary factor influencing its sedimentary stacking patterns, the structural development of new oceanic gateways permitting the inception of deep‐water flows that have since controlled the sedimentary processes.     

Geochemical modeling and low-frequency geoelectrical methods to evaluate the impact of an open dump in arid and deltaic environments

In Mexico, open dumps that are maintained by the municipality but provide no covering of waste are not uncommon. Further, disposal at these sites is often performed by burning. The aim of this study was to determine the leachate plume from an open dump located in a depositional deltaic environment, with arid climate, low rainfall and where the water table is about 2 m below the surface. The methodology comprised analysis of groundwater monitoring wells and geophysical and geochemical prospecting techniques. The 3D geoelectric interpretation shows a typical area of these depositional environments with low resistive values (10–20 Ω-m) associated with the presence of sands and clays interbedded. However, there is a very low resistivity zone associated with the dump’s impact which reaches values below 5 Ω-m, and it is located where the disposal and burning of wastes occurred. Another zone with values above 16 Ω-m appears as a limit for the advance of the saline. This is interpreted as a sandy lenses area. These sandy lenses with higher porosity transport aquifer’s water. Thus the dump is in direct contact by this conduct with clean groundwater. Piper diagrams constructed with the chemical data analysis reveal that the groundwater in the area corresponds to the chlorinated and/or sulfated sodium type, showing the impact caused by the dump. The monitoring well (NP8, on-site) with the highest dissolved solids content behaves anomalously and belongs to the more conductive zone according to the geoelectric profiles. The subsoil geochemical behavior is influenced by the seasonal water table variations provoking the dissolution of burned and unburned wastes, but the effects of slow flows in the direction of the regional flow are not discarded. Although the most impacted area within the dump is characterized to a depth of 10 m, there is a slow flow in the direction of the regional flow that has been moving pollutants out of the dumpsite during its almost 20 years of operation. The results of this study provide valuable information for the authorities to carry out an appropriate restoration project.     

Spatial–temporal patterns of cloud-to-ground lightning over the northwest Iberian Peninsula during the period 2010–2015

The spatial–temporal patterns of cloud-to-ground (CG) lightning covering the period 2010–2015 over the northwest Iberian Peninsula were investigated. The analysis conducted employed three main methods: the circulation weather types developed by Jenkinson and Collison, the fit of a generalized additive model (GAM) for geographic variables, and the use of a concentration index for the ratio of lightning strikes and thunderstorm days. The main activity in the summer months can be attributed to situations with eastern or anticyclonic flow due to convection by insolation. In winter, lightning proves to have a frontal origin and is mainly associated with western or cyclonic flow situations which occur with advections of air masses of maritime origin. The largest number of CG discharges occurs under eastern flow and their hybrids with anticyclonic situations. Thunderstorms with greater CG lightning activity, highlighted by a higher concentration index, are located in areas with a higher density of lightning strikes, above all in mountainous areas away from the sea. The modeling of lightning density with geographic variables shows the positive influence of altitude and, particularly, distance to the sea, with nonlinear relationships due to the complex orography of the region. Likewise, areas with convex topography receive more lightning strikes than concave ones, a relation which has been demonstrated for the first time from a GAM.     

Review of the Cambrian volcanic activity in Morocco: geochemical fingerprints and geotectonic implications for the rifting of West Gondwana

International Journal of Earth Sciences - Volcanic activities related to the opening of a Cambrian rift in Morocco were widespread from the Fortunian to the Cambrian Epoch 3. Numerous data are...     

A parsimonious distributed model for simulating transient water flow in a high-relief karst aquifer

A mathematical model of a highly heterogeneous functioning karst aquifer is described. The aquifer is in a high-relief karst massif and, as is common for such locations, data are scarce and there are no borehole, piezometer or pumping-test data. The scarcity of data in this case required a parsimonious approach to ensure that the level of complexity of the model was commensurate with the amount, type and quality of the available data. Parsimony also requires the model to include the minimum essential components that account adequately for the data, which in this and similar cases are the functional dualities of the karst system: duality in recharge, flow and discharge. The model is three-dimensional (3D) in the sense that the aquifer is discretized into 3D voxels, although the flow is one-dimensional (1D) and vertical in the vadose zone, and horizontal and two-dimensional (2D) in the saturated zone. The parsimonious model was designed by coupling a 1D unsaturated gravity-driven flow along the vertical (along each column of voxels that discretize the aquifer) and a 2D unconfined Darcy flow in the saturated zone. In the context of this type of aquifer, preferential recharge through the network of karst conduits implies a rapid rise in the water table, the location and extension of which are model parameters. The karst springs are simulated by drains. The methodology, which is completely general, is illustrated by application to the karst aquifer in the Sierra de las Nieves mountains in southern Spain.     

Holocene environmental change on the Atlantic coast of NW Iberia as inferred from the Ponzos wetland sequence

The intertidal environment of the Ponzos beach (NW Iberian Peninsula) hosts a sedimentary sequence (including large wood fragments) deposited during the first half of the Holocene in a hygrophilous continental wetland. Pollen and macrofossil data alongside radiocarbon dating allow reconstruction of the changes that occurred during the Early and Middle Holocene in the landscape of the NW Iberia coastal lowlands, as well as the local wetland plant communities, in response to the climate variations and the eustatic sea-level oscillations. The sequence represents the evolution of a coastal wetland from its initial phases as a hygrophilous wetland towards the subsequent installation of a freshwater lagoon. Pollen data show the dominant role of Atlantic (mainly deciduous) woody taxa, the scarcity of conifers and the lack of Mediterranean elements in the coastal landscapes around the Ponzos site. The presence and abundance of some taxa such as deciduous Quercus, Castanea, Fagus, Tilia and Ulmus during the Early Holocene provides further support for the occurrence of glacial refuges in the Cantabrian-Atlantic area during the Last Glaciation. The diverse vegetation that characterizes the modern landscapes in this territory established later, spreading from these glacial reservoirs of biodiversity. In this sense, the notable and early presence of Fagus at the beginning of the Holocene, a tree also previously recorded during several phases of the Last Glacial Cycle on the NW Iberia coasts, is noteworthy. In addition, during the Early and Middle Holocene are recorded other trees that are currently extirpated as natural taxa in the area, such as Pinus, Tilia and Carpinus.