Pollution history and recovery of a boreal lake exposed to a heavy bleached pulping effluent load

We examined the effects of heavy pulp mill discharges on the Lake Lievestuoreenjärvi ecosystem and the later recovery of diatom and chironomid communities from age-dated short core samples. Beginning in 1927 the lake received a heavy effluent load from a sulphite pulp mill. Except for the recession during the Second World War and the temporary closure of the mill from 1967 to 1971, the industrial load, containing large quantities of nutrients, organic matter and toxic compounds, increased continuously. In the early 1980s, laboratory documents were falsified by the directors of the mill and the systematic illegal effluent overload led to a collapse of the whole lake ecosystem. In 1985, the outdated plant was finally closed down. Based on the assessment of chemical properties and biological remains of the sediment, we distinguished five developmental phases in the ecological state of the lake. In the pre-industrial phase, the pelagic and profundal benthic communities were dominated by species preferring ultraoligotrophic or oligotrophic lakes. Concomitant with the increasing discharge and deposition of chlorine compounds, resin acids, and mercury, as well as strong acidity and hypolimnetic and epilimnetic anoxia, the ecological status changed in a short period from excellent to bad. Finally, in the early 1960s, the majority of the lake was virtually dead and the aquatic life survived only in the uppermost littoral zone. Since 1985, a fast recovery in the water quality has led to a strong, but temporary eutrophy in pelagic communities. The main peak of eutrophication was caused by the invasion of a species new to the lake,Aulacoseira granulata var.angustissima. Later, the pelagic communities shifted towards oligotrophy, but the original, pre-industrial status has not been re-established. The profundal benthic communities have not achieved the pre-industrial structure, but at present indicate mesotrophy.     

Magmatic zircon oxygen isotopes of 1.88–1.87 Ga orogenic and 1.65–1.54 Ga anorogenic magmatism in Finland

Summary Oxygen isotope ratios of igneous zircon from magmatic rocks in Finland provide insights into the evolution and growth of the Precambrian crust during the Svecofennian orogeny. These data preserve magmatic δ¹⁸O values and correlate with major discontinuities in the lower crust. Oxygen isotope ratios of zircon across the 1.88–1.87 Ga Central Finland granitoid complex (CFGC) range from 5.50‰ to 6.84‰, except for three plutons in contact with the adjacent greenstone and metasedimentary belts (δ¹⁸O(Zrc) = 7.60‰–7.78‰). There is a systematic variation in δ¹⁸O(Zrc) with respect to geographic location in the CFGC, ranging from 6.60±0.23‰ (σ) in the northeast to 5.90±0.40‰ in the west-southwest. These values correlate with a change in crustal thickness and shift in geochemical composition. The oxygen isotope composition of the 1.65–1.54 Ga rapakivi granites and related rocks in southern Finland show a decreasing trend from north to south, independent of their emplacement age. The southern anorogenic granite group has an average δ¹⁸O in zircon of 6.14±0.07‰ and the northern anorogenic group has an average δ¹⁸O in zircon of 8.14±0.59‰. This difference reflects the boundary between island arc terrains accreted during the Paleoproterozoic. Deceased     

Luminescence dating of ice‐marginal deposits in northern Germany: evidence for repeated glaciations during the Middle Pleistocene (MIS 12 to MIS 6)

The exact number, extent and chronology of the Middle Pleistocene Elsterian and Saalian glaciations in northern Central Europe are still controversial. This study presents new luminescence data from Middle Pleistocene ice‐marginal deposits in northern Germany, giving evidence for repeated glaciations during the Middle Pleistocene (MIS 12 to MIS 6). The study area is located in the Leine valley south of the North German Lowlands. The data set includes digital elevation models, high‐resolution shear wave seismic profiles, outcrop and borehole data integrated into a 3D subsurface model to reconstruct the bedrock relief surface. For numerical age determination, we performed luminescence dating on 12 ice‐marginal and two fluvial samples. Luminescence ages of ice‐marginal deposits point to at least two ice advances during MIS 12 and MIS 10 with ages ranging from 461±34 to 421±25 ka and from 376±27 to 337±21 ka. The bedrock relief model and different generations of striations indicate that the older ice advance came from the north and the younger one from the northeast. During rapid ice‐margin retreat, subglacial overdeepenings were filled with glaciolacustrine deposits, partly rich in re‐worked Tertiary lignite and amber. During MIS 8 and MIS 6, the study area may have been affected by two ice advances. Luminescence ages of glaciolacustrine delta deposits point to a deposition during MIS 8 or early MIS 6, and late MIS 6 (250±20 to 161±10 ka). The maximum extent of both the Elsterian (MIS 12 and MIS 10) and Saalian glaciations (MIS 8? and MIS 6) approximately reached the same position in the Leine valley and was probably controlled by the formation of deep proglacial lakes in front of the ice sheets, preventing a further southward advance.     

Energy partitioning over a semi‐arid shrubland in northern China

During the last decade, the widely distributed shrublands in northern China have shown significant signs of recovery from desertification, the result of widespread conservation practices. However, to support the current efforts in conservation, more knowledge is needed on surface energy partitioning and its biophysical controls. Using eddy‐covariance measurements made over a semi‐arid shrubland in northwest China in 2012, we examined how surface energy‐balance components vary on diurnal and seasonal scales, and how biophysical factors control bulk surface parameters and energy exchange. Sensible heat flux (H) exceeded latent heat flux (λE) during most of the year, resulting in an annual Bowen ratio (β, i.e. H/λE) of 2.0. λE exceeded H only in mid‐summer when frequent rainfall co‐occurred with the seasonal peak in leaf area index (LAI). Evapotranspiration reached a daily maximum of 3.3 mm day^?1, and summed to 283 mm yr^?1. The evaporative fraction (EF, i.e. λE/R_n), Priestley–Taylor coefficient (α), surface conductance (g_s) and decoupling coefficient (Ω) were all positively correlated with soil water content (SWC) and LAI. The direct enhancement of λE by high vapour pressure deficit (VPD) was buffered by a concurrent suppression of g_s. The g_s played a direct role in controlling EF and α by mediating the effects of LAI, SWC and VPD. Our results highlight the importance of adaptive plant responses to water scarcity in regulating ecosystem energy partitioning, and suggest an important role for revegetation in the reversal of desertification in semi‐arid areas. Copyright © 2015 John Wiley & Sons, Ltd.     

Diffusive mass exchange of non‐reactive substances in dual‐porosity porous systems – column experiments under saturated conditions

Diffusive mass exchange into immobile water regions within heterogeneous porous aquifers influences the fate of solutes. The percentage of immobile water is often unidentified in natural aquifers though. Hence, the mathematical prediction of solute transport in such heterogeneous aquifers remains challenging. The objective of this study was to find a simple analytical model approach that allows quantifying properties of mobile and immobile water regions and the portion of immobile water in a porous system. Therefore, the Single Fissure Dispersion Model (SFDM), which takes into account diffusive mass exchange between mobile and immobile water zones, was applied to model transport in well‐defined saturated dual‐porosity column experiments. Direct and indirect model validation was performed by running experiments at different flow velocities and using conservative tracer with different molecular diffusion coefficients. In another column setup, immobile water regions were randomly distributed to test the model applicability and to determine the portion of immobile water. In all setups, the tracer concentration curves showed differences in normalized maximum peak concentration, tailing and mass recovery according to their diffusion coefficients. These findings were more pronounced at lower flow rates (larger flow times) indicating the dependency of diffusive mass exchange into immobile water regions on tracers' molecular diffusion coefficients. The SFDM simulated all data with high model efficiency. Successful model validation supported the physical meaning of fitted model parameters. This study showed that the SFDM, developed for fissured aquifers, is applicable in porous media and can be used to determine porosity and volume of regions with immobile water. Copyright © 2015 John Wiley & Sons, Ltd.     

Correction to: Extreme waves induced by cyclone Nargis at Myanmar coast: numerical modeling versus satellite observations

Natural Hazards - A correction to this paper has been published: https://doi.org/10.1007/s11069-021-04687-9     

Synchronous pattern of moisture availability on the southern Tibetan Plateau since 17.5 cal. ka BP – the Tangra Yumco lake sediment record

A possible asynchronicity of the spatial and temporal moisture availability on the Tibetan Plateau has been a controversial subject of discussion in recent years. Here we present the first attempt to systematically investigate possible spatial and temporal variations in moisture availability by examining two lakes, Tangra Yumco and Nam Co, on an east–west transect on the southern Tibetan Plateau using identical proxies for palaeoenvironmental reconstruction. In this study, an independent record from Tangra Yumco was analysed applying a multi‐proxy approach to reconstruct variations in moisture availability since the Lateglacial. Results were subsequently compared with previously published records from Nam Co and additional records from Tso Moriri (northwestern Himalaya) and Naleng Co (southeastern Tibetan Plateau). Our results show that Tangra Yumco was at least partially ice covered prior to 17.1 cal. ka BP. A temperature rise after 17.1 cal. ka BP probably resulted in thawing of the permafrost. At 16.0 cal. ka BP moisture availability increased, representing an initial monsoonal intensification. Warmer conditions between 13.0 and 12.4 cal. ka BP and cooler conditions between 12.4 cal. ka BP and the onset of the Holocene reflect the Bølling‐Allerød and Younger Dryas. At the onset of the Holocene moisture availability rapidly increased, with moisture highest prior to 8.5 cal. ka BP when temperatures were also highest. After 8.5 cal. ka BP the moisture availability gradually decreased and showed only minor amplitude variations. These findings are consistent with the records from large lakes like Nam Co, Tso Moriri, and Naleng Co, revealing a synchronous pattern of moisture availability on the southern Tibetan Plateau.     

Local air temperature tolerance: a sensible basis for estimating climate variability

The customary representation of climate using sample moments is generally biased due to the noticeably nonstationary behaviour of many climate series. In this study, we introduce a moment-free climate representation based on a statistical model fitted to a long-term daily air temperature anomaly series. This model allows us to separate the climate and weather scale variability in the series. As a result, the climate scale can be characterized using the mean annual cycle of series and local air temperature tolerance, where the latter is computed using the fitted model. The representation of weather scale variability is specified using the frequency and the range of outliers based on the tolerance. The scheme is illustrated using five long-term air temperature records observed by different European meteorological stations.