Water partitioning between mantle minerals from peridotite xenoliths

The speciation and amount of water dissolved in nominally anhydrous silicates comprising eight different mantle xenoliths has been quantified using synchrotron micro-FTIR spectroscopy. Samples studied are from six geographic localities and represent a cross-section of the major upper mantle lithologies from a variety of tectonic settings. Clinopyroxene contains between 342 and 413 ppm H₂O. Orthopyroxene, olivine and garnet contain 169–201, 3–54 and 0 to <3 ppm H₂O, respectively. Pyroxenes water contents and the distribution of water between ortho- and clinopyroxene is identical regardless of sample mineralogy (D _water^cpx/opx = 2.1 ± 0.1). The total water contents of each xenolith are remarkably similar (113 ± 14 ppm H₂O). High-resolution spectroscopic traverses show that the concentration and speciation of hydrous defects dissolved in each phase are spatially homogeneous within individual crystals and identical in different crystals interspersed throughout the xenolith. These results suggest that the amount of water dissolved in the silicate phases is in partial equilibrium with the transporting melt. Other features indicate that xenoliths have also preserved OH signatures of equilibrium with the mantle source region: Hydroxyl stretching modes in clinopyroxene show that garnet lherzolites re-equilibrated under more reducing conditions than spinel lherzolites. The distribution of water between pyroxenes and olivine differs according to xenolith mineralogy. The distribution of water between clinopyroxene and olivine from garnet peridotites (D _water^cpx/oliv(gnt) = 22.2 ± 24.1) is a factor of four greater than mineral pairs from spinel-bearing xenoliths (D _water^cpx/oliv(sp) = 88.1 ± 47.8). Such an increase in olivine water contents at the spinel to garnet transition is likely a global phenomenon and this discontinuity could lead to a reduction of the upper mantle viscosity by 0.2–0.7 log units and a reduction of its electrical resistivity by a factor of 0.5–0.8 log units.     

Weakening AMOC connects Equatorial Atlantic and Pacific interannual variability

Observations indicate that since the 1970s Equatorial Atlantic sea surface temperature (SST) variations in boreal summer tend to modulate El Niño in the following seasons, indicating that the Atlantic Ocean can have importance for predicting the El Niño–Southern Oscillation (ENSO). The cause of the change in the recent decades remains unknown. Here we show that in the Bergen Climate Model (BCM), a freshwater forced weakening of the Atlantic meridional overturning circulation (AMOC) results in a strengthening of the relation between the Atlantic and the Pacific similar to that observed since the 1970s. During the weakening AMOC phase, SST and precipitation increase in the central Equatorial Atlantic, while the mean state of the Pacific does not change significantly. In the Equatorial Atlantic the SST variability has also increased, with a peak in variability in boreal summer. In addition, the characteristic timescales of ENSO variability is shifted towards higher frequencies. The BCM version used here is flux-adjusted, and hence Atlantic variability is realistic in contrast to in many other models. These results indicate that in the BCM a weakening AMOC can change the mean background state of the Tropical Atlantic surface conditions, enhancing Equatorial Atlantic variability, and resulting in a stronger relationship between the Tropical Atlantic and Pacific Oceans. This in turn alters the variability in the Pacific.     

Glacial and climate history of the last 24 000 years in the Polar Ural Mountains,Arctic Russia,inferred from partly varved lake sediments

We present a well‐dated, high‐resolution and continuous sediment record spanning the last c. 24 000 years from lake Bolshoye Shchuchye located in the Polar Ural Mountains, Arctic Russia. This is the first continuous sediment succession reaching back into the Last Glacial Maximum (LGM) ever retrieved from this region. We reconstruct the glacial and climate history in the area since the LGM based on sedimentological and geochemical analysis of a 24‐m‐long sediment core. A robust chronology was established using a combination of AMS ¹⁴C‐dating, the position of the Vedde Ash and varve counting. The varved part of the sediment core spans across the LGM from 24 to 18.7 cal. ka BP. We conclude that the lake basin remained ice‐free throughout the LGM, but that mountain glaciers were present in the lake catchment. A decrease in both glacial varve preservation and sedimentation rate suggests that these glaciers started to retreat c. 18.7 cal. ka BP and had disappeared from the catchment by 14.35 cal. ka BP. There are no indications of glacier regrowth during the Younger Dryas. We infer a distinct climatic amelioration following the onset of the Holocene and an Early to Middle Holocene thermal optimum between 10–5 cal. ka BP. Our results provide a long‐awaited continuous and high‐resolution record of past climate that supplements the existing, more fragmentary data from moraines and exposed strata along river banks and coastal cliffs around the Russian Arctic.     

Improved confidence in regional climate model simulations of precipitation evaluated using drought statistics from the ENSEMBLES models

An ensemble of regional climate model simulations from the European framework project ENSEMBLES is compared with observations of low precipitation events across a number of European regions. We characterize precipitation deficits in terms of two drought indices, the Standardized Precipitation Index and the self-calibrated Palmer Drought Severity Index. Models that robustly describe the observations for the period 1961–2000 in given regions are identified and an assessment of the overall performance of the ensemble is provided. The results show that in general, models capture the most severe drought events and that the ensemble mean model also performs well. Some regions that appear to be more problematic to simulate well are also identified. These are relatively small regions and have rather complex topographical features. The analysis suggests that assessment of future drought occurrence based on climate change experiments in general would appear to be robust. But due to the heterogeneous and often fine-scaled structure of drought occurrence, quantitative results should be used with great care, particularly in regions with complex terrain and limited information about past drought occurrence.     

Lake stratigraphy implies an 80 000 yr delayed melting of buried dead ice in northern Russia

Sediment cores from lakes Kormovoye and Oshkoty in the glaciated region of the Pechora Lowland, northern Russia, reveal sediment gravity flow deposits overlain by lacustrine mud and gyttja. The sediments were deposited mainly during melting of buried glacier ice beneath the lakes. In Lake Kormovoye, differential melting of dead ice caused the lake bottom to subside at different places at different times, resulting in sedimentation and erosion occurring only some few metres apart and at shifting locations, as further melting caused inversion of the lake bottom. Basal radiocarbon dates from the two lakes, ranging between 13 and 9 ka, match with basal dates from other lakes in the Pechora Lowland as well as melting of ice‐wedges. This indicates that buried glacier ice has survived for ca. 80 000 years from the last glaciation of this area at 90 ka until about 13 ka when a warmer climate caused melting of permafrost and buried glacier ice, forming numerous lakes and a fresh‐looking glacial landscape. Copyright © 2003 John Wiley & Sons, Ltd.     

Huge Ice‐age lakes in Russia

During an early phase of the Last Ice Age (Weichselian, Valdaian), about 90 000 yr ago, an ice sheet formed over the shallow Barents and Kara seas. The ice front advanced on to mainland Russia and blocked the north‐flowing rivers (Yenissei, Ob, Pechora, Dvina and others) that supply most of the freshwater to the Arctic Ocean. The result was that large ice‐dammed lakes were formed between the ice sheet in the north and the continental water divides to the south. Here we present reconstructions and calculations of the areas and volumes of these lakes. The lake on the West Siberian Plain was nearly twice as large as the largest lake on Earth today. The well‐mapped Lake Komi in northeast Europe and a postulated lake in the White Sea Basin would also rank before the present‐day third largest lake. The lakes overflowed towards the south and thus the drainage of much of the Eurasian continent was reversed. The result was a major change in the water balance on the continent, decreased freshwater supply to the Arctic Ocean, and increased freshwater flow to the Aral, Caspian, Black and Baltic seas. A sudden outburst of the lakes' water to the Arctic Ocean when the ice sheet thinned is postulated. Copyright © 2001 John Wiley & Sons, Ltd.     

Flow and sediment regimes at tributary junctions on a regulated river: impact on sediment residence time and benthic macroinvertebrate communities

Tributaries may either ameliorate or exacerbate the geomorphic and ecologic impacts of flow regulation by altering the flux of water and sediment into the flow‐regulated mainstem. To capture the effects of tributary influences on a flow regulated river, long‐term discharge and cross‐sectional data are used to assess the geomorphic and hydrologic impacts of impoundment. In addition, the use of the short‐lived cosmogenic radioisotope ⁷Be (half‐life 53·4 days) to link sediment transport dynamics to benthic macroinvertebrate community structure is evaluated. It is found that the ⁷Be activity of transitional bed load sediment is highly seasonal and reflects both variations in activity of sediment sources and limited sediment residence time within the junction. Benthic communities also exhibit a strong seasonal variability. In the spring, neither the ⁷Be activity of the sediment, nor benthic communities exhibit clear relationships with sample site location. In contrast, during the late summer the ratio of Ephemeroptera (mayflies)/Trichoptera (caddisflies) decreased significantly below tributary junctions. This decrease in benthic community ratio was driven by increases in caddisfly abundance and was strongly correlated with the presence of recently ⁷Be tagged transitional bedload sediment. These observations are probably associated with the presence of coarse, stable, and unembedded substrate downstream of tributaries and the rapid turnover of sediment that may also be associated with a rapid flux in nutrients or seston. The results show that tributaries are impacting the flow‐regulated mainstem and that these impacts are reflected in the benthic community structure and in the ⁷Be activity of transitional bed load sediment. Moreover, the observed reduction in competence and capacity of the mainstem following flood control suggests that these spatial discontinuities may be a consequence of impoundment. Copyright © 2008 John Wiley & Sons, Ltd.     

Dynamics of phosphorus compounds in a lowland river system: Importance of retention and non-point sources

Intensive measurements of the fluxes of phosphorus (P) and of P retention were carried out in a Danish lowland watershed (Gjern Å) during two hydrological years (June 1987 to May 1989). Seasonal and short-term variations of P concentrations were measured by intensive automatic sampling covering P fluxes from the entire Gjern Å watershed and two subcatchments: the Gelbæk and Lake Søbygård. Moreover, infrequent sampling was performed in all major tributaries of the river system. Transport of P compounds (dissolved and particulate P) exposed a seasonal pattern which was highly affected by flow conditions, instream processes, as well as point and non-point sources. Stormflow P transport during the two study years (1987-8 and 1988-9) constituted 56 and 61% in the Gelbæk, respectively, compared with 25 and 23% in the Gjern Å, respectively. Particulate P transport in the Gelbæk constituted 56 and 75% of annual total P transport during the two years compared with 77 and 75% in the Gjern Å. The magnitude of monthly baseflow and stormflow total P loads was significantly correlated with the mean monthly discharge during baseflow and stormflow in the Gelbæk, whereas only stormflow loads were correlated to discharge in the Gjern Å. In situ measurements of retention showed that the maximum amount of P stored in the Gelbæk during summer (June to August) was 22gPm^?2 (1988) compared with 27gPm^?2 (1987) in the Gjern Å. Lake Søbygård was a P source during summer but a P sink during winter and on an annual basis the net P released was 810 and 1420 kg, which corresponded to 7 and 20% of the annual P export from the watershed, respectively. Retention constituted about 30% of gross P transport in the Gelbæk during summer compared with 20% in the Gjern Å. Resuspension of retained P during stormflows in September 1987 constituted 94% of the stormflow P transport and 54% of the total P transport. Monthly total P and dissolved reactive P (DRP) mass balances for the main channel of the Gjern Å revealed a significant DRP retention over 17 months (p < 0.05) caused by P adsorption on sediments and biological uptake. On an annual basis the main channel was a sink of DRP (1220 and 1660 kg P) but a source of total P (3440 and 1000 kg P). implying that the channel is an important source of particulate P. Bank erosion proved to be a significant P source in the main channel of Gjern Å, whereas P delivery from soil erosion was possibly of minor importance. The annual non-point P export from two intensively sampled catchments was significantly higher (0.89 and 0.45 kg Pha^?1 yr^?1) than from the five extensively sampled subbasins (0.43 and 0.17 kg Pha^?1 yr^?1). No significant relationship could be established between non-point P export and the proportion of arable land and soil type. Only for the wet year of 1987-8 was a significant relationship established between non-point P export and the P load from scattered dwellings outside sewage areas in five subbasins.     

Coastal eutrophication and the Danish national aquatic monitoring and assessment program

Nutrient over-enrichment and cultural eutrophication are significant problems in the Danish marine environment. Symptoms of eutrophication include periods of hypoxia and anoxia in bottom waters, death of benthic-dwelling organisms during anoxia, long-term reductions in the depth distribution of macrophyte communities, changes in the species composition of macrophyte communities, and increases in reports of harmful algal blooms. In 1987 the Action Plan on the Aquatic Environment was adopted to combat nutrient pollution of the aquatic environment with the overall goal of reducing nitrogen loads by 50% and point source phosphorus loads by 80%. The Danish Aquatic Nation-wide Monitoring Program was begun in 1988 in order to describe the status of point sources (industry, sewage treatment plants, stormwater outfalls, scattered dwellings, and fish farms), ground water, springs, agricultural watersheds, streams, lakes, atmospheric deposition, and the marine environment. Another important aspect of the program was to document the effects on the aquatic environment of the measures and investments taken for nutrient reduction as outlined in the Action Plan. The monitoring program should determine if reductions in nutrients are achieved by the measures taken and should help decision makers choose appropriate additional measures to fulfill the objectives. Coordination with international programs and commissions is an important component of the monitoring program to meet internationally agreed upon reductions in nutrient inputs. The future and direction of the Danish National Aquatic Monitoring and Assessment Program will be to a large extent shaped by both the Water Framework Directive and Habitat Directive adopted by the European Union.