Metasomatic oxidation of upper mantle periodotite

Examination of Fe³⁺ in metasomatized spinel peridotite xenoliths reveals new information about metasomatic redox processes. Composite xenoliths from Dish Hill, California possess remnants of magmatic dikes which were the sources of the silicate fluids responsible for metasomatism of the peridotite part of the same xenoliths. Mössbauer spectra of mineral separates taken at several distances from the dike remnants provide data on Fe³⁺ contents of minerals in the metasomatized peridotite. Clinopyroxenes contain 33% of total iron (Fe_T) as Fe³⁺ (Fe³⁺/Fe_T=0.33); orthopyroxenes contain 0.06–0.09 Fe³⁺/Fe_T; spinels contain 0.30–0.40 Fe³⁺/Fe_T; olivines contain 0.01–0.06 Fe³⁺/Fe_T; and metasomatic amphibole in the peridotite contains 0.85–0.90 Fe³⁺/Fe_T. In each mineral, Fe³⁺ and Fe²⁺ cations per formula unit (p.f.u.) decrease with distance from the dike, but the Fe³⁺/Fe_T ratios of each mineral do not vary. Clinopyroxene, spinel, and olivine Fe³⁺/Fe_T ratios are significantly higher than in unmetasomatized spinel peridotites. Metasomatic changes in Fe³⁺/Fe_T ratios in each mineral are controlled by the oxygen fugacity of the system, but the mechanism by which each phase accommodates this ratio is affected by crystal chemistry, kinetics, rock mode, fluid composition, fluid/rock ratio, and fluid-mineral partition coefficients. Ratio increases in pyroxene and spinel occur by exchange reactions involving diffusion of Fe³⁺ into existing mineral grains rather than by oxidation of existing Fe²⁺ in peridotite mineral grains. The very high Fe³⁺/Fe_T ratio in the metasomatic amphibole may be a function of the high Fe³⁺/Fe_T of the metasomatic fluid, crystal chemical limitations on the amount of Fe³⁺ that could be accommodated by the pyroxene, spinel, and olivine of the peridotite, and the ability of the amphibole structure to accommodate large amounts of 3 + valence cations. In the samples studied, metasomatic amphibole accounts for half of the bulk-rock Fe₂O₃. This suggests that patent metasomatism may produce a greater change in the redox state of mantle peridotite than cryptic metasomatism. Comparison of the metasomatized samples with unmetasomatized peridotites reveals that both Fe²⁺ and Fe³⁺ cations p.f.u. were increased during metasomatism and 50% or more of iron added was Fe³⁺. With increasing distance from the dike, the ratio of added Fe³⁺ to added Fe²⁺ increases. The high Fe³⁺/Fe_T of amphibole and phlogopite in the dikes and in the peridotite, and the high ratios of added Fe³⁺/added Fe²⁺ in pyroxenes and spinel suggest that the Fe³⁺/Fe_T ratio of the metasomatic silicate fluid was high. As the fluid perolated through and reacted with the peridotite, Fe³⁺ and C–O–H volatile species were concentrated in the fluid, increasing the fluid Fe³⁺/Fe_T.     

Linking Spatial and Temporal Variation at Multiple Scales in a Heterogeneous Landscape*

Anthropogenic, ecological, and land‐surface processes interact in landscapes at multiple spatial and temporal scales to create characteristic patterns. The relationships between temporally and spatially varying processes and patterns are poorly understood because of the lack of spatiotemporal observations of real landscapes over significant stretches of time. We report a new method for observing joint spatiotemporal landscape variation over large areas by analyzing multitemporal Landsat data. We calculate the spatiotemporal variation of the Normalized Difference Vegetation Index (NDVI) in the area covered by one Landsat scene footprint in north central Florida, over spatial windows of 10⁴–10⁸ m² and time steps of two to sixteen years. The correlations, slopes, and intercepts of spatial versus temporal regressions in the real landscape all differ significantly from results obtained using a null model of a randomized landscape. Spatial variances calculated within windows of 10⁵–10⁷ m² had the strongest relationships with temporal variances (regressions with both larger and smaller windows had lower coefficients of determination), and the relationships were stronger with longer time steps. Slopes and y‐intercepts increased with window size and decreased with increased time step. The spatial and temporal scales at which NDVI signals are most strongly related may be the characteristic scales of the processes that most strongly determine landscape patterns. For example, the important time and space windows correspond with areas and timing of fires and tree plantation harvests. Observations of landscape dynamics will be most effective if conducted at the characteristic scales of the processes, and our approach may provide a tool for determining those scales.     

Diatom assemblage response to Iroquoian and Euro-Canadian eutrophication of Crawford Lake,Ontario, Canada

Diatom and geochemical data from Crawford Lake, Ontario, have been used to document limnological responses to periods of cultural disturbance resulting from native Iroquoian occupation of the watershed (1268–1486 AD) and Euro-Canadian agriculture and deforestation (1867 AD–present). Here, we further develop the high-resolution nature of the Crawford Lake sediment record to examine the physical, chemical and biological aspects of limnological response to human disturbances in the lake catchment area with exceptional detail. We report detailed diatom abundance and flux data for individual taxa from Crawford Lake, and further describe the relationship between assemblage composition and environmental conditions using canonical correspondence analysis (CCA). Diatom assemblage data are used to calculate diatom inferred-total phosphorus (DI-TP) concentrations for the past ∼1,000 years. We also examine the diatom community response during and after periods of disturbance by Iroquoian and Euro-Canadian populations, and compare this response to existing geochemical proxies of lake production and new elemental geochemical indicators of catchment area erosion. In particular, we explore the differing limnological response to the two distinct periods of cultural eutrophication and examine the limnological processes that occurred during the period of␣low (or no) human activity (1487–1866 AD), when geochemical indicators of lake production recovered to pre-disturbance conditions, but diatom assemblages notably did not. Our results illustrate the highly susceptible nature of diatom communities to periods of anthropogenic disturbance, and emphasize that ecological indicators (such as diatom assemblages) should be included with other proxies (such as nutrient concentrations and physical characteristics) when assessing disturbance and recovery in lake systems.     

Towards realistic simulations of lava dome growth using the level set method

The level set method has been implemented in a computational volcanology context. New techniques are presented to solve the advection equation and the reinitialisation equation. These techniques are based upon an algorithm developed in the finite difference context, but are modified to take advantage of the robustness of the finite element method. The resulting algorithm is tested on a well documented Rayleigh–Taylor instability benchmark [19], and on an axisymmetric problem where the analytical solution is known. Finally, the algorithm is applied to a basic study of lava dome growth.     

Imaging of the shell galaxies NGC 474 and 7600, and implications for their formation

We present photometric observations of two shell galaxies, NGC 474 and 7600. We examine the photometric colours and surface brightnesses of the shells and their host galaxies, and the isophotal parameters of each galaxy. In the case of NGC 474, we find that the shell formation is consistent with a merger origin, although it is possible that the close companion NGC 470 is contributing to the shell system via mass transfer. NGC 7600 exhibits shell geometry and colours which also favour a merger origin.     

Monitoring the grazing resources of the Badia region, Jordan, using remote sensing

In this paper we discuss how low spatial resolution (1 km) ERS ATSR-2 and NOAA AVHRR satellite data were used to map and monitor changes in the grazing vegetation of the Badia region of Jordan. This area is typical of many arid zone grazing areas, comprising sparse vegetation and highly reflective soils. These two factors were found to severely limit the usefulness of satellite-derived vegetation indices that are frequently used to map and monitor vegetation in more temperate areas. Furthermore, the relationship between vegetation indices and percentage vegetation cover was found to be site-specific, thus reducing their application for large-scale vegetation monitoring. As an alternative, a hybrid geometric optical/empirically based model was developed for the area. This was based on the illumination geometry and reflectance values from the red and near-infrared scattergram of the satellite images. The output of the model was a series of maps indicating percentage vegetation cover for different dates and these were used to construct maps showing areas of vegetation change. Strong correlations (r²=0.837) were found between estimates of percentage vegetation cover derived from the model, and measurements made at a series of 16 field sites in the area. The use of geometric optical models based on satellite imagery improves the ability to map areas of grazing vegetation in arid areas such as the Badia and provides a good alternative to the use of vegetation indices.     

Benthic metabolism and nutrient cycling along an estuarine salinity gradient

Benthic metabolism and nutrient exchange across the sediment-water interface were examined over an annual cycle at four sites along a freshwater to marine transect in the Parker River-Plum Island Sound estuary in northeastern Massachusetts, U.S. Sediment organic carbon content was highest at the freshwater site (10.3%) and decreased along the salinity gradient to 0.2% in the sandy sediments at the marine end of the estuary. C:N ratios were highest in the mid estuary (23:1) and lowest near the sea (11:1). Chlorophyll a in the surface sediments was high along the entire length of the estuary (39–57 mg chlorophyll a m⁻²) but especially so in the sandy marine sediments (172 mg chlorophyll a m⁻²). Chlorophyll a to phaeophytin ratios suggested most chlorophyll is detrital, except at the sandy marine site. Porewater sulfide values varied seasonally and between sites, reflecting both changes in sulfate availability as overlying water salinity changed and sediment metabolism. Patterns of sediment redox potential followed those of sulfide. Porewater profiles of inorganic N and P reflected strong seasonal patterns in remineralization, accumulation, and release. Highest porewater NH₄ ⁺ values were found in upper and mid estuarine sediments, occasionally exceeding 1 mM N. Porewater nitrate was frequently absent, except in the sandy marine sediments where concentrations of 8 μM were often observed. Annual average respiration was lowest at the marine site (13 mmol O₂ m⁻² d⁻¹ and 21 mmol TCO₂ m⁻² d⁻¹) and highest in the mid estuary (130 mmol O₂ m⁻² d⁻¹ and 170 mmol TCO₂ m⁻² d⁻¹) where clam densities were also high. N₂O and CH₄ fluxes were low at all stations throughout the year: Over the course, of a year, sediments varied from being sources to sinks of dissolved organic C and N, with the overall spatial pattern related closely to sediment organic content. There was little correlation between PO₄ ³⁻ flux and metabolism, which we attribute to geochemical processes. At the two sites having the lowest salinities, PO₄ ³⁻ flux was directed into the sediments. On average, between 22% and 32% of total system metabolism was attributable to the benthos. The mid estuary site was an exception, as benthic metabolism accounted for 95% of the total, which is attributable to high densities of filter-feeding clams. Benthic remineralization supplied from less than 1% to over 190% of the N requirements and 0% to 21% of the P requirements of primary producers in this system. Estimates of denitrification calculated from stoichiometry of C and N fluxes ranged from 0% for the upper and mid estuary site to 35% for the freshwater site to 100% of sediment organic N remineralization at the marine site. We hypothesize that low values in the upper and mid estuary are attributable to enhanced NH₄ ⁺ fluxes during summer due to desorption of exchangeable ammonium from rising porewater salinity. NH₄ ⁺ desorption during summer may be a mechanism that maintains high rates of pelagic primary production at a time of low inorganic N inputs from the watershed.     

Long-term impact of the proglacial lake Jökulsárlón on the flow velocity and stability of Breiðamerkurjökull glacier,Iceland

Proglacial lakes are becoming ubiquitous at the termini of many glaciers worldwide due to continued climate warming and glacier retreat, and such lakes have important consequences for the dynamics and future stability of these glaciers. In light of this, we quantified decadal changes in glacier velocity since 1991 using satellite remote sensing for Breiðamerkurjökull, a large lake-terminating glacier in Iceland. We investigated its frontal retreat, lake area change and ice surface elevation change, combined with bed topography data, to understand its recent rapid retreat and future stability. We observed highly spatially variable velocity change from 1991 to 2015, with a substantial increase in peak velocity observed at the terminus of the lake-terminating eastern arm from ~1.00 ± 0.36 m day⁻¹ in 1991 to 3.50 ± 0.25 m day⁻¹ in 2015, with mean velocities remaining elevated from 2008 onwards. This is in stark comparison to the predominately land-terminating arms, which saw no discernible change in their velocity over the same period. We also observed a substantial increase in the area of the main proglacial lake (Jökulsárlón) since 1982 of ~20 km², equating to an annual growth rate of 0.55 km² year⁻¹. Over the same period, the eastern arm retreated by ~3.50 km, which is significantly greater than the other arms. Such discrepancies between the different arms are due to the growth and, importantly, depth increase of Jökulsárlón, as the eastern arm has retreated into its ~300 m-deep reverse-sloping subglacial trough. We suggest that this growth in lake area, forced initially by rising air temperatures, combined with the increase in lake depth, triggered an increase in flow acceleration, leading to further rapid retreat and the initiation of a positive feedback mechanism. These findings may have important implications for how increased melt and calving forced by climate change will affect the future stability of large soft-bedded, reverse-sloped, subaqueous-terminating glaciers elsewhere. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd